Nano-SiO2/hexamethylenetetramine promoted synthesis of pyrano[2,3-c] pyrazoles under solvent-free conditions
محورهای موضوعی : Iranian Journal of CatalysisBi Bi Fatemeh Mirjalili 1 , Mina Keihanfar 2
1 - Department of Chemistry, Faculty of Sciences, Yazd University, P.O. Box 89195-741, Yazd, I.R. Iran.
2 - Department of Chemistry, Faculty of Sciences, Yazd University, P.O. Box 89195-741, Yazd, I.R. Iran.
کلید واژه: reusable catalyst, Multicomponent reactions, Nano-SiO2/hexamethylenetetramine, Pyrano[2, 3-c]pyrazole, Basic nanocatalyst,
چکیده مقاله :
In this study, the nano-SiO2/hexamethylenetetramine as a new basic heterogeneous nanocatalyst was prepared and used for the synthesis of pyranopyrazole via the four-component reaction. Various aldehydes, hydrazine hydrate, ethyl acetoacetate and malononitrile were reacted at room temperature under solvent-free and grinding conditions. The morphology and structure of nano-catalyst were investigated by techniques such as FT-IR spectroscopy, FESEM, TEM, XRD, CHNS elemental analyzer and TGA. The structure of pyranopyrazoles was determined by spectroscopic data of FTIR and NMR. The principal affairs of this procedure are easy work-up, high yields, mild conditions and short reaction times.
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