Investigation of Kinetics and Equilibrium Isotherms of Direct Red 12B Dye Adsorption on Hazelnut Shells

محورهای موضوعی :

Fathi M. R. Asfaram A. ¹ ( )

تاریخ دریافت : 1390/11/09 تاریخ پذیرش : 1397/08/07 تاریخ انتشار : 1390/11/09

کلید واژه: Kinetics, Adsorption, Isotherm, Direct Red 12B, Hazelnut shells,

چکیده مقاله :

In this work, efficiency and performance of Hazelnut shells (HS) adsorbent was examined for the removal and recovery of Direct Red 12B (DR12B) from wastewater. The absorbance of DR12B was measured spectrophotometrically at λmax=523 nm before and after adsorption of DR12B. The maximum removal was 99.8% for 30 mg L–1 ofDR12B concentration on 0.3 gr HS adsorbent. Acidic pH was favourable for the adsorption of DR12B. The influence of variables including pH, concentration dye, particle size, amount of adsorbent, temperature, in column method and kinetics, isotherm, contact time on the dye removal has been investigated in batch method by one at a time optimization method. The effect of foreign cations, anions and other dyes was investigated on removal efficiency. In order to investigate the efficiency of DR12B adsorption on the HS, pseudo-first-order, pseudo-second-order, Elovich and intra-particle diffusion kinetic models were studied. The graphical correlation of various adsorption isotherm models like, Langmuir, Freundlich and Tempkin have been carried out for this adsorbent.

منابع و مأخذ:

1. Abdelwahab. O., Evaluation of the use of loofa activated carbons as potential adsorbents for aqueous solutions containing dye, Desalination 222 (2008) 357-367.
2. Ahmed. A. A., B. H. Hameed and N. J. Hameed. Adsorption of direct dye on palm ash: Kinetic and equilibrium modelingHazard. Mat. 141 (2007) 70-76.
3. Annadurai. G., R.S. Annadurai, P.S. Yen and D. J. Lee, Use of thermally treated waste biological sludge as dye absorbent, Adv. Environ. Res. 7 (2003) 739ââ‚‌“744.
4. Basibuyuk. M. and C.F. Basibuyuk. An examination of the adsorption characteristics of a basic dye (Maxilon Red BL-N) on to live activated sludge system, Process Biochem. 38 (2003) 1311ââ‚‌“1316.
5. Bhattacharyya K.G. and A. Sarma, Adsorption characteristics of the dye, Brilliant green, on Neem leaf powder, Dyes Pigments 57 (2003) 211ââ‚‌“222.
6. Bulut. Y. and Z. Tezb, Adsorption studies on ground shells of hazelnut and almond, Journal of Hazardous Materials 149 (2007) 35ââ‚‌“41
7. Caritá. R. and M. A. Marin-Morales, Induction of chromosome aberrations in the Allium cepa test system caused by the exposure of seeds to industrial effluents contaminated with azo dyes Chemosphere 72 (2008) 722-725.
8. Chiang. T.H., Y.S. Ho and Y.M. Hsueh, Removal of basic dye from aqueous solutions using tree fern as a biosorbent, Process Biochem. 40 (2005) 119ââ‚‌“124.
9. Chien. S. H. and W. R. Clayton, Application of Elovich equation to the kinetics of phosphate release and sorption in soils. Soil Sci. J., Am. 44 (1980) 265-268.
10. Chilton. N., J. N. Losso, W. E. Marshal and N.R. Ramu Freundlich, adsorption isotherms of agricultural by-product-based powdered activated carbons in a geosminââ‚‌“water system. Bioresour. Technol. 85 (2002) 131-135.
11. Chingombe. P., B. Saha and R. J. Wakeman., Sorption of atrazine on conventional and surface modified activated carbons. J. Colloid Interf. Sci. 302 (2006) 408-416.
12. Dogan. M., H. Abak and M. Alkan, Adsorption of methylene blue onto hazelnut shell: Kinetics, mechanism and activation parameters. Journal of Hazardous Materials 164 (2009) 172ââ‚‌“181.
13. Dogan. M., M. Alkan, A. Alkan and Y. Ozdemir, Kinetics and mechanism of removal of methylene blue by adsorption onto perlite, J. Hazard. Mater. B109 (2004) 141ââ‚‌“148.
14. El-Geundi. M.S., Colour removal fromtextile effluents by adsorption techniques, Water Res. 25 (1991) 271ââ‚‌“273.
15. El-Geundi. M.S., Nassar. M.M., Comparative cost of colour removal from textile effluents using natural adsorbents, J. Chem. Technol. Biotechnol. 50 (2) (1991) 257ââ‚‌“264.
16. El-Nabarwy. T.H., Khedr. S.A., Removal of pollutants fromwater using untreated and treated sawdust and water hyacinth, Adsorp. Sci. Technol. 18 (4) (2000) 385ââ‚‌“398.
17. Freundlich. H. M. F., Over the adsorption in solution. Phys. Chem. (Leipzig) 57A (1906) 385-470.
18. Fu, Y., Viraraghavan. T., Fungal decolorization of dye wastewaters: a review, Bioresour. Technol. 79 (2001) 251ââ‚‌“262.
19. Greene, J. C.; Baughman, G. J. Effects of 46 Dyes on Population Growth Of Freshwater Green Alga Selenastrum Capricornutum. Text. Chem. Color. 28 (1996) 23-26.
20. Guo, B., Hong, L., Jiang, H.X., 2003. Macroporous poly(calcium acrylate-divinylbenzene) bead ââ‚‌“ a selective orthophosphate sorbent. Ind. Eng. Chem. Res. 42, 5559ââ‚‌“5567.
21. Gupta. V.K., Mohan. D., Sharma. S., Sharma. M., Removal of basic dye (Rhodamine B and Methylene blue) from aqueous solutions using bagasse fly ash, Sep. Sci. Technol. 35 (2000) 2097ââ‚‌“2113.
22. Ho, Y. S and Mckay, G., Kinetic models for the sorption of dye from aqueous solution by wood. Process Safety and Environmental Protection, 76 (B2), 183ââ‚‌“191 (1998).
23. Kavitha. D., Namasivayam. C. Capacity of activated carbon in the removal of acid brilliant blue: Determination of equilibrium and kinetic model parameters. Chemical Engineering Journal,139 (2008) 453-461.
24. Khan, M.N., Sarwar, A., Zareen, U., Fahimuddin. Adsorption characteristics of crystal violet on beach sand from aqueous solution. Pak. J. Anal. Chem. 3 (2002) 8-12.
25. Lagergren. S., Svenska. B. K., Zur Theorie der Sogenannten Adsorption Geloester Stoffe, Kungliga Svenska Vetenskapsakademiens Handlingar, Band, 24 (4), 1ââ‚‌“39 (1898).
26. Langmuir. I., The adsorption of gases on plane surfaces of glass, mica and platinum. J. Am. Chem. Soc., 40, 1361-1403 (1918).
27. Langmuir. I., The Adsorption of Gases on Plane Surfaces of Glass, Mica and Platinium.J. Am. Chem. Soc. 38 (1916) 2221-2295.
28. Lorenc-Grabowska. E., Gryglewicz. G., Adsorption characteristics of Congo Red on coal-based mesoporous activated carbon, Dyes Pigments 74 (2007).
29. Mall. D. I., Srivastqava. V. C., Agarwal. N. K., Removal of Orange-G and Methyl Violet dyes by adsorption onto bagasse fly ash-kinetic study and equilibrium isotherm analyses .Dyes Pigm. 69 (2006) 210ââ‚‌“223.
30. McKay. G., McKay M., Nassar. M.M., External mass transport processes during the adsorption of dyes onto bagasse pith, Water Res. 22 (12) (1988) 1527ââ‚‌“1533.
31. Mckay. G., Mckay. J. F., Prasad. G. R., The removal of dye colours from aqueous solutions by adsorption on low cost materials", Water, Air and Soil Pollut, 114 (1999) 423-438.
32. Namasivayam. C., Arasi. D. J. S. E., Removal of Congo red from wastewater by adsorption onto red mud, Chemosphere 34 (1997) 401ââ‚‌“471.
33. Namasivayam. C., Muniasamy. N., Gayathri. K., Rani. M., Ranganathan. K., Removal of dyes from aqueous solutions by cellulosic waste orange peel, Bioresour. Technol. 57 (1996) 37ââ‚‌“43.
34. Namasivayam. C., Namasivayam. K.M., Selvi. K., Begum. A.R., Begum. T., Yamuna. R.T., Waste coir pithââ‚‌”a potential biomass for the treatment of dyeing wastewaters, Biomass Bioenergy 21 (2001) 477ââ‚‌“483.
35. Pavan F. A., Dias., S. L. P., Lima E. C., Benvenutti E. V., Removal of congo red from aqueous solution by anilinepropylsilica xerogel. Dyes Pigm. 76 (2008) 64-69.
36. Pavan, F.A., E.C. Lima, S.L.P. Dias and A.C. Mazzocato, 2008. Methylene blue biosorption from aqueous solutions by yellow passion fruit waste. J. Hazard. Mater., 150(3): 703-712.
37. Pavan. F. A., Gushikem Y., Mazzocato. A. S., Dias. S. L. P., Lima. E. C., Statistical design of experiments as a tool for optimizing the batch conditions to methylene blue biosorption on yellow passion fruit and mandarin peels. Dyes Pigm. 72 (2007) 256-266.
38. Ramakrishna. K.R., T. Viraraghavan, Dye removal using peat, Am. Dyestuff Rep. 85 (10) (1996) 28ââ‚‌“34.
39. Salvadori. C. M., De Lima .R. O. A., Bazo. A. P., Rech D. M. F., Oliveira. D. P., Umbuzeiro .G. A., Mutat. Res. 626 (2007) 53-60.
40. Santhy. K., Selvapathy. P., Removal of reactive dyes from wastewater by adsorption on coirpith activated carbon. Bioresource Technology. 97 (2006) 1329- 1336.
41. Shenai. V. A., Some aspects of toxicity of aromatic amines and azo dyes. Colourage, 43 (1996) 41-46.
42. Sivaraj. R., Namasivayam. C., Kadirvelu. K., Orange peel as an adsorbent in the removal of Acid violet 17 (acid dye) from aqueous solutions,Waste Manage.2001, 21(1), 105.
43. Sun. G., Sun. X., Sunflower stalks as adsorbents for color removal from textile wastewater, Ind. Eng. Chem. Res. 36 (3) (1997) 808ââ‚‌“812.
44. Sureshkumar, M.V, Namasivayam, C, Adsorption behavior of Direct Red 12B and Rhodamine B from water onto surfactant-modified coconut coir pith, Colloids and Surfaces A: Physicochem. Eng. Aspects 317 (2008) 277ââ‚‌“283.
45. Tsuboy. M. S., Angel. J. P. F. i., Mantovani, M. S. S., Knasmüller., Umbuzeiro., G. A., Ribeiro., L. R., Toxicol. In Vitro 21 (2007) 1650-1655.
46. Weber. W. J., Morris. J. C., Kinetics of adsorption on carbon from solution, J. Sanitary Eng. Div. Proceed. Am. Soc. Civil Eng. 89 (1963) 31-59.
47. Weng. C.H., Chang. E.E., Chiang. P.C., Characteristics of new coccine dye adsorption onto digested sludge particulates,Water Sci. Technol. 44 (2001) 279ââ‚‌“284.
48. Zhao. X.K., Yang. G.P., Gao. X.C., Studies on the sorption behaviors of nitrobenzene on marine sediments, Chemosphere 52 (2003) 917ââ‚‌“925.