Simulation of chromium, nickel and lead removal from aqueous environment using polypyrrol and its composites
محورهای موضوعی : فصلنامه شبیه سازی و تحلیل تکنولوژی های نوین در مهندسی مکانیکArash Shabani 1 , Majid Riahi Samani 2 , Davood Toghraie 3
1 - 1Department of Civil Engineering, Khomeinishahr Branch, Islamic Azad University, Khomeinishahr, Isfahan,Iran
2 - Department of Mechanical and Civil Engineering, khomeinishahr Branch, Islamic Azad University , Khomeinishahr , Isfahan, Iran
3 - Department of Mechanical Engineering, Khomeinishahr Branch, Islamic Azad University, Khomeinishahr , Isfahan, Iran
کلید واژه: Heavy metals, Removal simulation, Polypyrrol, Composite, Aqueous environment,
چکیده مقاله :
In the present study, removal of chromium, lead and nickel by using polypyrrol and its composites from the aqueous environment were simulated. In order to prepare polypyrrol and its composites, iron chloride oxidant with 8 g, water solvents, acetonitrile and ethyl acetate were used in the presence of two additives, polyvinyl alcohol and polyethylene glycol at concentrations of 1.5 and 2. Batch quarantine method was used to measure the removal of these metals from the aqueous environment. The simulated results showed that all polypyrrols and their composites are suitable for the removal of +6 chromium. The highest adsorption of total chromium and +6 chromium was observed by polypyrrol and polyethylene glycol composites with 90.7% and 96.2%, respectively. However, polypyrrol and its composites are undesirable for removal of lead, cadmium and nickel. The highest removal rates of lead and cadmium by activated carbon powder were 99.5% and 78.08%, respectively. Also, the percentage of nickel removal by some polypyrrols was lower than activated carbon with 14.96% removal. Some polypyrrols also have a higher percentage of knockout than activated carbon, which does not seem very high in comparison with other heavy metals. In general, it can be found that the use of polypyrrol composites, especially polypyrrol and polyethylene glycol composites, are suitable for the removal of total chromium and +6 chromium from the aqueous environment, but are undesirable for the removal of lead and nickel.
In the present study, removal of chromium, lead and nickel by using polypyrrol and its composites from the aqueous environment were simulated. In order to prepare polypyrrol and its composites, iron chloride oxidant with 8 g, water solvents, acetonitrile and ethyl acetate were used in the presence of two additives, polyvinyl alcohol and polyethylene glycol at concentrations of 1.5 and 2. Batch quarantine method was used to measure the removal of these metals from the aqueous environment. The simulated results showed that all polypyrrols and their composites are suitable for the removal of +6 chromium. The highest adsorption of total chromium and +6 chromium was observed by polypyrrol and polyethylene glycol composites with 90.7% and 96.2%, respectively. However, polypyrrol and its composites are undesirable for removal of lead, cadmium and nickel. The highest removal rates of lead and cadmium by activated carbon powder were 99.5% and 78.08%, respectively. Also, the percentage of nickel removal by some polypyrrols was lower than activated carbon with 14.96% removal. Some polypyrrols also have a higher percentage of knockout than activated carbon, which does not seem very high in comparison with other heavy metals. In general, it can be found that the use of polypyrrol composites, especially polypyrrol and polyethylene glycol composites, are suitable for the removal of total chromium and +6 chromium from the aqueous environment, but are undesirable for the removal of lead and nickel.
[1] Zamora-Ledezma, C., Negrete-Bolagay, D., Figueroa, F., Zamora-Ledezma, E., Ni, M., Alexis, F., & Guerrero, V. H. (2021). Heavy metal water pollution: A fresh look about hazards, novel and conventional remediation methods. Environmental Technology & Innovation, 101504.
[2] Jinisha, R., Gandhimathi, R., Ramesh, S. T., Nidheesh, P. V., & Velmathi, S. (2018). Removal of rhodamine B dye from aqueous solution by electro-Fenton process using iron-doped mesoporous silica as a heterogeneous catalyst. Chemosphere, 200, 446-454.
[3] Mousa, S. M., Ammar, N. S., & Ibrahim, H. A. (2016). Removal of lead ions using hydroxyapatite nano-material prepared from phosphogypsum waste. Journal of Saudi Chemical Society, 20(3), 357-365.
[4] Chen, Z., & Pan, K. (2021). Enhanced removal of Cr (VI) via in-situ synergistic reduction and fixation by polypyrrole/sugarcane bagasse composites. Chemosphere, 272, 129606.
[5] Mekonnen, M. M., & Hoekstra, A. Y. (2018). Global anthropogenic phosphorus loads to freshwater and associated grey water footprints and water pollution levels: A high‐resolution global study. Water resources research, 54(1), 345-358.
[6] Maity, S., Dubey, A., & Chakraborty, S. (2019). A review on polypyrrole-coated bio-composites for the removal of heavy metal traces from waste water. Journal of Industrial Textiles, 1528083719871272.
[7] Azimi, A., Azari, A., Rezakazemi, M., & Ansarpour, M. (2017). Removal of heavy metals from industrial wastewaters: a review. ChemBioEng Rev 4: 37–59.
[8] Maity, S., Dubey, A., & Chakraborty, S. (2019). A review on polypyrrole-coated bio-composites for the removal of heavy metal traces from waste water. Journal of Industrial Textiles, 1528083719871272.
[9] Kong, J., Gu, R., Yuan, J., Liu, W., Wu, J., Fei, Z., & Yue, Q. (2018). Adsorption behavior of Ni (II) onto activated carbons from hide waste and high-pressure steaming hide waste. Ecotoxicology and environmental safety, 156, 294-300.
[10] Xiangxue, W. A. N. G., Xing, L., Jiaqi, W. A. N. G., & Hongtao, Z. H. U. (2021). Recent advances in carbon nitride-based nanomaterials for the removal of heavy metal ions from aqueous solution. Journal of Inorganic Materials, 35(3), 260-270.
[11] Pang, H., Wu, Y., Wang, X., Hu, B., & Wang, X. (2019). Recent advances in composites of graphene and layered double hydroxides for water remediation: a review. Chemistry–An Asian Journal, 14(15), 2542-2552.
[12] Chen, Z., Zhang, S., Liu, Y., Alharbi, N. S., Rabah, S. O., Wang, S., & Wang, X. (2020). Synthesis and fabrication of g-C3N4-based materials and their application in elimination of pollutants. Science of The Total Environment, 731, 139054.
[13] Rohanifar, A., Rodriguez, L. B., Devasurendra, A. M., Alipourasiabi, N., Anderson, J. L., & Kirchhoff, J. R. (2018). Solid-phase microextraction of heavy metals in natural water with a polypyrrole/carbon nanotube/1, 10–phenanthroline composite sorbent material. Talanta, 188, 570-577.
[14] Waijarean, N., MacKenzie, K. J., Asavapisit, S., Piyaphanuwat, R., & Jameson, G. N. (2017). Synthesis and properties of geopolymers based on water treatment residue and their immobilization of some heavy metals. Journal of Materials Science, 52(12), 7345-7359.
[15] Samuel, M. S., Shah, S. S., Bhattacharya, J., Subramaniam, K., & Singh, N. P. (2018). Adsorption of Pb (II) from aqueous solution using a magnetic chitosan/graphene oxide composite and its toxicity studies. International journal of biological macromolecules, 115, 1142-1150.
[16] Alawa, B., Srivstava, J., Srivastava, A., & Palsania, J. (2015). Adsorption of heavy metal Pb (II) from synthetic waste water by polypyrrole composites. Int. J. Chem. Stud, 3, 04-08.
[17] Ajmani, A., Shahnaz, T., Narayanan, S., & Narayanasamy, S. (2019). Equilibrium, kinetics and thermodynamics of hexavalent chromium biosorption on pristine and zinc chloride activated Senna siamea seed pods. Chemistry and Ecology, 35(4), 379-396.
[18] Shahnaz, T., Padmanaban, V. C., & Narayanasamy, S. (2020). Surface modification of nanocellulose using polypyrrole for the adsorptive removal of Congo red dye and chromium in binary mixture. International journal of biological macromolecules, 151, 322-332.
[19] Aigbe, U. O., Das, R., Ho, W. H., Srinivasu, V., & Maity, A. (2018). A novel method for removal of Cr (VI) using polypyrrole magnetic nanocomposite in the presence of unsteady magnetic fields. Separation and Purification Technology, 194, 377-387.
[20] Najafabadi, H. H., Irani, M., Rad, L. R., Haratameh, A. H., & Haririan, I. (2015). Correction: Removal of Cu2+, Pb2+ and Cr6+ from aqueous solutions using a chitosan/graphene oxide composite nanofibrous adsorbent. Rsc Advances, 5(29), 22390-22390.
[21] He, Y., Wu, P., Xiao, W., Li, G., Yi, J., He, Y. & Duan, Y. (2019). Efficient removal of Pb (II) from aqueous solution by a novel ion imprinted magnetic biosorbent: Adsorption kinetics and mechanisms. PLoS One, 14(3), e0213377.
[22] Chávez-Guajardo, A. E., Medina-Llamas, J. C., Maqueira, L., Andrade, C. A., Alves, K. G., & de Melo, C. P. (2015). Efficient removal of Cr (VI) and Cu (II) ions from aqueous media by use of polypyrrole/maghemite and polyaniline/maghemite magnetic nanocomposites. Chemical Engineering Journal, 281, 826-836.
[23] Ajmani, A., Shahnaz, T., Narayanan, S., & Narayanasamy, S. (2019). Equilibrium, kinetics and thermodynamics of hexavalent chromium biosorption on pristine and zinc chloride activated Senna siamea seed pods. Chemistry and Ecology, 35(4), 379-396.
[24] Dubal, D. P., Patil, S. V., Gund, G. S., & Lokhande, C. D. (2013). Polyaniline–polypyrrole nanograined composite via electrostatic adsorption for high performance electrochemical supercapacitors. Journal of alloys and compounds, 552, 240-247.
[25] Xu, Y., Chen, J., Chen, R., Yu, P., Guo, S., & Wang, X. (2019). Adsorption and reduction of chromium (VI) from aqueous solution using polypyrrole/calcium rectorite composite adsorbent. Water research, 160, 148-157.
[26] Xie, L., Yu, Z., Islam, S. M., Shi, K., Cheng, Y., Yuan, M., ... & Kanatzidis, M. G. (2018). Remarkable Acid Stability of Polypyrrole‐MoS4: A Highly Selective and Efficient Scavenger of Heavy Metals Over a Wide pH Range. Advanced Functional Materials, 28(20), 1800502.
[27] Shyam Sunder, G. S., Rohanifar, A., Alipourasiabi, N., Lawrence, J. G., & Kirchhoff, J. R. (2021). Synthesis and Characterization of Poly (pyrrole-1-carboxylic acid) for Preconcentration and Determination of Rare Earth Elements and Heavy Metals in Water Matrices. ACS Applied Materials & Interfaces, 13(29), 34782-34792.
[28] Wang, H., Yuan, X., Wu, Y., Chen, X., Leng, L., Wang, H., ... & Zeng, G. (2015). Facile synthesis of polypyrrole decorated reduced graphene oxide–Fe3O4 magnetic composites and its application for the Cr (VI) removal. Chemical Engineering Journal, 262, 597-606.
[29] Zhang, Y., Duan, Y., Liu, J., Ma, G., & Huang, M. (2018). Wormlike acid-doped polyaniline: controllable electrical properties and theoretical investigation. The Journal of Physical Chemistry C, 122(4), 2032-2040.
[30] Birniwa, A. H., Abubakar, A. S., Huq, A. O., & Mahmud, H. N. M. E. (2021). Polypyrrole-polyethyleneimine (PPy-PEI) nanocomposite: an effective adsorbent for nickel ion adsorption from aqueous solution. Journal of Macromolecular Science, Part A, 58(3), 206-217.
[31] Rafiaee, S., Samani, M. R., & Toghraie, D. (2020). Removal of hexavalent chromium from aqueous media using pomegranate peels modified by polymeric coatings: effects of various composite synthesis parameters. Synthetic Metals, 265, 116416.
[32] Zhang, Y., Xue, Q., Li, F., & Dai, J. (2019). Removal of heavy metal ions from wastewater by capacitive deionization using polypyrrole/chitosan composite electrode. Adsorption Science & Technology, 37(3-4), 205-216.
[33] Chen, Z., & Pan, K. (2021). Enhanced removal of Cr (VI) via in-situ synergistic reduction and fixation by polypyrrole/sugarcane bagasse composites. Chemosphere, 272, 129606.
[34] Hızal, J., & Yılmazoğlu, M. (2021). Montmorillonite clay composite for heavy metal removal from water. In Green Adsorbents to Remove Metals, Dyes and Boron from Polluted Water (pp. 93-112). Springer, Cham.
[35] Xiang, L., Niu, C. G., Tang, N., Lv, X. X., Guo, H., Li, Z. W., ... & Liang, C. (2021). Polypyrrole coated molybdenum disulfide composites as adsorbent for enhanced removal of Cr (VI) in aqueous solutions by adsorption combined with reduction. Chemical Engineering Journal, 408, 127281.
[36] Sahu, S., Kar, P., Bishoyi, N., Mallik, L., & Patel, R. K. (2019). Synthesis of polypyrrole-modified layered double hydroxides for efficient removal of Cr (VI). Journal of Chemical & Engineering Data, 64(10), 4357-4368.
[37] Guo, R., Guo, W., Pei, H., Wang, B., Guo, X., Liu, N., & Mo, Z. (2021). Polypyrrole deposited electrospun PAN/PEI nanofiber membrane designed for high efficient adsorption of chromium ions (VI) in aqueous solution. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 627, 127183.
[38] Sarojini, G., Venkateshbabu, S., & Rajasimman, M. (2021). Facile synthesis and characterization of polypyrrole-iron oxide–seaweed (PPy-Fe3O4-SW) nanocomposite and its exploration for adsorptive removal of Pb (II) from heavy metal bearing water. Chemosphere, 278, 130400.
[39] Nyairo, W. N., Eker, Y. R., Kowenje, C., Akin, I., Bingol, H., Tor, A., & Ongeri, D. M. (2018). Efficient adsorption of lead (II) and copper (II) from aqueous phase using oxidized multiwalled carbon nanotubes/polypyrrole composite. Separation Science and Technology, 53(10), 1498-1510.
[40] Joshi, N. C., Malik, S., & Gururani, P. (2020). Utilization of Polypyrrole/ZnO Nanocomposite in the Adsorptive Removal of Cu2+, Pb2+ and Cd2+ ions from wastewater.
[41] Sall, M. L., Diaw, A. K. D., Gningue-Sall, D., Chevillot-Biraud, A., Oturan, N., Oturan, M. A., & Aaron, J. J. (2018). Removal of lead and cadmium from aqueous solutions by using 4-amino-3-hydroxynaphthalene sulfonic acid-doped polypyrrole films. Environmental Science and Pollution Research, 25(9), 8581-8591.
