Fe3O4@SiO2@IL‐PVP magnetic nanoparticles: Effective synthesis of spirooxindoles

محورهای موضوعی : Iranian Journal of Catalysis

Shahla Veysipour ¹ (Department of Chemistry, Faculty of Science, Yasouj University, Yasouj, 75918-74831, Iran.)
Masoud Nasr-Esfahani ² (Department of Chemistry, Faculty of Science, Yasouj University, Yasouj, 75918-74831, Iran.)
Zahra Rafiee ³ (Department of Chemistry, Faculty of Science, Yasouj University, Yasouj, 75918-74831, Iran.)
Behrouz Eftekhari far ⁴ (Department of Chemistry, Faculty of Science, Yasouj University, Yasouj, 75918-74831, Iran.)

تاریخ دریافت : 1398/12/13 تاریخ پذیرش : 1400/03/04 تاریخ انتشار : 1400/03/11

کلید واژه: reusable catalyst, Green synthesis, Magnetic nanoparticles, Spirooxindoles, Fe3O4@SiO2@IL‐PVP nanocomposite,

چکیده مقاله :

Various magnetite heterogeneous catalysts for the organic reaction are increasingly recognized while their stability still is a critical challenge. In this regard, SiO2, ionic liquid (IL), and polyvinyl pyrrolidone (PVP) were applied as a three-layer stabilization system for modifying magnetic Fe3O4 to produce Fe3O4@SiO2@IL‐PVP as a novel nanocatalyst. The Fe3O4@SiO2@IL‐PVP as stabilized heterogeneous catalysts were utilized in a robust, and environmentally friendly strategy for the preparation of the spirooxindole derivatives by the one-pot condensation of isatin, malononitrile, and 1,3-dicarbonyl in a water solvent. The proposed method revealed a high yield spirooxindole derivatives preparation (99%) at short reaction times (1.0 min), low catalyst mass (0.002 g), and satisfactory temperature (30 °C) which confirm the lack of any tedious challenge and promising applicability and reusability. This work introduces a rational core-shell nanosystem design with a facile and novel construction strategy to arrive at nonexquisite metal-based composite catalysts with superior catalytic proficiency and prominent long-term stability.

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