• صفحه اصلی
  • Facile wet chemical synthesis and characterization of zinc doped gadolinium oxide nanoparticles for enhanced photodegradation of Rhodamine B dye under illumination of UV light

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آدرس مقاله


کد مقاله : IJC-2112-1904 (R3) بازدید : 58 صفحه: 315 - 336

10.30495/ijc.2022.1948621.1904

نوع مقاله: پژوهشی

Facile wet chemical synthesis and characterization of zinc doped gadolinium oxide nanoparticles for enhanced photodegradation of Rhodamine B dye under illumination of UV light

محورهای موضوعی : Iranian Journal of Catalysis

Leena Vinolia Thaninki 1 (a) Department of Applied Chemistry, Karunya Institute of Technology and Sciences (Deemed to be University), Karunya Nagar, Coimbatore - 641114, Tamil Nadu, India|Department of Chemistry, CMR Technical Campus, Kandlakoya, Hyderabad – 501 401, Telengana, India.)
Arputharaj Samson Nesaraj 2 (a) Department of Applied Chemistry, Karunya Institute of Technology and Sciences (Deemed to be University), Karunya Nagar, Coimbatore - 641114, Tamil Nadu, India|Department of Chemistry, Kalasalingam Academy of Research and Education (Deemed to be University), Krishnankoil – 626126, Tamil Nadu, India.)
Manasai Arunkumar 3 (a) Department of Applied Chemistry, Karunya Institute of Technology and Sciences (Deemed to be University), Karunya Nagar, Coimbatore - 641114, Tamil Nadu, India)

تاریخ دریافت : 1400/10/10 تاریخ پذیرش : 1401/04/20 تاریخ انتشار : 1401/06/10

کلید واژه: Rhodamine B, Photodegradation, Co-precipitation method, Zn doped Gd2O3 catalysts,

چکیده مقاله :

In this study, we discuss the wet chemical synthesis and experimental analysis of zinc doped Gd2O3(Gd2-xZnxO3-δ) nanoparticles where, x=0, 0.1, 0.2, 0.3, 0.4, and 0.5. The cubic crystalline structure is derived from XRD results and the existence of metal-oxide bond has been confirmed from FTIR studies. According to SEM and PSA analysis, the produced nanoparticles are found to be of nano size. The EDX data verified the presence of Gd, Zn, and O in the samples. Based on UV-visible spectroscopy, the band gap and λmax values were computed. In an aqueous medium and under UV light irradiation, the photodegradation of Rhodamine B over Zn doped Gd2O3 nanoparticles was studied. It was observed that Gd1.50Zn0.50O3-δ has exhibited 82% of photo-degradation of the dye solution which further increased to 96% because of increasing the catalyst loading. The effect of pH and the concentration of the dye are also reported. According to the kinetic analysis, the photocatalysis process followed a pseudo-first-order kinetic model. A radical scavenger technique was used to further examine and identify the function of photoactive species.

چکیده انگلیسی:

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