Investigation of Wear Resistance and Corrosion of Ni-P-PTFE Composite Coatings Prepared by Electrodeposition Method
محورهای موضوعی : Composite materials
1 - College of Materials Engineering, University of Babylon, Babylon, Iraq.
کلید واژه: Electrodeposition, Composite Coatings, PTFE, Wear, Corrosion, EIS.,
چکیده مقاله :
Coating is one of the effective ways to increase the corrosion resistance and wear of metallic substrates. Additionally, the composite coatings using nanoparticles can also further protect the substrate. In this study, using electrodeposition process and polytetrafluoroethylene (PTFE) particles (with concentrations of 10, 20 or 30 g /L), Ni- PTFE coatings were prepared and their corrosion and wear properties were investigated and compared with Ni-P coating. Using scanning electron microscopy (SEM) and X-ray diffraction (EDS) method, the surface morphology and elemental composition of the coatings were analyzed and finally, by using open circuit potential (OCP) techniques, electrochemical impedance spectroscopy (EIS) and TAFEL polarization techniques, the corrosion resistance of the resulting coatings in 3/5 wt.% NaCl solution were evaluated. Microhardness and pin on disk tests were also utilized to investigate the effect of PTFE concentration on the tribological properties of the coatings. The results of SEM and EDS studies confirmed the formation of nanocomposites. Electrochemical studies also showed that Ni-PTFE coatings, at a concentration of 20 g/L PTFE, had the highest electrochemical corrosion resistance. Microhardness also decreased with increasing PTFE particles in the coating and reached its lowest value. By using the wear test, the lowest coefficient of friction obtained in composite coatings with concentration of 20 g/L, which shows the applicability of PTFE particles as a solid lubricant in Ni-P coatings.
Coating is one of the effective ways to increase the corrosion resistance and wear of metallic substrates. Additionally, the composite coatings using nanoparticles can also further protect the substrate. In this study, using electrodeposition process and polytetrafluoroethylene (PTFE) particles (with concentrations of 10, 20 or 30 g /L), Ni- PTFE coatings were prepared and their corrosion and wear properties were investigated and compared with Ni-P coating. Using scanning electron microscopy (SEM) and X-ray diffraction (EDS) method, the surface morphology and elemental composition of the coatings were analyzed and finally, by using open circuit potential (OCP) techniques, electrochemical impedance spectroscopy (EIS) and TAFEL polarization techniques, the corrosion resistance of the resulting coatings in 3/5 wt.% NaCl solution were evaluated. Microhardness and pin on disk tests were also utilized to investigate the effect of PTFE concentration on the tribological properties of the coatings. The results of SEM and EDS studies confirmed the formation of nanocomposites. Electrochemical studies also showed that Ni-PTFE coatings, at a concentration of 20 g/L PTFE, had the highest electrochemical corrosion resistance. Microhardness also decreased with increasing PTFE particles in the coating and reached its lowest value. By using the wear test, the lowest coefficient of friction obtained in composite coatings with concentration of 20 g/L, which shows the applicability of PTFE particles as a solid lubricant in Ni-P coatings.
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