Conformational Study of some novel Methoxy Half-Analogues of Michler’s Ketone by NMR
محورهای موضوعی : Journal of the Iranian Chemical Research
Naghi Saadatjou
1
(Department of Applied Chemistry, Faculty of Science, University of Semnan, Semnan, Iran)
Geoffrey Hallas
2
(Department of Colour and Polymer Chemistry, University of Leeds, Leeds LS2 9JT, England)
کلید واژه: Conformational study, Michler’s Ketone, NMR spectroscopy, Proton Shift, Steric Effect, Ring Current, Carbonyl-induced shift, Tertiary amino groups,
چکیده مقاله :
One series of half-analogues of Michler’s ketone containing one or more terminal methoxysubstituents with variable tertiary amino groups have been used in this study. NMR spectralresults for the parent ketones confirm earlier findings that ortho proton shifts are apparentlyindependent from steric effects in derivatives of Michler’s ketone because the ring current andcarbonyl-induced shifts are self-canceling.
[1] N. Saadatjou, Iranian J. Sci. Tech. 14 (1990) 135-144.
[2] G. Montaudo, P. Finocchiaro, P. Maravigina, J. Am. Chem. Soc. 93 (1971) 4214-4217.
[3] K.D. Bartle., G. Hallas, J.D. Hepworth. Org. Magnetic Resonance 7 (1975) 154-159.
[4] A.G. Pinkus, H.C. Custard, J. Phys. Chem. 74 (1970) 1042-1049.
