بررسی عوامل موثر بر راندمان حذف آمون یوم در تصفیه خانه های فاضلاب با استفاده از فرایند زدایش توسط هوا

محورهای موضوعی : آلودگی محیط زیست (آب و فاضلاب)

آرزو زنگنه ¹ , سیما سبزعلیپور ² , افشین تکدستان ³ , رضا جلیل زاده ینگجه ⁴ , مرتضی خفائی ⁵

1 - دانشجوی دکتری گروه مهندسی محیط زیست، واحد اهواز، دانشگاه آزاد اسلامی، اهواز، ایران.
2 - استادیار گروه مهندسی محیط زیست، واحد اهواز، دانشگاه آزاد اسلامی، اهواز، ایران. *(مسوول مکاتبات)
3 - استاد مرکز تحقیقات فناوریهای زیست محیطی، دانشگاه علوم پزشکی جندی شاپور اهواز، اهواز، ایران.
4 - دانشیار گروه مهندسی محیط زیست، واحد اهواز، دانشگاه آزاد اسلامی، اهواز، ایران.
5 - دانشیار مرکز تحقیقات فناوریهای زیست محیطی، دانشگاه علوم پزشکی جندی شاپور اهواز، اهواز، ایران.

تاریخ دریافت : 1399/09/14 تاریخ پذیرش : 1399/10/06 تاریخ انتشار : 1401/08/01

کلید واژه: فاضلاب شهری, فرایند زدایش توسط هوا, آمونیوم,

چکیده مقاله :

زمینه و هدف: حذف آمونیوم از پساب ها درتصفیه خانه های فاضلاب به دلیل تأثیرات خطرناک و سمی آن بر سلامتی انسان و منابع بیوتیک ضروری است. هدف از انجام این مطالعه بررسی پارمترهای عملیاتی بر راندمان فرایند زدایش با هوا ، تعیین اولویت و درجه تاثیر آنها بر حذف آمونیوم و مقایسه راندمان حذف آمونیم طی فرایند زدایش توسط هوا در تصفیه خانه های فاضلاب شهری با استفاده از فاضلاب مصنوعی و واقعی بود. روش بررسی: در این مطالعه تاثیر هر یک از پارمترهای عملیاتی بر روی راندمان حذف آمونیوم شامل غلظت آمونیوم ورودی، pH و دما طی فرایند زدایش با هوا به ترتیب برای فاضلاب مصنوعی و واقعی، بر اساس روش های استاندارد (نسلریزاسیون و تهیه محلول های استاندارد) و با استفاده از اسپکتروفتومتر، pH سنج و ماژول دما بررسی شد. این مطالعه در بهمن ماه 1397 انجام پذیرفت. یافته ها: نتایج این مطالعه نشان داد که حداکثر راندمان حذف آمونیوم طی فرایند زدایش توسط هوا برای فاضلاب مصنوعی با نسبت هوا به آب 80 و غلظت آمونیوم ورودی 6/59 میلی گرم در لیتر ، pH 05/12و دمای 3/46 درجه سانتی گراد 91% است. همچنین نتایج مطالعه در زمینه بررسی راندمان حذف آمونیوم در تصفیه خانه های فاضلاب شهری نشان داد که راندمان حذف حداکثری 91% برای فاضلاب واقعی (پساب مخزن ته نشینی اولیه) با نسبت هوا به آب 80 و غلظت آمونیوم ورودی 04/61 میلی گرم در لیتر،pH 53/12و دمای 9/45 درجه است. بحث و نتیجه گیری: براساس نتایج مدل رگرسیون تک متغییره به ترتیب غلظت آمونیوم ورودی˂ دما ˂ pH بیشترین میزان تاثیر را بر راندمان حذف آمونیوم در فاضلاب مصنوعی و فاضلاب واقعی دارند. در مدل رگرسیون چند متغییره به ترتیب تاثیر دما وpH بر راندمان حذف آمونیوم در فاضلاب مصنوعی و فاضلاب واقعی افزایشی و کاهشی است. بر اساس یافته های این مطالعه، فرایند زدایش توسط هوا می تواند با موفقیت به منظور حذف آمونیوم از پساب تصفیه خانه های فاضلاب شهری به ویژه برای مناطق گرمسیری به کار رود.

چکیده انگلیسی:

Background and Objective: Removal of ammonia from wastewater in the treatment plants due to its dangerous and toxic effects on human health and biotic resources is essential. This study was aimed to investigate the effective operational parameters on the efficiency of the air stripping process, determine their priority and degree of effect on ammonia removal and compare the ammonia removal efficiency during the air stripping process in the municipal wastetewater treatment plants using synthetic and real wastewater. Material and Methodology: In this study, the effect of each operating parameter on the ammonia removal efficiency including initial ammonia concentration, pH and temperature during the air stripping process for synthetic and real wastewater, respectively, based on standard methods (the Nesslerization method, preparation of standard solutions) using a spectrophotometer, pH meter and temperature module were evaluated. Findings: The results of this study showed that the maximum of ARE for synthetic wastewater with Air to water ratio 80 and an initial ammonia concentration of 59. 6 mg /l, pH 12.05 and temperature 46.3°C was %91. Also, the results of the study on the ARE during the air stripping process showed that the maximum of ARE (%91) for real wastewater (primary sedimentation tank effluent (PST)) with Air to water ratio 80 and an initial ammonia concentration of 61.04 mg/l, pH 12.53 and temperature 45.9 ° C was obtained. Discussion and Conclusion: Based on the results of univariate regression model, initial ammonia concentration˃ temperature˃ pH have the greatest effect on the ammonia removal efficiency in synthetic wastewater and real wastewater, respectively. In the multivariate regression model, the effect of temperature and pH on the ammonia removal efficiency in synthetic and real wastewater is increasing and decreasing, respectively. Based on the findings of this study, the air stripping process can be successfully used to remove ammonia from wastewater in the municipal treatment plants, especially in the tropics.  

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