Improved preparation of 3,7-dinitro-1,3,5,7-tetraazabicyclo[3,3,1] nonane (DPT) from urea

محورهای موضوعی : Journal of the Iranian Chemical Research

Ming Lu ¹ (Chemical Engineering College, Nanjing University of Science and Technology, Nanjing 210094, China)
Xiaobing Liu, ² (Chemical Engineering College, Nanjing University of Science and Technology, Nanjing 210094, China)
Xiaoyu Yu ³ (Chemical Engineering College, Nanjing University of Science and Technology, Nanjing 210094, China)

تاریخ دریافت : 1388/12/29 تاریخ پذیرش : 1389/03/09 تاریخ انتشار : 1389/10/10

کلید واژه: Urea, 3, 7-dinitro-1, 3, 5, 7-tetraazabicyclo[3, 3, 1]nonane (DPT), Nitration, N, N’- dinitrourea (DNU),

چکیده مقاله :

An improved and facile preparation of 3,7-dinitro-1,3,5,7-tetraazabicyclo [3,3,1] nonane(DPT) has been developed starting from urea. In the procedure DPT was synthesized viaN,N’-dinitrourea (DNU) as intermediate and various operating parameters such astemperature, pH and molar ratio of reagents have been optimized to give maximum yield ofthe desired product. The low cost method is concise, operationally simple and offers highpurity and satisfactory yield of DPT.

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