Preparation and application of HMCM-22 zeolite as an efficient solid acid catalyst for the synthesis of acetals
محورهای موضوعی : Iranian Journal of CatalysisHosein Hoseini 1 , Maryam Gorjizadeh 2 , Soheil Sayyahi 3 , Amirhossein Shahbazi Kootenaei 4
1 - Department of Chemistry, Mahshahr Branch, Islamic Azad University, Mahshahr, Iran.
2 - Department of Chemistry, Shoushtar Branch, Islamic Azad University, Shoushtar, Iran.
3 - Department of Chemistry, Mahshahr Branch, Islamic Azad University, Mahshahr, Iran.
4 - Department of Chemical Engineering, Mahshahr Branch, Islamic Azad University, Mahshahr, Iran.
کلید واژه: Protection, Heterogeneous catalyst, HMCM-22, Acetals,
چکیده مقاله :
HMCM-22 with a Si:Al molar ratio of 15:1 has been shown to effectively catalyze the synthesis of acetals with 100% selectivity by the reaction of aldehydes with methanol under reflux conditions. Platelet HMCM-22 particles were prepared by the static strategy and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), BET techniques and N2-adsorption/desorption analysis. The catalyst was recovered by simple filtration and reused for several cycles without considerable loss of activity. HMCM-22 with a Si:Al molar ratio of 15:1 has been shown to effectively catalyze the synthesis of acetals by the reaction of aldehydes with methanol under reflux conditions. Platelet HMCM-22 particles were prepared by static method and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), BET techniques and N2-adsorption/desorption analysis. The catalyst was recovered by simple filtration and reused for several cycles without considerable loss of activity.
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