Microwave assisted Pd(OAc)2-catalyzed chemoselective reduction of aryl α,β-unsaturated esters with triethylsilane

محورهای موضوعی : Iranian Journal of Catalysis

Yogesh Kumar ¹ , Renuka Yadav ² , Anshu Kumar Sinha ³ , Pooja Rawat ⁴ , Gyandshwar Kumar Rao ⁵ , Chandra Mohan Srivastava ⁶ , Nirmala Kumari Jangid ⁷ , Anamika Srivastava ⁸ , Manish Srivastava ⁹ , Varun Rawat ¹⁰

1 - Department of Applied Chemistry, Amity School of Applied Sciences, Amity University Haryana, Gurugram-122413 (Haryana), India.
2 - Department of Applied Chemistry, Amity School of Applied Sciences, Amity University Haryana, Gurugram-122413 (Haryana), India.
3 - Department of Applied Chemistry, Amity School of Applied Sciences, Amity University Haryana, Gurugram-122413 (Haryana), India.
4 - Department of Applied Chemistry, Amity School of Applied Sciences, Amity University Haryana, Gurugram-122413 (Haryana), India.
5 - Department of Applied Chemistry, Amity School of Applied Sciences, Amity University Haryana, Gurugram-122413 (Haryana), India.
6 - Centre for Polymer Technology, Amity School of Applied Sciences, Amity University Haryana, Gurugram-122413 (Haryana), India.
7 - Department of Chemistry, Banasthali Vidyapith, Banasthali-304022 (Rajasthan), India.
8 - Department of Chemistry, Banasthali Vidyapith, Banasthali-304022 (Rajasthan), India.
9 - Department of Chemistry, Banasthali Vidyapith, Banasthali-304022 (Rajasthan), India.
10 - Department of Applied Chemistry, Amity School of Applied Sciences, Amity University Haryana, Gurugram-122413 (Haryana), India.

تاریخ دریافت : 1398/10/10 تاریخ پذیرش : 1399/05/04 تاریخ انتشار : 1399/06/11

کلید واژه: reduction, Microwave, Palladium, Chemoselective, Triethylsilane,

چکیده مقاله :

In this communication, we have reported that the Pd(OAc)2–Et3SiH-DMF system promotes the microwave-assisted chemoselective reduction of aryl α,β-unsaturated esters in good yields. The protocol affords a convenient reduction of aryl-conjugated double bonds even in presence of other functional groups like esters, phenols, and ethers.

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