Boric acid as a highly efficient and reusable catalyst for the one-pot synthesis of 1,8-dioxo-octahydroxanthenes under solvent-free conditions

محورهای موضوعی : Iranian Journal of Catalysis

Sobhan Rezayati ¹ (Department of Chemistry, Payame Noor University, PO BOX 19395-4697, Tehran, Iran. Chemistry Department, Qaemshahr Branch, Islamic Azad University, Qaemshahr, Iran.)
Rahimeh Hajinasiri ² (Chemistry Department, Qaemshahr Branch, Islamic Azad University, Qaemshahr, Iran.)
Zahra Erfani ³ (Department of Chemistry, Payame Noor University, PO BOX 19395-4697, Tehran, Iran.)
Saman Rezayati ⁴ (Department of Chemistry, Payame Noor University, PO BOX 19395-4697, Tehran, Iran.)
Saeid Afshari-sharifabad ⁵ (Chemistry Department, Qaemshahr Branch, Islamic Azad University, Qaemshahr, Iran.)

تاریخ دریافت : 1392/10/20 تاریخ پذیرش : 1393/02/28 تاریخ انتشار : 1393/06/10

کلید واژه: Dimedone, Xanthenes, Solid acid, Boric acid, Aromatic aldehyde, One-pot reaction,

چکیده مقاله :

An efficient and simple procedure for the synthesis of 1,8-dioxo-octahydroxanthenes from the aromatic aldehydes and 5,5-dimethylcyclohexane-1,3-dione (dimedone) in the presence of boric acid [BO3H3 or B(OH)3] as an inexpensive and reusable catalyst is described. The salient features of this methodology are: the elimination of corrosive liquid acids, high yields, simple methodology, short reaction times, easy work-up and green heterogeneous catalyst.

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