An Investigation of the Manufacturing Process, Structure, and Performance of the New Micro and Nano Thermoplastic-based Composites Prepared with Zeolite Filler
محورهای موضوعی : Manufacturing process monitoring and control
Ahmed Hebatalrahman
1
(Dr. Eng., Consultant in Material Science, Egypt)
کلید واژه: zeolite, Composite, Filler, Thermoplastic, Micro-nano, Manufacturing process,
چکیده مقاله :
New nano and micro thermoplastic-based composites are prepared with zeolite filler in this study. The method involves using zeolite in powder form, the preparation of zeolite powder from ores by crushing it into small-sized granules. The characteristics of the zeolite powder are determined. The physical properties and chemical composition (XRD) are evaluated before impeding it into the thermoplastic. Thermoplastics powder is added to the zeolite powder as granules in different sizes, the particles sizes ranging from the size of a millimeter to a nanometer. The manufacturing quality parameters are optimized at volume percentages of filler in the range of 20 to 25%, composite material is formed into molds. New Composite material is characterized by easy deformation into different shapes besides machineability. The characteristics of new composites such as SEM, EDX, and FTIR in absorption and transmission mode are evaluated and compared with the standard characteristics of Zeolite ores. The performance and characteristics of the new composite are completely different. The new composite is hard, solid, and does not absorb water.
[1] Koronis, G.,Silva, A. and Fontul, M. 2013. Green composites: A review of adequate materials for automotive applications. Composites Part B: Engineering.44 (1):120-127.
[2] Cai, Y., Zhao, L., and Zhang, Y. Composites Based Green Poly (L-Lactic Acid) and Dioctyl Phthalate: Preparation and Performance. Advances in Materials Science and Engineering: Green Composite Materials. Article ID 289725.
[3] Lee, S. M. 1989. Reference Book for Composites Technology, Volume I. CRC Press.
[4] Moliner, M., Martínez, C. and Corma, A. 2015. Multipore Zeolites: Synthesis and Catalytic Applications. Angewandte Chemie. 54(12):3560-3579.
[5] Liu, J. W., Chen, L. F., Cui, H., Zhang, J. Y., Zhang, L., Y. and Su, C. Y. 2014. Applications of metal-organic frameworks in heterogeneous supramolecular catalysis. Chemical Society Reviews. 43:6011–6061.
[6] Chughtai, A. H., Ahmad, N., Younus, H. A., Laypkovc, A. and Verpoort, F. 2015. Metal–organic frameworks: versatile heterogeneous catalysts for efficient catalytic organic transformations. Chemical Society Reviews. 44:6804-6849.
[7] He, H., Perman, J. A., Zhu, G. and Ma. S. 2016. Small. Metal-Organic Frameworks for CO2 Chemical Transformations. 12(46): 6309-6324.
[8] Rimoldi, M., Howarth, A. J., DeStefano, M. R., Lin, L., Goswami, S., Li, P., Hupp, J. T. and O. K. Farha. 2017. Catalytic Zirconium/Hafnium-Based Metal–Organic Frameworks. ACS Catalysis, 7(2): 997–1014.
[9] Huang, Y-B., Liang, J., Wang, X-S. and R. Cao. 2017. Multifunctional metal–organic framework catalysts: synergistic catalysis and tandem reactions. Chemical Society Reviews. 46: 126-157.
[10] Guo, X., Feng, Y., Ma, L., Gao, D., Jing, J., Yu, J., Sun, H., Gong, H. and Zhang. Y. 2017. Phosphoryl functionalized mesoporous silica for uranium adsorption. Applied Surface Science. 402: 53-60.
[11] Falcaro, P., Ricco, R., Yazdi, A., Imaz, I., Furukawa, S., Maspoch, D., Ameloot, R., Evans, J. D., and Doonan, C. J. 2016. Application of metal and metal oxide nanoparticles at MOFs. Coordination Chemistry Reviews.307 (Part 2):237-254.
[12] Chen, Y-Z., Wang, Z. U., Wang, H., Lu, J., Yu, S-H., Jiang. H-L. 2017. Singlet Oxygen-Engaged Selective Photo-Oxidation over Pt Nanocrystals/Porphyrinic MOF: The Roles of Photothermal Effect and Pt Electronic State. Journal of the American Chemical Society. 139(5):2035–2044.
[13] Guisnet, M. and Gilson, J. 2003. Zeolites for Cleaner Technologies, Imperial College Press, London.
[14] Maxwell, I. E., Minderhoud, J. K., Stork, W. H. J. and van Veen, J. A. R. 1997. Handbook of Heterogeneous Catalysis. Wiley-VCH, Weinheim, Germany.
[15] Baerlocher, Ch., McCusker, L. B. and Olson, D.H. 2007. Atlas of Zeolite Framework Types. Elsevier Science; 6th edition.
[16] Ferraz, E., Andrejkovicová, S., Velosa, A., Santos Silva, A. and Rocha, F. 2014 Synthetic zeolite pellets incorporated to air lime–metakaolin mortars: mechanical properties. Construction & Building Materials. 69: 243–252.
[17] Auerbach, S. M., Carrado, K. A. and Dutta, P. K. 2003. Handbook of zeolite science and technology. CRC Press, Boca Raton.
[18]First, E. L., Gounaris, C. E., Wei, J. and Floudas, C. A. 2011. Computational characterization of zeolite porous networks: An automated approach. Physical Chemistry Chemical Physics. 13(38): 17339–17358.
[19] Koningsveld, H. 2007. Compendium of Zeolite Framework Types (Building Schemes and Type Characteristics). Elsevier, Amsterdam.
