Extraction and Determination of Trace Copper (II) Using Octadecyl Silica Membrane Disks Modified 1-(2-Pyridyl Azo) 2-Naphtol(Pan) in Water Samples and Paraffin-Embedded Tissues from Liver Loggerhead Turtles Specimens by FAAS

محورهای موضوعی :

A. Moghimi ¹ , M. Shabanzadeh ²

1 - Department of Chemistry, Varamin (Pishva) Branch , Islamic Azad University, Varamin, Iran
2 - 2Department of Chemistry, Damghan Branch, Islamic Azad University, Damghan, Iran

تاریخ دریافت : 1391/04/22 تاریخ پذیرش : 1397/08/07 تاریخ انتشار : 1391/03/12

کلید واژه: SPE, Copper (II), Octadecyl slica disks, AAS, 1-(2-Pyridyl Azo) 2-Naphtol (PAN) Formalin-fixed paraffin-embedded (FFPE),

چکیده مقاله :

A simple and reproducible method for the rapid extraction and determination of trace amounts of copper(II) ions using octadecyl-bonded silica membrane disks modified by 1-(2-Pyridyl Azo)2-Naphtol(PAN)and Atomic Absorption Spectrometry was presented. The method was based on complex formation on the surface of the ENVI-18 DISKTM disks followed by stripping of the retained species by minimum amounts of appropriate organic solvents. The elution was efficient and quantitative. The effect of potential interfering ions, pH, ligand amount, stripping solvent, and sample flow rate were also investigated. Under the optimal experimental conditions, the break-through volume was found to about 1000mL providing a preconcentration factor of 500. In the present study, we reported the application of preconcentration techniques still continues increasingly for trace metal determinations by flame atomic absorption spectrometry (FAAS) for quantification of Cu in Formalin-fixed paraffin-embedded (FFPE) tissues from Liver loggerhead turtles. The maximum capacity of the disks was found to be 389± 4 µg for Cu2+.The limit of detection of the proposed method was 5ng per 1000mL.The method was applied to the extraction and recovery of copper in different water samples.

منابع و مأخذ:

1. H.J.M.Bowen.1979 .Enviromental Chemistery
2. of the Elements, Academic Press, New York,
3. -135 .
4. L.E.Brand, W.G. Sunda,R.R.L. Guillard.1986
5. J.Exp.Mar.Biol.Ecol.96:225.
6. H.H. Taylor, J.M.Anstiss.1999, Mar. Freshwat.
7. Res.50:907.
8. F.M.M.Morel, R.J.M. Hudson, N.M.Price,
9. Limnol.Oceanogr.36:1742.
10. A.S.Gordan, 1992 Mar.Chem.38:1.
11. J.W.Moffett, L.E.Brand, P.L. Croot,
12. K.A.Barbeau1997 ,Limnol.Oceanoger. 42:789.
13. P.L.Croot,J.W.Moffett, L.E.Brand,2000
14. Limnol.Oceanogr.45:619.
15. M.Wood, H.K.Wang, 1983
16. Environ.Sci.Technol.17:582A.
17. N.N.Greemwood, A.Eamshow, 1984
18. Chemistery of Elements, Pergamon Press, New
19. York.
20. C.A.Burtis, E.R.Ashwood,Tiets 1999 Textbook
21. of Clinical Chemistery, third ed.,
22. Macmillan,New York.
23. B. Wetz, 1985 Atomic Absorption
24. Spectroscopy, VCH, Amsterdam.
25. A.D.Eaton, L.S.Clesceri, A.E.Greenberg, 1995
26. Standard Methods for the examination of water
27. and waste water ,19 th ed ,American Public
28. Health Association, Washington,DC .
29. F.J.Welcher, E.Boschmann, 1979 Organic
30. Reagents for Copper, Krieger Huntington, New
31. York.
32. Z.Marczenko, 1986 Separation and
33. Spectrophotometric Determination of
34. Elements,Ellis Horwood, London.
35. O.P.Bharagava, 1969 Talanta 16:743.
36. A.A. Schilt, W.C. Hoyle, 1964Anal. Chem.
37. :344.
38. L.G.Borchart, J.P. Butler, 1957 Anal. Chem.
39. :414.
40. R. Chaisuksant, W.P. Ayuthaya, K. Grudpan,
41. Talanta 53:579.
42. D. Kara, M. Alkan, 2002 Microchem. J. 71: 29.
43. K.Saito, S.Murakami, A. Muromatsu,
44. E.Sekido, 1994 Anal.Chim. Acta 294:329.
45. K. Ikeda, S. Abe, 1998 Anl.Chim. Acta 363:
47. S. Igarashi, N. Ide, Y.Takagai, 2000
48. Anal.Chim. Acta 424:263.
49. J. Liu, W.Wang, G. Li, 2001Talanta 53:1149.
50. A.N.Anthemidis, G.A. Zachariadis, J.A. Stratis,
51. Talanta 54:935.
52. D. Zenedelovska, G. Pavlovska, K. Cundeva,
53. T.Stafilov, 2001 Talanta 54:139.
54. M.Endo, K.Suziki, S.Abe, 1998 Anal. Chim.
55. Acta 364:13.
56. M.E. Campderros, A. Acosta, J. Marchese,
57. Talanta 47:19.
58. I.Narin, M. Soylak, L.Elic, M.Dogan, 2000
59. Talanta 52:1041.
60. Y.Akama, M.Ito, S.Tanaka, 2000 Talanta
61. :645.
62. K.Ohta, H.Tanahasi, T. Suzuki, S.Kaneco,
63. , Talanta 53:715.
64. V.Cuculic, M.Mlakar, M.Branica, Anal. Chim.
65. Acta 339:(1997)181.
66. A.Moghimi, M.S.Tehrani, S.Waqif Husain,
67. Material Science Research India 3(1a)
68. :27.
69. M.S.Tehrani, A.Moghimi, S.Waqif Husain,
70. Material Science Research India 3(2)
71. :135.
72. E.M.Thurman,M.S.Mills, 1998 Solid-Phase
73. Extraction, Principles and Practice, Wiley, New
74. York.
75. J.Pawliszyn, 1997 Solid-Phase Microextraction,
76. Theory and Practice, Wiley-VCH, New York.,
77. R.M. Izatt, J.S. Bradshaw, R.L. Bruening, 1996
78. Pure Appl. Chem. 68:1237.
79. D.F.Hagen, C.G.Markell, G.A. Schmitt, 1990
80. Anal.Chim. Acta 236:157.
81. C.J.Krueger, J.A. Fild, 1995 Anal.Chem.
82. :3363.
83. K.Z.Taylor, D.S.Waddell,E.J.Reiner, 1995
84. Anal. Chem. 67:1186.
85. Y.Yamini, M.Ashraf-Khorassani, 1994 J.High
86. Resolut. Chromatogr.17:634.
87. M.Shamsipur, A.R.Ghiasvand, Y.Yamini, 1999
88. Anal.Chem. 71:4892.
89. M.Shamsipur, A.R.Ghiasvand, H. Sharghi,
90. Int. J.Environ. Anal.Chem. 82:23.
91. Brunner, J.;Mokhir, A.;Kramer, R. 2003
92. J.Am.Chem.Soc. 125:12410.
93. Zelder, F.H.;Brunner, J.; Kramer, R. 2004
94. Chem. Commun., 902.
95. Boll, I.; Kramer, R.; Brunner, J.; Mokhir, A.
96. J.Am.Chem. Soc. 27(2005)7849.
97. Hagen, D.F.;Mrkell, C.G.; Schmitt, G.A.;
98. Blevins, D.D.; Anal. Chim. Acta 236(1990)
99. .
100. Yamini, Y.; Alizadeh, N.; Shamsipur, M.; Anal.
101. Chim. Acta 69(1997) 355.
102. Petit de Pena, Y.; Gallego M.; Valcarcel, M.;
103. Anal. Chem. 67:2524 .
104. Alizadeh, N.; Naeimi, H.; Sharghi,H.;
105. Samsipur,Polish, M.; 1999 Polish
106. J.Chem.73:915.
107. Moghimi A, Poursharifi M.J. 2011, Australian
108. Journal of Basic and Applied Sciences, 5(6):
109. -986 ,
110. Choi,Y.S.;Choi,H.S. 2003 Bull.Korean Chem.
111. Soc.24:222.
112. Matoso,E.;Kubota,L.T.;Cadore,S. 2003
113. STalanta 60:1105.
114. Purachat, B.;
115. Liawruangrath,S.;Sooksamiti,P.;Rattanaphani,S
116. .;Buddhasukh, D.2001 Anal.Sci. 17:443.
117. Ensafi,A.A.;Abbasi,S.;Rahimi
118. Mansour,H.;Mohammad pour Baltork, I.
119. Anal.Sci. 17:609.
120. Saber Tehrani,M.; Rastegar,F.; Parchehbaf,
121. A.;Rezvani,Z,2005.Chinese Journal of
122. Chemistry 23:1437.
123. Moghimi A, R. Ghiasi, 2008 J. Korean Chem.
124. Soc., 52: 4.
125. Moghimi A., 2007; Chinese Journal of
126. Chemistry 12:1842-1847.
127. Hashemi, O. R.; Kargar-Razi, M.; Raoufi, F.;
128. Moghimi, A.; Aghabozorg, H.; Ganjali, M. R.
129. Microchem. J. 69: 1
130. Hashemi, O. R.; Raoufi, F.; Ganjali, M. R.;
131. Moghimi, A.; Kargar-Razi, M.; Aghabozorg,
132. H.; Shamsipur, M. 2000,Anal. Sci. 16: 1221.
133. Ganjali,M R ; Pourjavid, M. R.; Hajiagha
134. Babaei, L.;Niasari, M. S. 2004.Quim Nova 27:
136. Ganjali,M. R.; Pourjavid, M. R.; Hajiagha
137. Babaei, L.;Niasari, M. S. 2004.Ann. Chim.
138. (Rome) 94: 47.
139. Ganjali,M R.; Basiripour, F.; Niasari, M. S.
140. Can. 2002 J. Anal. Sci. Spect. 47: 41