Nano cotton-shape mesoporous (NCSM) modified by Fe3O4: Green, magnetic and reusable catalytic system for dechlorization of bromothymol blue (BTB)
محورهای موضوعی : Iranian Journal of Catalysis
1 - Department of Chemistry, Shahreza Branch, Islamic Azad University, 86145-311, Iran.
کلید واژه: Nano cotton-shape mesoporous (NCSM), Fe3O4, Heterogeneous photocatalysis, Bromothymol blue (BTB),
چکیده مقاله :
Fe3O4-containing cotton-like mesoporous silica system (Fe3O4@NCSM) was studied with regard to its performance towards the photodecolorization of bromothymol blue (BTB) aqueous solution. The surface properties of the functionalized catalyst were analyzed by a series of characterization techniques like FTIR, XRD, BET, SEM and TEM. The N2 Adsorption–desorption analysis shows that the mesostructure of silica remains intact after Fe3O4 modifications, while the spectral technique shows the successful encapsulating of the neat Fe3O4 inside the porous silica support. The optimum values of the experimental parameters which affect the degradation efficiency were obtained as: 0.15 g L−1 of the photocatalyst, 25 ppm dye concentration and pH 5.6.
[1] X. Hui-Li, Z. Hui-Sheng, Z. Tao, X. Dong-Chang, J. Environ. Sci. 19 (2007) 1141-1145.
[2] C. Sahoo, A.K. Jupta, A. Pal, Desalination 181 (2005) 91–100.
[3] S. Senthilvelan, V.L. Chandraboss, B. Karthikeyan, L. Natanapatham, M. Murugavelu, Mater. Sci. Semicond. Process 16 (2013) 185–192.
[4] A. Saepurahman, M.A. Abdullah, F.K. Chong, Chem. Eng. J. 158 (2010) 418-425.
[5] Zh. Aiyong, Zh. Minghua, H. Lu, Zh. Qixing, Appl. Catal. A 385 (2010) 114-122.
[6] S. Chin, E. Park, M. Kim, J. Jurng, Powder Technol. 201 (2010) 171-176.
[7] H. Faghihian, A. Bahranifard, Iran. J. Catal. 1 (2011) 45-50.
[8] H.R. Pouretedal, M. Ahmadi, Iran. J. Catal. 3 (2013) 149-155.
[9] A. Nezamzadeh-Ejhieh, Z. Banan, Iran. J. Catal. 2 (2012) 79-83.
[10] A. Bagheri Ghomi, V. Ashayeri, Iran. J. Catal. 3 (2012) 135-140.
[11] A. Nezamzadeh-Ejhieh, M. Khorsandi, Iran. J. Catal. 1 (2011) 99-104.
[12] M.H. Habibi, E. Askari, Iran. J. Catal. 1 (2011) 41-44.
[13] H.R. Pouretedal; S. Basati, Iran. J. Catal. 2 (2012) 51-55.
[14] H.L. Xu, W.Z. Wang, Angew. Chem. Int. Ed. 46 (2007) 1489-1492.
[15] S. Yang, L.Z. Zhao, C.Z. Yu, X.F. Zhou, J.W. Tang, P. Yuan, D.Y. Chen, J. Am. Chem. Soc. 128 (2006) 10460-10466.
[16] G.L. Lin, Y.H. Tasi, H.P. Lin, C.Y. Tang, C.Y. Lin, Langmuir 23 (2007) 4115-4119.
[17] Y.Q. Yeh, B.C. Chen, H.P. Lin, C.Y. Tang, Langmuir 22 (2006) 6-9.
[18] B.C. Chen, M.C. Chao, H.P. Lin, C.Y. Mou, Microporous Mesoporous Mater. 81 (2005) 241-249.
[19] H. Blas, M. Save, P. Pasetto, C. Boissiere, C. Sanchez, B. Charleux, Langmuir 24 (2008) 13132-13137.
[20] Feng Z, Li YS, Niu DC, Li L, Zhao WR, Chen HR, Lei L, Gao JH, 295 Ruan ML, Shi JL., Chem. Commun. (2008) 2629-2631.
[21] J.G. Wang, F. Li, H.J. Zhou, P.C. Sun, D.T. Ding, T.H. Chen, Chem. Mater. 21 (2009) 612-620.
[22] H. Blas, M. Save, P. Pasetto, C. Boissiere, C. Sanchez, B. Charleux, Langmuir 24 (2008) 13132-13137.
[23] Z. Feng, Y.S. Li, D.C. Niu, L. Li, W.R. Zhao, H.R. Chen, L. Lei, J.H. Gao, M.L. Ruan, J.L. Shi, Chem. Commun. (2008) 2629-2631.
[24] E. Bishop, Indicators, Pergamon Press, New York, 1972.
[25] J.B. Puschett, B.S. Rao, B.M. Karandikar, K. Matyiaszewsui, Talanta 38 (1999) 335–338.
[26] L. Du, H. Song, S. Liao, Appl. Surf. Sci. 255 (2009) 9365–9370.
[27] N. Sobana, B. Krishnakumar, M. Swaminathan, Mater. Sci. Semicond. Process 16 (2013) 1046–1051.
[28] Z. Feng, Y.S. Li, D.C. Niu, L. Li, W.R. Zhao, H.R. Chen, L. Lei, J.H. Gao, M.L. Ruan, J.L. Shi, Chem. Commun. (2008) 2629-2631.
[29] H. Aliyan, R. Fazaeli, R. Jalilian, Appl. Surf. Sci. 276 (2013) 147-153.
[30] Y.M. Liu, Y. Cao, K.K. Zhu, S.R. Yan, W.L. Dai, H.Y. He, K.N. Fan, J. Catal. 224 (2004) 417-428.
[31] R. Fazaeli, H. Aliyan, M. Moghadam, M. Masoudinia, J. Mol. Catal. A: Chem. 374-375 (2013) 46–52.
[32] Y.M. Liu, W.L. Feng, T.C. Li, H.Y. He, W.L. Dai, W. Huang, Y. Cao, K.N. Fan, J. Catal. 239 (2006) 125–136.
[33] R. Fazael, H. Aliyan, J. Sol-Gel Sci. Tech. 76 (2015) 456-464.
[34] C.T. Kresge, M.E. Leonowicz, W.J. Roth, J.C. Vartuli, J.S. Beck, Nature 359 (1992) 710-712.
[35] M. Che, J.C. Vedrine, Wiley-VCH, Weinheim, Germany 2012.
[36] A. Riga, K. Soutsas, K. Ntampegliotis, V. Karayannis, G. Papapolymerou, Desalination 211 (2007) 72-86.
[37] S. Lathasree, A. Nageswara, B. SivaSankar, V. Sadasivam, K. Rengaraj, J. Mol. Catal. A: Chem. 223 (2004) 101-105.
[38] C.H. Chiou, C.Y. Wu, R.S. Juang, Chem. Eng. J. 139 (2008) 322-329.
