B-podands as efficient catalysts for the ring opening of epoxides in water: A versatile and atom economical method for the synthesis of vicinal azidoalcohols

محورهای موضوعی : Iranian Journal of Catalysis

Ali Kiasat ¹ , Fakhri Ataeian ² , Mehdi Fallah-Mehrjardi ³

1 - Department of Chemistry, College of Science, Shahid Chamran University, Ahvaz 61357-4-3169, I.R. Iran.
2 - Department of Chemistry, College of Science, Shahid Chamran University, Ahvaz 61357-4-3169, I.R. Iran.
3 - Department of Marine Chemistry, Khorramshahr University of Marine Science and Technology, Khorramshahr 669, I.R. Iran.

تاریخ دریافت : 1390/10/22 تاریخ پذیرش : 1390/11/12 تاریخ انتشار : 1390/10/11

کلید واژه: 1, Ring Opening, Phase transfer catalyst, B-podands, 2-Azidoalcohol, Epoxide, Atom economic,

چکیده مقاله :

For the first time B-podands have been studied as an efficient and powerful catalysts in the ring opening of epoxides with azide anion in water. The reaction afforded the corresponding 1,2-azidoalcohols with high regioselectivity under mild reaction conditions and in a highly atom economic fashion.

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