Fabrication Of Cu(In,Ga)Se2 Solar Cells With In2S3 Buffer Layer By Two Stage Process
محورهای موضوعی : فصلنامه نانوساختارهای اپتوالکترونیکیHeydar Izadneshan 1 , Valery Gremenok 2 , Ghahraman Solookinejad 3
1 - Department of physics, Marvdasht Branch, Islamic Azad University, Marvdasht, Iran.
2 - Scientific-Practical Materials Research Centre of National Academy of Sciences of Belarus, Minsk.
3 - Department of physics, Marvdasht Branch, Islamic Azad University, Marvdasht, Iran
کلید واژه: morphology, Solar Cell, Cu(In, Ga)Se2, optical property, In2S3, buffer layer,
چکیده مقاله :
Cu(In,Ga)Se2 thin films (CIGS) on metallic substrate (titanium, molybdenum, aluminum, stainless steel) were prepared by a two-step selenization of Co-evaporated metallic precursors in Se-containing environment under N2 gas flow. Structural properties of prepared thin film were studied. To characterize the optical quality and intrinsic defect nature low-temperature photoluminescence, were performed. Results shows that the structural and optical properties of Cu(In,Ga)Se2 thin films strongly depend on the growth condition, charactristics of substrate and chemical composition. In2S3 thin layer has been used as buffer layer in CIGS solar cells and physical properties of them investigated. Solar cells were completed by vacuum deposition of ZnO/ZnO:Al layers and Ni/Al contact fingers. The surface morphology and bulk composition of thin films were investigated by scanning electron microscopy (SEM) equipped with energy-dispersive X-ray spectroscopy (EDS). The optical testing was carried out by recording transmittance spectra of the samples by spectrophotometers in the spectral range 190–3000 nm at a resolution of 1 nm. The better conversion efficiencies were around 12.0 %.
[1] S. Bailey, D. Flood, Space photovoltaics, Progress in Photovoltaics, 6 (1998) 1-14.
[2] A. Romeo, M. Terheggen, Development of Thin-film Cu(In,Ga)Se2 and CdTe Solar Cells, Prog. Photovolt: Res. Appl. 12(2004) 93–111.
[3] T. M. Razykov, Solar photovoltaic electricity: Current status and future prospects, Solar Energy, 85 (2011) 1580-1608.
[4] M. A. Green, K. Emyry, Y. Hishikawa, W. Warta, Solar cell efficiency tables, Progress in Photovoltaics, 42 (2013) 827–837.
[5] F. Kessler, D. Rudmann, Technological aspects of flexible CIGS solar cells and modules, Solar Energy, 77 (2004)685- 695.
[6] K. Otte, L. Makhova, A. Braun, I. Konovalov, Flexible Cu(In,Ga)Se2 thin-film solar cells for space application, Thin Solid Films, 511 (2006) 613-622.
[7] H. Izadneshan, V. F. Gremenok, Influence of Annealing on the Optical Parameters of In2S3 Thin Films Produced by Thermal Evaporation, Journal of Applied Spectroscopy, 81 (2014) 293–296.
[8] E. P. Zaretskaya, V. F. Gremenok, I. A. Victorov, Properties of CuInSe2 Polycrystalline Thin Films Prepared by Selenization of Co-Sputtered Cu-In Alloys. Solid State Phenomena, 80 (2001) 287-292.
[9] M. V. Yakushev, A. V. Mudryi, V. F. Gremenok, E. P. Zaretskaya, V. B. Zalesski, Y. Feofanov, R. W. Martin, Influence of growth conditions on the structural quality of Cu(InGa)Se2 and CuInSe2 thin films, Thin Solid Films, 451 (2004) 133-136.
[10] B. I. Shklovskii, A. L. Efros, Electronic Properties of Doped Semiconductors, Springer Verlag, Berlin. (1984), 124.
[11] I. Dirnstorfer, M. Wagner, D. M. Hofmann, M. D. Lampert, F. Karg, B. K. Meyer, Characterization of CuIn(Ga)Se2 Thin Films, Physics Status Solidi (a), 168 (1998), 163-175.
[12] J. Krustok, H. Collan, M. Yakushev, K. Hjelt, The role of spatial potential fluctuations in the shape of the PL bands of multinary semiconductor compounds, Physica Scripta, T79 (1999) 179-182.
[13] P. Pistor, R. Caballero, D. Hariskos, V. Izquierdo-Roca Wächter, Quality and stability of compound indium sulphide as source material for buffer layers in Cu(In,Ga)Se2 solar cells, Solar Energy Materials and Solar Cells, 93( 2009) 148-152.
[14] H. Dittrich, A. Bieniok, U. Brendel, M. Grodzicki, A new class of compound semiconductors for photovoltaic applications, Thin Solid Films, 515 (2007) 5745-5750.
[15] D. Rudmann, M. Kaelin, F. J. Haug, Effects of NaF coevaporation on structural properties of Cu(In,Ga)Se2 thin film, Thin Solid Films, 431 (2003) 37-40.
[16] D. Rudmann, A. F. Cunha, M. Kaelin, F. Kurdesau, Efficiency Enhancement of Cu(In,Ga)Se2 Solar Cells Fabricated on Flexible Polyimide Substrates using Alkali-Silicate Glass Thin Layers, Applied Physics Letter, 84 (2004) 1129-1131.