Melamine trisulfonic acid: An efficient and recyclable solid acid catalyst for the green synthesis of Biscoumarin derivatives
محورهای موضوعی : Iranian Journal of CatalysisNasir Iravani 1 , Mosadegh Keshavarz 2 , Maryam Mousavi 3 , Mojtaba Baghernejad 4
1 - Department of Chemistry, Faculty of Science, Gachsaran Branch, Islamic Azad University, Gachsaran, Iran.
2 - Department of Gas and Petroleum, Yasouj University, Yasouj, Zip Code 75918-74831, Iran
3 - Department of Chemistry, Gachsaran Branch, Islamic Azad University, Gachsaran, Iran
4 - Young and Reasearcers Elite, Gachsaran Branch, Islamic Azad University, Gachsaran, Iran
کلید واژه: Melamine trisulfonic acid, Aromatic aldehydes, Biscoumarins, 4-hydroxycoumarin,
چکیده مقاله :
A novel catalytic synthesis of 3,3'-(arylmethylene)-bis-(4-hydroxy-2H-chromene-2-one) derivatives from a tandem condensation reaction of 4-hydroxycoumarin and aromatic aldehydes has been developed. The reaction occurs in water in the presence of Melamine trisulfonic acid as catalyst to give the corresponding products in good to high yields. This green approach has several advantages such as short reaction times, clean reaction profiles, and simple experimental and workup procedures. Moreover, the catalyst can be easily recovered by filtration and used at least seven times with only slight reduction in its catalytic activity. The results of the presented protocol in comparison with the different available catalysts in condensation reaction of benzaldehyde with 4-Hydroxycoumarin show that MTSA presented better results due to the structure of MTSA.
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