Age-Hardening Behavior and the Related Changes in a Silver-Copper-Palladium Alloy
محورهای موضوعی : Non-Ferrous H.T.Morteza Hadi 1 , Iman Ebrahimzadeh 2 , Omid Bayat 3
1 - Metallurgy and Materials Engineering Department, Golpayegan University of Technology, Golpayegan, Iran
2 - Advanced Materials Research Center, Department of Materials Engineering, Najafabad Branch, Islamic Azad University, Najafabad, Iran
3 - Department of Materials science and Engineering, Hamedan University of Technology, Hamedan, Iran
کلید واژه: X-ray diffraction, Scanning Electron Microscopy, Age-hardening, Ag-Cu-Pd alloys,
چکیده مقاله :
Age-hardening behavior and related changes were studied to elucidate the hardening mechanism of an Ag–Cu–Pd alloyby Differential Scanning Calorimetry (DSC), hardness test, X-ray diffraction (XRD), scanning electron microscopic (SEM) observations and energy dispersive spectrometer (EDS). The results showed that hardness of the alloy was raised to 90% and 68% of its solution state value by isothermal aging at 300 ◦C and 400 ◦C, respectively. However, aging at 500 ◦C led to a decrease in the hardness of the alloy. Moreover, while age hardening at 300◦C occurred due to coherency strains between the (111) plane of Ag-rich and the (111) plane of Cu3Pd phases, the mechanism of aging at 400◦C was the formation ofCu3Pd superlattice with the L12-type crystal structure. In contrast, reduction of Cu3Pd phase and formation of Cu solid solution decreased hardness during aging at 500oC.
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