Synthesis of 4,4′-(arylmethylene)bis(1H-pyrazol-5-ols) via multi-component reactions by using silica-bonded sulfamic acid derivatives
محورهای موضوعی : Iranian Journal of Catalysis
Shekoofeh Tayebi
1
(Young Researchers Club, Gachsaran Branch, Islamic Azad University, Gachsaran, Iran.)
Khodabakhsh Niknam
2
(Department of Chemistry, Faculty of Sciences, Persian Gulf University, Bushehr 75169 Iran.)
کلید واژه: Aldehydes, Multi-component reactions, Catalyst, Silica-bonded N-propylpiperazine sulfamic acid, 4, 4′-(Arylmethylene)bis(1H-pyrazol-5-ols),
چکیده مقاله :
The one-pot, multi-component synthesis of 4,4′-(arylmethylene)bis(1H-pyrazol-5-ols) by tandem Knoevenagel-Michael reaction of phenylhydrazine, ethyl acetoacetate and aldehydes in the presence of silica-bonded N-propylpiperazine sulfamic acid (SBPPSA) as a recyclable solid acid catalyst was reported. SBPPSA showed much the same efficiency when used in consecutive reaction runs.
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