تهیه نانوکامپوزیت جاذب حشرهکش دیازینون از آب با استفاده از کربن فعال میوه کاج و نانوذرات اکسید منگنز
محورهای موضوعی :
کشاورزی و محیط زیست
نورالدین حسین پورآزاد
1
,
احسان شکری
2
,
نجمه نصیری
3
1 - استادیار گروه علوم گیاهی و گیاهان دارویی، دانشکده کشاورزی مشگین شهر، دانشگاه محقق اردبیلی *(مسئول مکاتبات)
2 - استادیار، بخش نانوفناوری، پژوهشگاه بیوتکنولوژی کشاورزی ایران، سازمان تحقیقات، آموزش و ترویج کشاورزی، کرج، ایران.
3 - دانش آموخته دکترای تخصصی مهندسی ژنتیک، دانشگاه علوم کشاورزی و منابع طبیعی ساری، ساری، ایران.
تاریخ دریافت : 1400/12/01
تاریخ پذیرش : 1401/02/12
تاریخ انتشار : 1401/04/01
کلید واژه:
نانوذرات دیاکسید منگنز,
میوه کاج,
نانوکامپوزیت,
جذب سطحی,
دیازینون,
کربن فعال,
چکیده مقاله :
زمینه و هدف: در سال های اخیر، استفاده از کربن فعال همراه با نانوکاتالیست های فلزی برای حذف بقایای آفت کش ها از محیط زیست، مورد توجه محققین قرار گرفته است. هدف از این پژوهش، حذف بقایای دیازینون از آب با استفاده از نانوکامپوزیت Nano-MnO2/PAC ساخته شده از کربن فعال میوه کاج Pinus eldarica حاوی نانوذرات دی اکسید منگنز می باشد.روش بررسی: ابتدا بقایای پودر شده میوه کاج با استفاده از اسید فسفریک بعنوان فعال کننده و به روش شیمیایی-گرمایی در اتمسفر نرمال تبدیل به کربن فعال گردید و سپس نانوذرات دی اکسید منگنز در بستر آن سنتز شده سپس ساختار شیمیایی و ظاهر کربن میوه کاج و نانوکامپوزیت حاصل با روش های مشخصه یابی SEM، TEM، XRD و IR توصیف شد. در ادامه آزمایشات جذب به منظور ارزیابی کارایی حذف دیازینون از محلول آبی با اعمال متغیرهای عملیاتی شامل pH (10-2)، دما ( ◦C42-16)، زمان تماس (min 120-2) و در غلظت های اولیه دیازینون (mg/L 100-05/0) مطالعه گردید.یافته ها: تصاویر میکروسکوپی و آنالیز طیف نشان داد که نانوذرات دی اکسید منگنز با اندازه تقریبی 5/37 نانومتر با پراکنش مطلوب در ساختار نانوکامپوزیت حضور داشته و مقادیر جزئی از نانوکامپوزیت (mg/L 3) قادر است 6/94 درصد از سم با غلظت اولیه mg/L 40 را از آب خارج نماید. بهترین توصیف از فرآیند جذب در pH بهینه 4 و برازش داده ها در مدل ایزوترم لانگمویر با ضریب همبستگی 985/0 بدست آمد.نتیجه گیری: با توجه به نتایج، حضور نانوذرات دی اکسید منگنز کارایی قابلیت حذف دیازینون را در مقایسه با کربن فعال میوه کاج به میزان 7/13 درصد بهبود می بخشد.
چکیده انگلیسی:
Background and Objective: The use of activated carbon in company with metal nano catalysts for pesticides removal from the environment has been considered by researchers, recently. This study aimed to remove diazinon residues from water using Nano-MnO2/PAC composite mading from Pinus eldarica activated carbon containing manganese dioxide nanoparticles.Method: Initially, the powdered residues of pine cone were treated using phosphoric acid and then converted to activated carbon by chemically heat method under ordinary atmosphere. Then manganese dioxide nanoparticles were synthesized in its substrate. The chemical structure and carbon appearance of the resulting pine fruit and nanocomposite were described by SEM, TEM, XRD, and IR characterization methods. Adsorption tests are performed to evaluate the removal efficiency of diazinon from aqueous solution by applying operational variables including pH (2-10), temperature (16-42 0C), contact time (2-120 min), and at initial concentrations (0.05-100 mg/L) of diazinon was studied.Findings: Microscopic images and spectroscopy showed that manganese dioxide nanoparticles with an approximate size of 37.5 nm were present in the nanocomposite. The results showed that small amounts of nanocomposite (3 mg/L) were able to remove 94.6% of the diazinon with an initial concentration of 40 mg/L. The best description of the adsorption process at optimal pH 4, with fit in the Langmuir isotherm model with a correlation coefficient of 0.985.Discussion and Conclusions: According to results, the presence of manganese dioxide nanoparticles improved the removal efficiency of diazinon by 13.7% compared to activated carbon of pine fruit.
منابع و مأخذ:
Edwards CA. Environmental pollution by pesticides. Springer Science & Business Media; 2013.
Sergiusz P. Drought and water shortages in Asia as a threat and economic problem. Journal of modern science. 2015; 26(3):235-250.
ČOlović M, Krstić D, Petrović S, Leskovac A, Joksić G, Savić J, et al. Toxic effects of diazinon and its photodegradation products. Toxicology Letters. 2010; 193(1):9–18.
Rajasulochana P, Preethy V. Comparison on efficiency of various techniques in treatment of waste and sewage water - A comprehensive review. Resource-Efficient Technologies. 2016; 2(4):175–184.
González-García P. Activated carbon from lignocellulosics precursors: A review of the synthesis methods, characterization techniques and applications. Renewable and Sustainable Energy Reviews. 2018; 82: 1393–1414.
Salehian P, Karimi K. Alkali Pretreatment for Improvement of Biogas and Ethanol Production from Different Waste Parts of Pine Tree. Industrial & Engineering Chemistry Research. 2013; 52(2): 972–978.
Bhomick PC, Supong A, Baruah M, Pongener C, Sinha D. Pine Cone biomass as an efficient precursor for the synthesis of activated biocarbon for adsorption of anionic dye from aqueous solution: Isotherm, kinetic, thermodynamic and regeneration studies. Sustainable Chemistry and Pharmacy. 2018; 10:41–49.
Thakur RS, Katoch SS, Modi A. Assessment of pine cone derived activated carbon as an adsorbent in defluoridation. SN Applied Sciences. 2020; 2(8):1-12.
Syed R, Saggar S, Tate K, Rehm BHA. Assessment of farm soil, biochar, compost
and weathered pine mulch to mitigate methane emissions. Applied Microbiology and Biotechnology. 2016; 100(21):9365–9379.
Rezaei F, Moussavi G, Riyahi Bakhtiari AR, Yamini Y. Toluene adsorption from waste air stream using activated carbon impregnated with manganese and magnesium metal oxides. Iranian Journal of Health & Environment. (2016); 8(4):491-508.
Gawande MB, Pandey RK, Jayaram RV. Role of mixed metal oxides in catalysis science-versatile applications in organic synthesis. Catalysis Science & Technology. 2012; 2(6):1113.
Rezaei E, Soltan J, Chen N. Catalytic oxidation of toluene by ozone over alumina supported manganese oxides: Effect of catalyst loading. Applied Catalysis B: Environmental. 2013; 136:239–247.
Wang HC, Liang HS, Chang MB. Chlorobenzene oxidation using ozone over iron oxide and manganese oxide catalysts. Journal of Hazardous Materials. 2011; 186(2–3):1781–1787.
Roohbakhsh Bidaei MR, Azadfallah M, Yarahmadi R. Adsorption of Rhodamine B dye with activated carbon prepared from beech wood. Iranian Journal of Wood and Paper Science Research. 2018; 33(2):280-289.
Nakagawa Y, Molina-Sabio M, Rodríguez-Reinoso F. Modification of the porous structure along the preparation of activated carbon monoliths with H3PO4 and ZnCl2. Microporous and Mesoporous Materials. 2007; 103(1–3):29–34.
Saroyan HS, Arampatzidou A, Voutsa D, Lazaridis NK, Deliyanni EA. Activated carbon supported MnO2 for catalytic degradation of reactive black 5. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2019; 566:166–175.
Rajahmundry GK, Garlapati C, Kumar PS, Alwi RS, Vo DVN. Statistical analysis of adsorption isotherm models and its appropriate selection. Chemosphere. 2021; 276:130176.
Jagtoyen M, Derbyshire F. Activated carbons from yellow poplar and white oak by H3PO4 activation. Carbon. 1998; 36(7–8):1085–1097.
Timur S, Cem Kantarli I, Ikizoglu E, Yanik J. Preparation of Activated Carbons from Oreganum Stalks by Chemical Activation. Energy & Fuels. 2006; 20(6):2636–2641.
Sharifi Darabad H, Adeli M. An investigation on the production of activated carbon from olive stone. Advanced Processes in Materials Engineering. 2018; 12(3):71-80.
Peoples CSL. 2019. Pesticide storage dissipation in surface water samples. In: Pesticides in Surface Water: Monitoring, Modeling, Risk Assessment, and Management. American Chemical Society; 2019. p. 89–100.
Ouznadji ZB, Sahmoune MN, Mezenner NY. Adsorptive removal of diazinon: kinetic and equilibrium study. Desalin. Water Treat. 2016; 57 (4):1880–1889.
Baharum NA, Nasir HM, Ishak MY, Isa NM, Hassan MA, Aris AZ. Highly efficient removal of diazinon pesticide from aqueous solutions by using coconut shell-modified biochar. Arabian Journal of Chemistry. 2020; 13(7):6106-6121.
Dehghani MH, Niasar ZS, Mehrnia MR, Shayeghi M, Al-Ghouti MA, Heibati B, et al. Optimizing the removal of organophosphorus pesticide Malathion from water using multi-walled carbon nanotubes. Chemical Engineering Journal. 2017; 310:22–32.
Ahmed MB, Zhou JL, Ngo HH, Guo W, Johir MAH, Sornalingam K. Single and competitive sorption properties and mechanism of functionalized biochar for removing sulfonamide antibiotics from water. Chemical Engineering Journal. 2017; 311:348–358.
Hassan AF, Elhadidy H, Abdel-Mohsen AM. Adsorption and photocatalytic detoxification of diazinon using iron and nanotitania modified activated carbons. Journal of the Taiwan Institute of Chemical Engineers. 2017; 75: 299–306.
Moussavi G, Hosseini H, Alahabadi A. The investigation of diazinon pesticide removal from contaminated water by adsorption onto NH4Cl-induced activated carbon. Chemical engineering journal. 2013; 214: 172-179.
_||_
Edwards CA. Environmental pollution by pesticides. Springer Science & Business Media; 2013.
Sergiusz P. Drought and water shortages in Asia as a threat and economic problem. Journal of modern science. 2015; 26(3):235-250.
ČOlović M, Krstić D, Petrović S, Leskovac A, Joksić G, Savić J, et al. Toxic effects of diazinon and its photodegradation products. Toxicology Letters. 2010; 193(1):9–18.
Rajasulochana P, Preethy V. Comparison on efficiency of various techniques in treatment of waste and sewage water - A comprehensive review. Resource-Efficient Technologies. 2016; 2(4):175–184.
González-García P. Activated carbon from lignocellulosics precursors: A review of the synthesis methods, characterization techniques and applications. Renewable and Sustainable Energy Reviews. 2018; 82: 1393–1414.
Salehian P, Karimi K. Alkali Pretreatment for Improvement of Biogas and Ethanol Production from Different Waste Parts of Pine Tree. Industrial & Engineering Chemistry Research. 2013; 52(2): 972–978.
Bhomick PC, Supong A, Baruah M, Pongener C, Sinha D. Pine Cone biomass as an efficient precursor for the synthesis of activated biocarbon for adsorption of anionic dye from aqueous solution: Isotherm, kinetic, thermodynamic and regeneration studies. Sustainable Chemistry and Pharmacy. 2018; 10:41–49.
Thakur RS, Katoch SS, Modi A. Assessment of pine cone derived activated carbon as an adsorbent in defluoridation. SN Applied Sciences. 2020; 2(8):1-12.
Syed R, Saggar S, Tate K, Rehm BHA. Assessment of farm soil, biochar, compost
and weathered pine mulch to mitigate methane emissions. Applied Microbiology and Biotechnology. 2016; 100(21):9365–9379.
Rezaei F, Moussavi G, Riyahi Bakhtiari AR, Yamini Y. Toluene adsorption from waste air stream using activated carbon impregnated with manganese and magnesium metal oxides. Iranian Journal of Health & Environment. (2016); 8(4):491-508.
Gawande MB, Pandey RK, Jayaram RV. Role of mixed metal oxides in catalysis science-versatile applications in organic synthesis. Catalysis Science & Technology. 2012; 2(6):1113.
Rezaei E, Soltan J, Chen N. Catalytic oxidation of toluene by ozone over alumina supported manganese oxides: Effect of catalyst loading. Applied Catalysis B: Environmental. 2013; 136:239–247.
Wang HC, Liang HS, Chang MB. Chlorobenzene oxidation using ozone over iron oxide and manganese oxide catalysts. Journal of Hazardous Materials. 2011; 186(2–3):1781–1787.
Roohbakhsh Bidaei MR, Azadfallah M, Yarahmadi R. Adsorption of Rhodamine B dye with activated carbon prepared from beech wood. Iranian Journal of Wood and Paper Science Research. 2018; 33(2):280-289.
Nakagawa Y, Molina-Sabio M, Rodríguez-Reinoso F. Modification of the porous structure along the preparation of activated carbon monoliths with H3PO4 and ZnCl2. Microporous and Mesoporous Materials. 2007; 103(1–3):29–34.
Saroyan HS, Arampatzidou A, Voutsa D, Lazaridis NK, Deliyanni EA. Activated carbon supported MnO2 for catalytic degradation of reactive black 5. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2019; 566:166–175.
Rajahmundry GK, Garlapati C, Kumar PS, Alwi RS, Vo DVN. Statistical analysis of adsorption isotherm models and its appropriate selection. Chemosphere. 2021; 276:130176.
Jagtoyen M, Derbyshire F. Activated carbons from yellow poplar and white oak by H3PO4 activation. Carbon. 1998; 36(7–8):1085–1097.
Timur S, Cem Kantarli I, Ikizoglu E, Yanik J. Preparation of Activated Carbons from Oreganum Stalks by Chemical Activation. Energy & Fuels. 2006; 20(6):2636–2641.
Sharifi Darabad H, Adeli M. An investigation on the production of activated carbon from olive stone. Advanced Processes in Materials Engineering. 2018; 12(3):71-80.
Peoples CSL. 2019. Pesticide storage dissipation in surface water samples. In: Pesticides in Surface Water: Monitoring, Modeling, Risk Assessment, and Management. American Chemical Society; 2019. p. 89–100.
Ouznadji ZB, Sahmoune MN, Mezenner NY. Adsorptive removal of diazinon: kinetic and equilibrium study. Desalin. Water Treat. 2016; 57 (4):1880–1889.
Baharum NA, Nasir HM, Ishak MY, Isa NM, Hassan MA, Aris AZ. Highly efficient removal of diazinon pesticide from aqueous solutions by using coconut shell-modified biochar. Arabian Journal of Chemistry. 2020; 13(7):6106-6121.
Dehghani MH, Niasar ZS, Mehrnia MR, Shayeghi M, Al-Ghouti MA, Heibati B, et al. Optimizing the removal of organophosphorus pesticide Malathion from water using multi-walled carbon nanotubes. Chemical Engineering Journal. 2017; 310:22–32.
Ahmed MB, Zhou JL, Ngo HH, Guo W, Johir MAH, Sornalingam K. Single and competitive sorption properties and mechanism of functionalized biochar for removing sulfonamide antibiotics from water. Chemical Engineering Journal. 2017; 311:348–358.
Hassan AF, Elhadidy H, Abdel-Mohsen AM. Adsorption and photocatalytic detoxification of diazinon using iron and nanotitania modified activated carbons. Journal of the Taiwan Institute of Chemical Engineers. 2017; 75: 299–306.
Moussavi G, Hosseini H, Alahabadi A. The investigation of diazinon pesticide removal from contaminated water by adsorption onto NH4Cl-induced activated carbon. Chemical engineering journal. 2013; 214: 172-179.
