Optoelectronic Properties of PbS Films: Effect of Carrier Gas
محورهای موضوعی : فصلنامه نانوساختارهای اپتوالکترونیکی
1 - Young Researchers and Elite Club, Ahvaz Branch, Islamic Azad University,
Ahvaz, Iran
کلید واژه: Solar Cell, Lead sulfide (PbS), Thermal evaporation, Carrier gas, Optoelectronic properties,
چکیده مقاله :
In this study, lead sulfide (PbS) films were grown on Fluorine-doped Tin
Oxide (FTO) glass substrate by thermal evaporation in a horizontal furnace to
investigate carrier gas effect on structural, morphological, elemental, optical, electrical
and photovoltaic properties of PbS. X-ray diffraction (XRD) patterns confirmed the
formation of cubic polycrystalline PbS particles for all samples. The results showed that
using Ar+H2 as a carrier gas increased crystallite size of the film. Field emission
scanning electron microscopy (FESEM) images showed nano-dimension surface
morphologies and revealed that using carrier gas can make the obtained films and their
surface porosities more uniform and regular. Also, the elemental analysis demonstrates
that using mixed carrier gas provides a better stoichiometry for PbS film. Optical and
electrical evaluations indicated improvements in absorption intensity and electrical
conductivity of the PbS film when using the mixed carrier gas. Finally, the deposited
films were characterized as solar cells and their quality parameters (QP) were extracted
and presented. The obtained results illustrate the improvement in QPs of PbS solar cell
when using mixed carrier gas.
[1] H. Izadneshan, G. Solookinejad. Effect of Annealing on Physical Properties
of Cu2ZnSnS4 (CZTS) Thin Films for Solar Cell Applications. Journal of
Optoelectronical Nanostructures. 3 (2018) 19-28.
[2] F. Jamali-Sheini,M. Cheraghizade,F. Niknia, R. Yousefi. Enhanced
photovoltaic performance of tin sulfide nanoparticles by indium doping.
MRS Communications. 6 (2016) 421-8.
[3] A. Mirkamali, K. Muminov. The Effect of Change the Thickness on
CdS/CdTe Tandem Multi-Junction Solar Cells Efficiency. Journal of
Optoelectronical Nanostructures. 2 (2017) 13-24.
[4] S. M. S. Hashemi Nassab,M. Imanieh, A. Kamaly. The Effect of Doping and
the Thickness of the Layers on CIGS Solar Cell Efficiency. Journal of
Optoelectronical Nanostructures. 1 (2016) 9-24.
[5] J. J. Loferski. Theoretical Considerations Governing the Choice of the
Optimum Semiconductor for Photovoltaic Solar Energy Conversion. Journal
of Applied Physics. 27 (1956) 777-84.
[6] W. Shockley, H. J. Queisser. Detailed Balance Limit of Efficiency of p‐n
Junction Solar Cells. Journal of Applied Physics. 32 (1961) 510-9.
[7] P. Würfel. Physics of Solar Cells: From Principles to New Concepts. Wiley,
2008.
[8] A. S. Obaid,M. A. Mahdi,Z. Hassan, M. Bououdina. Preparation of
chemically deposited thin films of CdS/PbS solar cell. Superlattices and
Microstructures. 52 (2012) 816-23.
[9] J. M. Luther,J. Gao,M. T. Lloyd,O. E. Semonin,M. C. Beard, A. J. Nozik.
Stability Assessment on a 3% Bilayer PbS/ZnO Quantum Dot
Heterojunction Solar Cell. Advanced Materials. 22 (2010) 3704-7.
[10] M. Cheraghizade,R. Yousefi, F. Jamali-Sheini. Substrate Temperature
Effect on Photovoltaic Performance of Lead Sulfide (PbS) Nanostructures
Deposited by Chemical Vapor Deposition (CVD) method. Majlesi Journal
of Telecommunication Devices. 5 (2016)
[11] C. Justin Raj,S. N. Karthick,S. Park,K. V. Hemalatha,S.-K. Kim,K.
Prabakar, et al. Improved photovoltaic performance of CdSe/CdS/PbS
quantum dot sensitized ZnO nanorod array solar cell. Journal of Power
Sources. 248 (2014) 439-46.
[12] M. Cheragizade,R. Yousefi,F. Jamali-Sheini,M. R. Mahmoudian,A.
Sa΄aedi, N. Ming Huang. Synthesis and characterization of PbS
mesostructures as an IR detector grown by hydrogen-assisted thermal
evaporation. Materials Science in Semiconductor Processing. 26 (2014)
704-9.
[13] R. Yousefi,M. Cheraghizade,F. Jamali-Sheini,W. J. Basirun, N. M. Huang.
Effect of hydrogen gas on the growth process of PbS nanorods grown by a
CVD method. Current Applied Physics. 14 (2014) 1031-5.
[14] M. J. Bierman,Y. K. A. Lau, S. Jin. Hyperbranched PbS and PbSe
Nanowires and the Effect of Hydrogen Gas on Their Synthesis. Nano
Letters. 7 (2007) 2907-12.
[15] M. Cheragizade,R. Yousefi,F. Jamali-Sheini,M. R. Mahmoudian,A.
Sa΄aedi, N. Ming Huang. Synthesis and characterization of PbS
mesostructures as an IR detector grown by hydrogen-assisted thermal
evaporation. Materials Science in Semiconductor Processing. 26 (2014)
704-9.
[16] P. D. F. ICDD. International Centre for Diffraction Data. Powder
Diffraction File, Newtown Square, Pennsylvania, USA. (1997)
[17] B. D. Cullity. Elements of X-Ray Diffraction. American Journal of Physics.
25 (1957) 394-5.
[18] F. Jamali-Sheini,R. Yousefi,N. Ali Bakr,M. Cheraghizade,M. Sookhakian,
N. M. Huang. Highly efficient photo-degradation of methyl blue and band
gap shift of SnS nanoparticles under different sonication frequencies.
Materials Science in Semiconductor Processing. 32 (2015) 172-8.
[19] Z. Dehghani Tafti,M. Borhani Zarandi, H. Amrollahi Bioki. Thermal
Annealing Influence over Optical Properties of Thermally Evaporated
SnS/CdS Bilayer Thin Films. Journal of Optoelectronical Nanostructures. 4
(2019) 87-98.
[20] J. He,H. Lindström,A. Hagfeldt, S.-E. Lindquist. Dye-Sensitized
Nanostructured p-Type Nickel Oxide Film as a Photocathode for a Solar
Cell. The Journal of Physical Chemistry B. 103 (1999) 8940-3.
[21] F. Jamali-Sheini,F. Niknia,M. Cheraghizade,R. Yousefi, M. R.
Mahmoudian. Broad Spectral Response of Se-Doped SnS Nanorods
Synthesized through Electrodeposition. ChemElectroChem. 4 (2017) 1478-
86.
[22] M. Cheraghizade,F. Jamali-Sheini, R. Yousefi. Optical, electrical, and
photovoltaic properties of PbS thin films by anionic and cationic dopants.
Applied Physics A. 123 (2017) 390.
[23] M. A. Barote,A. A. Yadav, E. U. Masumdar. Synthesis, characterization
and photoelectrochemical properties of n-CdS thin films. Physica B:
Condensed Matter. 406 (2011) 1865-71.
[24] H. Christiana, B. Stuart. PVeducation.
[25] S. M. Sze, K. K. Ng. Physics of Semiconductor Devices. Wiley, 2006.
[26] M. Shirkavand,M. Bavir,A. Fattah,H. R. Alaei, M. H. Tayarani Najaran.
The Construction and Comparison of Dye-Sensitized Solar Cells with
Blackberry and N719 Dyes. Journal of Optoelectronical Nanostructures. 3
(2018) 79-92.