سنتز و بررسی خواص الکتروشیمیایی اکسید آنتروپی بالا (FeVCrMnNiZn)_3 O_4 به‌عنوان آند در باتری لیتیم-یون

محورهای موضوعی : روش ها و فرآیندهای نوین در تولید

محمدرضا اسماعیلی ¹ , فرزاد سلیمانی ²

1 - دانشجوی دکتری، دانشکده مهندسی و علم مواد، دانشگاه صنعتی شریف، تهران، ایران
2 - استادیار، دانشکده مهندسی متالورژی، دانشگاه پیام نور، تهران، ایران

تاریخ دریافت : 1403/06/18 تاریخ پذیرش : 1403/10/30 تاریخ انتشار : 1404/10/02

کلید واژه: باتری لیتیم- یون اکسید با آنتروپی بالا روش هیدروترمال ساختار اسپینل,

چکیده مقاله :

اکسیدهای با آنتروپی بالا با ترکیب فلزات واسطه (HEO-TM) به دلیل توانایی انجام واکنش‌های اکسایش-کاهش چند الکترونی، گزینه‌ای بالقوه برای استفاده به‌عنوان آند در باتری‌های لیتیوم-یونی معرفی شده‌اند. در این پژوهش، از روش هیدروترمال برای سنتز اکسید با آنتروپی بالای (FeVCrMnNiZn)₃O₄ استفاده شده است. در ادامه، نمونه سنتز شده در دمای 900 درجه‌ سانتی‌گراد کلسینه شده است. آنالیز XRD تشکیل ساختار تک‌فاز اسپینل را به خوبی نشان داده است. نتایج آزمون‌های الکتروشیمیایی ظرفیت اولیه 773 میلی‌آمپر ساعت بر گرم را ثبت کرده‌اند که پس از گذشت 200 چرخه در اثر واکنش‌های تبدیل به مقدار 1046 میلی‌آمپر ساعت بر گرم رسیده است. همچنین، آزمون قابلیت نرخ‌پذیری حاکی از بازیابی ساختاری فوق‌العاده این الکترود است. ضریب نفوذ یون لیتیوم در ساختار این ماده الکترودی از طریق طیف‌سنجی امپدانس الکترومغناطیسی محاسبه و مشخص شده است که با گذشت هر چرخه در اثر تثبیت لایه SEI ضریب نفوذ افزایش می‌یابد. به‌طوری‌که ضریب نفوذ یون لیتیوم از   05/1 در نمونه تازه به  37/13 در چرخه 200 رسیده است.

چکیده انگلیسی:

High-entropy oxides containing transition metals (HEO-TM) have been identified as promising anode materials for lithium-ion batteries, owing to their capacity for multi-electron redox reactions. In this study, the (FeVCrMnNiZn)₃O₄ high-entropy oxide was synthesized via a hydrothermal methodp, followed by calcination at 900°C. XRD analysis confirmed the successful formation of a single-phase spinel structure. Electrochemical performance tests revealed an initial capacity of 773 mAh/g, which increased to 1046 mAh/g after 200 cycles due to conversion reactions. Additionally, rate capability tests demonstrated exceptional structural recovery of this electrode. The lithium-ion diffusion coefficient in this electrode material was calculated using electrochemical impedance spectroscopy (EIS), showing an increase with each cycle due to the stabilization of the SEI layer. Specifically, the lithium-ion diffusion coefficient improved from 1.05 × 10⁻¹⁴ cm² s⁻¹ in the fresh sample to 13.37 × 10⁻¹⁴ cm² s⁻¹ after 200 cycles.

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