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  • اثرات بور بر محیط زیست و روش‌های حذف آن از محلول‌های آبی

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آدرس مقاله


کد مقاله : 13661 بازدید : 57 صفحه: 17 - 27

20.1001.1.15625532.1397.16.4.2.9

نوع مقاله: پژوهشی

اثرات بور بر محیط زیست و روش‌های حذف آن از محلول‌های آبی

محورهای موضوعی : آلودگی محیط زیست (آب و فاضلاب)

شهره عسگری 1 (دکتری شیمی، دانشکده شیمی، دانشگاه پیام نور، تهران، ایران. *(مسوول مکاتبات))
اعظم منفرد 2 (استادیار، دانشکده شیمی، دانشگاه پیام نور، تهران ، ایران.)
مهرداد فلاح 3 (دکتری شیمی، دانشکده شیمی، دانشگاه پیام نور، تهران، ایران.)

تاریخ دریافت : 1395/12/25 تاریخ پذیرش : 1396/02/16 تاریخ انتشار : 1397/10/01

کلید واژه: بور, محیط زیست, حذف بور,

چکیده مقاله :

بور (بورون) میکرو مغذی بسیار مهمی برای گیاهان و حیوانات می باشد، بدین معنی که مقادیر بسیار کم بور برای رشد آن ها لازم و ضروری است. این عنصر بسیار مورد توجه است، زیرا هم کمبود آن و هم مازاد آن برای بسیاری از گیاهان مضر است و فاصله بین این دو مقدار بسیار محدود است. در انسان ها نیز مقادیر بسیار کمی از بورون در تمام بافت ها وجود دارد، اما مقدار اضافی بور ممکن است منجر به آسیب سیستم عصبی شود، از این جهت در بسیاری از کشورها غلظت بور در آب آشامیدنی و فاضلاب کنترل می شود. مقدار مجاز بور در آب آشامیدنی طبق توصیه سازمان بهداشت جهانی(WHO)[1]مقدار5/0 است و بر این اساس، حذف بور از محلول های مایی و آب ها یکی از دغدغه های بزرگ بهداشت عمومی و محیط زیستی می باشد. اخیرا روش های مختلفی برای جداسازی بور از آب در حال توسعه هستند که از بین این روش ها، فرآیندهای جذبی، فرآیندهای غشایی، فرآیندهای هیبریدی کارامدتر هستند. ما دراین مقاله، اطلاعاتی در مورد بور-خواص آن منابع آن، تاثیر آن بر محیط زیست، گیاهان و حیوانات و روش های جدیدی برای حذف آن ارایه می کنیم. [1]-World Health Organization

چکیده انگلیسی:

Boron is very important micronutrient for plants and animals, which menas essential for growth of them in very small quantities. This is the element of special attention as its deficiency and excess are harmful for many plants and the gap between both these level is very narrow. In humans, small amount of boron occur in all tissues but an excess of boron may lead to damage of nervous system. Therefore, boron concentration in drinking water and wastewater is regulated in many countries. The recommended boron content in drinking water according to world health organization (WHO) guideline is 0.5 and according to this limit, the removal of boron from aqueous solution and water is of great environmental and health public health concern. Recently different methods to separate boron from water have been developed. Among them the more effective methods are adsorption processes, membrane processes and hybrid processes. In this manuscript, we presenting knowledge on boron, its properties, sources, effects on environment, plants, animals and new methods for its removal.

منابع و مأخذ:


  1. Sarkar, A.,Mao, X.,Russo, R, E., Advancing the analytical capabilities of laser ablation molecular isotopic spectrometry for boron isotopic analysis. Spectrochimica Acta Part B: Spectrochimica Acta Part B: Atomic Spectroscopy, 2014; vol.92, pp. 42- 50.
    2.
  2. Hilal, N.,Kim,G, J., Somerfield, C., Boron removal from saline water: A comprehensive review. Desalination 2010; vol.273, pp.23-35.
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  3. Sahin, S., A mathematical relationship for the explanation of ion exchange for boron adsorption. Desalination 2002; vol.143, pp.35-43.
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  4. Kozlecki, T., Polowczyk, I., Adsorption of Boron by Minerals, Clays, and Soils, Boron Separation processes, 2015; vol.6, pp.147– 168.
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  5. Tu, K, L., Ngheim, L, D., Chivas, A, R., Boron removal by reverse osmosis membranesin seawater desalination, Sep. Purif. Technol, 2010; vol.75, pp. 87 –101.
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  6. Stumm, W, W., Morgan, J., Aquatic Chemistry: Chemical Equilibria and Rates in Natural Waters, 3rd Edition, John Wiley & Sons, London, 1995, 1040 pages.
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  7. Edzwald, J, K., Haarhoff ,J., Seawater pretreatment for reverse osmosis: chemistry contaminants and coagulation, Water Res. 2011; vol. 45, pp. 5428– 5440.
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  8. Wyness, A, J., Parkaman, R, H., Neal, C., A summary of boron surface water qualitydata throughout the European Union, Sci. Total Environ. 2003; vol. 314–316, pp.255-269.
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  9. Melnyk, L., Goncharuk, V., Butnyk, I., Tsapiuk, E.,.Boron removal from natural and wastewaters using combined sorption membrane process, Desalination, 2005; vol.185, pp.147-157.
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  10. Takano, J., Miwa, K., Fujiwara, T., Boron transport mechanisms: collaboration ofchannel and transports, Trends Plant Sci, 2008; vol.13, pp. 451– 457.
    11.
  11. Kabay, N., Yilmaz, I., Yamac, S., Yuksel, M., Yuksel, U., Yildirim, N., Aydogdu, O., Iwanaga, T., Hirowatari, K.,. Removal and recovery of boron from geothermal waste-water by selective ion-exchange resins II. Field tests, Desalination, 2004; vol. 167, pp. 427 –438.
    12.
  12. Kabay, N., Yilmaz, I., Bryjak, M., Yuksel, M., Removal of boron from aqueous solu-tions by hybrid ion exchange-membrane process, Desalination, 2006; vol.198, pp.158-165.
    13.
  13. Rainey, C, J., Nyquist, L. A., Christensen, R, E., Strong, P,L., Dwight Culver, B.,Coughlin, J,R.,. Daily boron intake from the American diet, J. Am. Diet. Assoc, 1999; vol. 99 , pp.335-340.
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  14. Melnik, L. A., Butnik, I, A., Goncharuk, V, V., Sorption – membrane removal of boron compounds from natural and waste waters: ecological and economic aspects, J. Water Chem. Technol, 2008; vol. 30, pp.167 –179.
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  15. Wolska, J., Bryjak, M., Method for boron removal from aqueous solutions, Desalination, 2013; vol. 310, pp. 18-24.
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  16. Bicak, N., Bulutcu, N., Senkal, B,F., Gazi, M., Modi fication of crosslinked glycidylmethacrylate- based polymers for boron-specific column extraction, React. Funct. Polym, 2001; vol.47, pp. 175– 184.
    17.
  17. Bicak, N., Ozbelge, O., Yilmaz, L., Senkal, B,F., Crosslinked polymer gels for boronextraction derived from N -glucidol- N-methyl-2-hydroxypr opyl methacrylate, Macromol. Chem. Phys, 2000; vol. 201, pp. 577– 584.
    18.
  18. Marston, C., Busch, M., Prabhakaren, S., A boron selective resin for seawater desalination , in: Proceedings of Euro pean Desalination Socie ty Con ference on Desa-lination and the Environment, 2005, 5, 11 Santa Margerita Ligure, Italy.
    19.
  19. Bicak, N., Bulutcu, N., Senkal, B, F., Gazi, M., Modification of crosslinked glycidyl methacrylate- based polymers for boron-specific column extraction, React. Funct. Polym, 2001; vol. 47, pp. 175– 184.
    20.
  20. Orlando, U, S., Okuda, T., Nishijima, W., Chemical properties of anion exchangersprepared from waste natural materials, React. Funct. Polym, 2003; vol.55, pp. 311 – 318.
    21.
  21. Wei, Y, T., Zheng, Y, M.., Chen, J, P., Design and fabrication of an innovative and en-vironmental friendly adsorbent for boron removal, Water Res, 2011; vol. 45, pp. 2297-2305.
    22.
  22. Goncharuk,V,V., Babak, Yu, V., Melnik, L, A., Trachevskii, V, V., Removal of boron inthe course of pressure-driven demineralization, J. Water Chem. Technol, 2011; vol. 33, pp. 307-314.
    23.
  23. Hasson, D., Shemer, H., Brook, H., Zaslavschi, I., Semiat, R., Bartels, C., Wilf, M.,. Scalingpropensity of seawater in RO boron removal processes, J. Membr. Sci, 2011; vol. 384, PP.198-204.
    24.
  24. Bryjak, M., Duraj, I., Poź niak, G., Colloid-enhanced ultrafiltration in removal oftraces amounts of borates from water, Environ. Geochem. Health, 2010; vol. 32, PP. 275-277.
    25.
  25. Dilek, C., Őzbelge, H, O., Bicak, N., Yilmaz, L., Removal of boron from aqueous solutions by continuous polymer-enhanced ultrafi ltration with polyvinyl alcohol, Sep. Sci. Technol, 2002; vol. 37, PP. 1257– 1271.
    26.
  26. Smith, B, F., Robison, T, W., Carlson, B, J., Labouriau, A., Khalsa, G, R, K., Schroeder, N, C., Jarvinen, G, D., Lubeck, C, R., Folkert, S, L., Aguino, D, I., Boric acid recovery usingpolymer filtration: studies with alkyl monool, diol, and triol containingpolyethylenimine s, J. Appl. Polym. Sci, 2005; vol. 97, pp. 1590 – 1604.
    27.
  27. Doganay, C, O., Őzbelge, H, O., Bicak, N., Aydogan, N., Yilmaz, L., Use of specificallytailored chelating polymers for boron removal from aqueous solutions by polymer enhanced ultrafiltration, Sep. Sci. Technol, 2011; vol. 46, pp. 581–591.
    28.
  28. Koltuniewicz, A, B., Witek, A., Bezak, K., Efficiency of membrane sorption integrates processes, J. Membr. Sci, 2004; vol. 239, pp. 129–141.
    29.
  29. Vasudevan, S., Lakshmi, J., Sozhan, G., Electrochemically assisted coagulation forthe removal of boron from water using zinc anode, Desalination, 2013; vol. 310, pp. 122–129.
    30.
  30. Akretche, D, E., Kerdjoudj, H., Donnan dialysis of copper, gold and silver cyanides with various anion exchange membranes, Talanta, 2000. vol. 51, pp. 281–289.
    31.
  31. Avraham, A., Noked, M., Soffer, A., Aurbach, D., The feasibility of boron removalfrom water by capacitive deionization, Electrochim. Acta, 2011 vol. 56, pp. 6312–6317.
    32.
  32. Hou, D., Wang, J., Sun, X., Luan, Z., Zhao, Ch., Ren, X., Boron removal from aqueoussolution by direct contact membrane distillation, J. Hazard. Mater, 2010; vol. 177, pp. 613–619.
    33.
  33. Tsai, H, Ch., Lo, S, L., Boron removal and recovery from concentrated wastewaterusing a microwave hydrothermal method, J. Hazard. Mater, 2011; vol. 186, pp. 1431–1437.
    34.
  34. Fortuny, A., Coll, M. T., Sastre, A, M., Use of methyltrioctyl/decylammonium bis2,4,4-(trimethylpentyl)phosphinate ionic liquid (ALiCY IL) on the boron extractionin chloride media, Sep. Purif. Technol, 2012; vol. 90, pp. 151-159.
    35.



 

_||_

  1. Sarkar, A.,Mao, X.,Russo, R, E., Advancing the analytical capabilities of laser ablation molecular isotopic spectrometry for boron isotopic analysis. Spectrochimica Acta Part B: Spectrochimica Acta Part B: Atomic Spectroscopy, 2014; vol.92, pp. 42- 50.
    2.
  2. Hilal, N.,Kim,G, J., Somerfield, C., Boron removal from saline water: A comprehensive review. Desalination 2010; vol.273, pp.23-35.
    3.
  3. Sahin, S., A mathematical relationship for the explanation of ion exchange for boron adsorption. Desalination 2002; vol.143, pp.35-43.
    4.
  4. Kozlecki, T., Polowczyk, I., Adsorption of Boron by Minerals, Clays, and Soils, Boron Separation processes, 2015; vol.6, pp.147– 168.
    5.
  5. Tu, K, L., Ngheim, L, D., Chivas, A, R., Boron removal by reverse osmosis membranesin seawater desalination, Sep. Purif. Technol, 2010; vol.75, pp. 87 –101.
    6.
  6. Stumm, W, W., Morgan, J., Aquatic Chemistry: Chemical Equilibria and Rates in Natural Waters, 3rd Edition, John Wiley & Sons, London, 1995, 1040 pages.
    7.
  7. Edzwald, J, K., Haarhoff ,J., Seawater pretreatment for reverse osmosis: chemistry contaminants and coagulation, Water Res. 2011; vol. 45, pp. 5428– 5440.
    8.
  8. Wyness, A, J., Parkaman, R, H., Neal, C., A summary of boron surface water qualitydata throughout the European Union, Sci. Total Environ. 2003; vol. 314–316, pp.255-269.
    9.
  9. Melnyk, L., Goncharuk, V., Butnyk, I., Tsapiuk, E.,.Boron removal from natural and wastewaters using combined sorption membrane process, Desalination, 2005; vol.185, pp.147-157.
    10.
  10. Takano, J., Miwa, K., Fujiwara, T., Boron transport mechanisms: collaboration ofchannel and transports, Trends Plant Sci, 2008; vol.13, pp. 451– 457.
    11.
  11. Kabay, N., Yilmaz, I., Yamac, S., Yuksel, M., Yuksel, U., Yildirim, N., Aydogdu, O., Iwanaga, T., Hirowatari, K.,. Removal and recovery of boron from geothermal waste-water by selective ion-exchange resins II. Field tests, Desalination, 2004; vol. 167, pp. 427 –438.
    12.
  12. Kabay, N., Yilmaz, I., Bryjak, M., Yuksel, M., Removal of boron from aqueous solu-tions by hybrid ion exchange-membrane process, Desalination, 2006; vol.198, pp.158-165.
    13.
  13. Rainey, C, J., Nyquist, L. A., Christensen, R, E., Strong, P,L., Dwight Culver, B.,Coughlin, J,R.,. Daily boron intake from the American diet, J. Am. Diet. Assoc, 1999; vol. 99 , pp.335-340.
    14.
  14. Melnik, L. A., Butnik, I, A., Goncharuk, V, V., Sorption – membrane removal of boron compounds from natural and waste waters: ecological and economic aspects, J. Water Chem. Technol, 2008; vol. 30, pp.167 –179.
    15.
  15. Wolska, J., Bryjak, M., Method for boron removal from aqueous solutions, Desalination, 2013; vol. 310, pp. 18-24.
    16.
  16. Bicak, N., Bulutcu, N., Senkal, B,F., Gazi, M., Modi fication of crosslinked glycidylmethacrylate- based polymers for boron-specific column extraction, React. Funct. Polym, 2001; vol.47, pp. 175– 184.
    17.
  17. Bicak, N., Ozbelge, O., Yilmaz, L., Senkal, B,F., Crosslinked polymer gels for boronextraction derived from N -glucidol- N-methyl-2-hydroxypr opyl methacrylate, Macromol. Chem. Phys, 2000; vol. 201, pp. 577– 584.
    18.
  18. Marston, C., Busch, M., Prabhakaren, S., A boron selective resin for seawater desalination , in: Proceedings of Euro pean Desalination Socie ty Con ference on Desa-lination and the Environment, 2005, 5, 11 Santa Margerita Ligure, Italy.
    19.
  19. Bicak, N., Bulutcu, N., Senkal, B, F., Gazi, M., Modification of crosslinked glycidyl methacrylate- based polymers for boron-specific column extraction, React. Funct. Polym, 2001; vol. 47, pp. 175– 184.
    20.
  20. Orlando, U, S., Okuda, T., Nishijima, W., Chemical properties of anion exchangersprepared from waste natural materials, React. Funct. Polym, 2003; vol.55, pp. 311 – 318.
    21.
  21. Wei, Y, T., Zheng, Y, M.., Chen, J, P., Design and fabrication of an innovative and en-vironmental friendly adsorbent for boron removal, Water Res, 2011; vol. 45, pp. 2297-2305.
    22.
  22. Goncharuk,V,V., Babak, Yu, V., Melnik, L, A., Trachevskii, V, V., Removal of boron inthe course of pressure-driven demineralization, J. Water Chem. Technol, 2011; vol. 33, pp. 307-314.
    23.
  23. Hasson, D., Shemer, H., Brook, H., Zaslavschi, I., Semiat, R., Bartels, C., Wilf, M.,. Scalingpropensity of seawater in RO boron removal processes, J. Membr. Sci, 2011; vol. 384, PP.198-204.
    24.
  24. Bryjak, M., Duraj, I., Poź niak, G., Colloid-enhanced ultrafiltration in removal oftraces amounts of borates from water, Environ. Geochem. Health, 2010; vol. 32, PP. 275-277.
    25.
  25. Dilek, C., Őzbelge, H, O., Bicak, N., Yilmaz, L., Removal of boron from aqueous solutions by continuous polymer-enhanced ultrafi ltration with polyvinyl alcohol, Sep. Sci. Technol, 2002; vol. 37, PP. 1257– 1271.
    26.
  26. Smith, B, F., Robison, T, W., Carlson, B, J., Labouriau, A., Khalsa, G, R, K., Schroeder, N, C., Jarvinen, G, D., Lubeck, C, R., Folkert, S, L., Aguino, D, I., Boric acid recovery usingpolymer filtration: studies with alkyl monool, diol, and triol containingpolyethylenimine s, J. Appl. Polym. Sci, 2005; vol. 97, pp. 1590 – 1604.
    27.
  27. Doganay, C, O., Őzbelge, H, O., Bicak, N., Aydogan, N., Yilmaz, L., Use of specificallytailored chelating polymers for boron removal from aqueous solutions by polymer enhanced ultrafiltration, Sep. Sci. Technol, 2011; vol. 46, pp. 581–591.
    28.
  28. Koltuniewicz, A, B., Witek, A., Bezak, K., Efficiency of membrane sorption integrates processes, J. Membr. Sci, 2004; vol. 239, pp. 129–141.
    29.
  29. Vasudevan, S., Lakshmi, J., Sozhan, G., Electrochemically assisted coagulation forthe removal of boron from water using zinc anode, Desalination, 2013; vol. 310, pp. 122–129.
    30.
  30. Akretche, D, E., Kerdjoudj, H., Donnan dialysis of copper, gold and silver cyanides with various anion exchange membranes, Talanta, 2000. vol. 51, pp. 281–289.
    31.
  31. Avraham, A., Noked, M., Soffer, A., Aurbach, D., The feasibility of boron removalfrom water by capacitive deionization, Electrochim. Acta, 2011 vol. 56, pp. 6312–6317.
    32.
  32. Hou, D., Wang, J., Sun, X., Luan, Z., Zhao, Ch., Ren, X., Boron removal from aqueoussolution by direct contact membrane distillation, J. Hazard. Mater, 2010; vol. 177, pp. 613–619.
    33.
  33. Tsai, H, Ch., Lo, S, L., Boron removal and recovery from concentrated wastewaterusing a microwave hydrothermal method, J. Hazard. Mater, 2011; vol. 186, pp. 1431–1437.
    34.
  34. Fortuny, A., Coll, M. T., Sastre, A, M., Use of methyltrioctyl/decylammonium bis2,4,4-(trimethylpentyl)phosphinate ionic liquid (ALiCY IL) on the boron extractionin chloride media, Sep. Purif. Technol, 2012; vol. 90, pp. 151-159.
    35.



 

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