Removal of Acid Red 33 from Aqueous Solution by Fenton and Photo Fenton Processes
محورهای موضوعی :
1 - Young Researchers and Elite Club, Arak Branch, Islamic Azad University, Arak, Iran
کلید واژه: Mineralization, Decolorization, Chemical oxygen demand (COD), Batch photo reactor, Pseudo first order equation,
چکیده مقاله :
In this project decolorization and mineralization of synthetic wastewater containing acid red 33 (AR33) was investigated by Fenton and photo Fenton processes in a batch photo reactor. A comparative assessment using Fenton and photo Fenton processes was performed after initial optimization studies such as varying pH, the concentration of pollutant, peroxide and iron. The color removal and mineralization efficiency of AR33 were calculated by Spectrophotometric and chemical oxygen demand (COD) tests. The degradation efficiency in photo Fenton process (98.5% in 10 min of reaction) was higher than Fenton ones (97.5% in 30 min). After 60 min of reaction, the removal of COD in photo Fenton and Fenton processes was 71% and 37.5%, respectively. Therefore, photo Fenton was the most effective process in partial mineralization of AR33. Kinetic constants were evaluated using pseudo first order equations to obtain the rate constant, K.
- Panakoulias T., Kalatzis P., Kalderis D., Katsaounis A., 2010. Electrochemical degradation of reactive Red 120 using DSAand BDD anodes. J Appl Electrochem. 40, 1759âââ1765.
- Yahiat S., Fourcade F., Brosillon S., Amrane A., 2011. Photocatalysis as a pre-treatment prior to a biological degradation of cyproconazole. Desalination. 281, 61âââ67.
- Moradi H., Sharifnia S., Rahimpour F., 2015. Photocatalytic decolorization of reactive yellow 84 from aqueous solutions using ZnO nanoparticles supported on mineral LECA. Mater Chem Phys. 158, 38âââ44.
- Behnajady M.A., Modirshahla N., Fathi H., 2006. Kinetics of decolorization of an azo dye in UV alone and UV/H2O2 processes. J Hazard Mater B. 136, 816âââ821.
- Shokri A., 2015. Degradation of 2-Nitrophenol from Petrochemical Wastewater by Ozone. Russ J Appl Chem. 88, 2038âËâ2043.
- Katsumata H., Kawabe S., Kaneco S., Suzuki T., Ohta K., 2004. Degradation of bisphenol A in water by the photo-Fenton reaction. J Photochem Photobiol A: Chem. 162, 297âââ305.
- Malik P.K., Sanyal S.K., 2004. Kinetics of decolourisation of azo dyes in wastewater by UV/H2O2 process. Sep Purif Technol. 36, 167âââ175.
- Shokri A., Mahanpoor K., Soodbar D., 2016. Degradation of 2-Nitrophenol from Petrochemical Wastewater by UV/NiFe2O4/Clinoptilolite process. Fresenius Environ Bull. 25, 500-508.
- Momani F.A., Sans C., Esplugas S., 2004. A comparative study of the advanced oxidation of 2,4-dichlorophenol. J Hazard Mater B. 107, 123âââ9.
- Kang S.F., Liao C.H., Po S.T., 2000. Decolorization of textile wastewater by photo-Fenton oxidation technolog. Chemosphere. 41, 1287âââ94.
- Malik P.K., Saha S.K., 2003. Oxidation of direct dyes with hydrogen peroxide using ferrous ion catalys. Sep Purif Technol. 31, 241âââ50.
- El-sousy K., Hussen A., Hartani K., El-Aila H., 2007. Elimination of Organic Pollutants using Supported Catalysts with Hydrogen Peroxide. Jordan J Chem. 2, 97âââ103.
- Kolthof I.M., Sandell E.B, Meeehan E.J., Buckstein S., Quantitative Chemical Analysis, 4thed., Macmillan, New York, 1862âââ1867.
- Badawy M.I, 2006. Advanced oxidation processes for the removal of Organophosphorus pesticides from wastewater. Desalination. 194, 166âââ175.
- Ming-Chun L., Jong-Nan C., Cheu-Ping C., 1999. Oxidation of dichloros with H2O2 using ferrous ion as catalyst. J Hazard Mater. 65, 277âââ288.
- Tunc S., Gurkan T., Duman O., 2012. On-line spectrophotometric method for the determination of optimum operation parameters on the decolorization of Acid Red 66 and Direct Blue 71 from aqueous solution by Fenton process. Chem Eng J. 181âââ182, 431âââ442.
- Zhao X.K., Yang G.P., Wang Y.J., Gao X.C., 2004. Photochemical degradation of dimethyl phthalate by Fenton reagent. J Photochem Photobiol A Chemistry. 161, 215âââ20.
- Romero V., Acevedo S., Marco P., Gimenez J., Esplugas S., 2016. Enhancement of Fenton and photo-Fenton processes at initial Circumneutral pH for the degradation of the ò-blocker metoprolol. Water Res. 88, 449âââ457.
- Schrank S.G., Jose H.J., Moreira R.F.P.M., Schroder H.F., 2005. Applicability of Fenton and H2O2/UV reactions in the treatment of tannery wastewaters. Chemosphere. 60, 644âââ655.
- Catalkaya E.C., Sengul F., 2005. Application of BoxâââWilson experimental design method for the photo degradation of bakeryâââ¢s yeast industry with UV/H2O2 and UV/H2O2/Fe (II) process. J Hazard Mater. 128, 201âââ207.
- Wailling C., 1975. Fentonâââ¢s reagent revisited. Acc Chem Res. 8, 125âââ131.
- Lioua M.J., Lub M.C., Chena J.N., 2003. Oxidation of explosives by Fenton and photo-Fenton processes. Water Res. 37, 3172âââ3179.
- Zhao X.K., Yang G.P., Wang Y.J., Gao X.C., 2004. Photochemical degradation of dimethyl phthalate by Fenton reagent. J Photochem Photobiol A Chemistry. 161, 215âââ20.
- Ramirez J.H., Duarte F.M., Martins F.G., Costa C.A., Madeira L.M., 2009. Modelling of
- the synthetic dye Orange II degradation using Fentonâââ¢s reagent: from batch to continuous reactor operation. Chem Eng J. 148, 394âââ404.
- Daneshvar N., Rabbani M., Modirshahla N., Behnajady M.A., 2005. Photo oxidative degradation of Acid Red 27 in a tubular continuous-flow photo reactor: influence of operational parameters and mineralization products. J Hazard Mater. 118, 155âââ60.
- Bali U., Catalkaya E.C., Sengul F., 2003. Photochemical degradation and mineralization of phenol: A comparative study. J Environ Sci Health: Part A. 38, 2259âââ2275.
- Javier Benitez F., Beltran-Heredia J., Acero J. L., Javier Rubio F., 2000. Rubio contribution of free radicals to Chlorophenols decomposition by several advanced oxidation processes. Chemosphere. 41, 1271âââ1277.
- Shokri A., Mahanpoor K., Soodbar D., 2015. Degradation of Ortho-Toluidine in petrochemical wastewater by Ozonation, UV/O3, O3/H2O2 and UV/O3/H2O2 processes. Des Water Treat. 2015, 1-10.
- Bayarri B., Gimenez J., Curco D., Esplugas S., 2005. Photocatalytic degradation of 2, 4-dichlorophenol by TiO2/UV: kinetics, actinometries and models. Catal Today. 101, 227âââ236.