Investigation on Germanium Synergic extraction from synthetic solution
Subject Areas :
1 - دانشگاه تهران
Keywords: Germanium, Synergic Extraction, D2EHPA, LIX 63,
Abstract :
In this study, germanium synergic solvent extraction was investigated from synthetic acidic solution. Coal waste and zinc resources are the main resources for germanium extraction. Usually hydrometallurgical methods are used in procedure for germanium recovery. Di(2-ethylhexyl) phosphoric acid (D2EHPA) and LIX 63 were used to separate germanium form solution. The effects of pH, extraction time and stirring speed were investigated and results showed that the optimum pH was lower than 0.2. The optimum time was 3 minutes and in this time equilibrium was reached. By optimization of the parameters, more than 87% of germanium was extracted.
[1] Virolainen, S., J. Heinonen & E. Paatero, “Selective recovery of germanium with N-methylglucamine functional resin from sulfate solutionsˮ, Separation and Purification Technology, Vol. 104, pp. 193-199, 2013.
[2] B. Depuydt, De Jonghe, M. De Baets, W. Romandic, I. Theuwis, A. Quaeyhaegens, C. Deguet & A. C. T. Letertre, F. Chapter 1 - germanium materials. Germanium-based Technologies, Elsevier: Oxford, pp. 1-39, 2007.
[3] D. E. Guberman, Germanium. U.S. Geological Survey, 2011.
[4] S. A. Wood &I. M. Samson, “The aqueous geochemistry of galliumˮ, germanium, indium and scandium, Ore Geology Reviews, Vol. 28, No. 1, pp. 57-102, 2006.
[5] S. Nusen, et al., “Recovery of germanium from synthetic leach solution of zinc refinery residues by synergistic solvent extraction using LIX 63 and Ionquest 801ˮ, Hydrometallurgy, Vol. 151, pp. 122-132, 2015.
[6] H. Wang, L. Jiangshun, J. Kaixi & Q. Dingfan, “Recovery of Ga, Ge from zinc residues by hydrometallurgical processesˮ, Sohn International Symposium Advanced Processing of Metals and Materials, New, Improved and Existing Technologies: Aqueous and Electrochemical Processing, Vol. 6, pp. 413-420, 2006.
[7] D. D. Harbuck, J. C. Judd & D. V. Behunin, “Germanum Solvent Extraction From Sulfuric Acid Solutions (AND CO-EXTRACTION OF GERMANIUM AND GALLIUM)ˮ, Solvent Extraction and Ion Exchange, Vol. 9, No. 3, pp. 383-401, 1991.
[8] X. h. Ma, W. q. Qin & X. l. Wu, “Extraction of germanium(IV) from acid leaching solution with mixtures of P204 and TBPˮ, Journal of Central South University, Vol. 20, No. 7, pp. 1978-1984, 2013.
[9] S. f. Tang, et al., “Extraction separation of germanium with hydroxamic acid HGS98ˮ, Journal of Central South University of Technology, Vol. 7, No. 1, pp. 40-42, 2000.
[10] M. Alibrahim, S. H. S. Alike, “Solvent extraction of Vanadium (IV) with di-2-ethylhexyl phosphoric acid and tributyl phosphate Rperiodica Polytechnicˮ Chemical Engineering, Vol. 1, No. 52, pp. 29-33, 2008.
[11] A. A. B. Zhuravlev, T. A. Abrarov & O. A. “Preparation of germanium-71. Extraction of germanium by hexane from hydrochloric acid solutionsˮ RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY, Vol. 13, No. 05, 1981.
[12] S. A. Javanshir, M. Abolghasemi, H. Khodadadi Darban & A., “The effect of kinetics parameters on Gold extraction by Lewis Cell: comarison between synthetic and leach solutionˮ, Iran. J. Chem. Chem. Eng, Vol. 31, No. 4, 2012.
[13] س. جبارزارع، و س. عموشاهی فروشانی، "بررسی لیچینگ غبار تشویه مولیبدنیت"، نشریه فرایندهای نوین در مهندسی مواد، دوره 3، شماره 4، صفحه 65-70، 1388.
[14] ص. محمدیان و ع. سعیدی، "بررسی مقایسهای تأثیر فعالسازی مکانیکی بر فرآیند ترکیبی پیرو-هیدرومتالورژیکی در استخراج مس از کانه سولفیدی توسط آسیابهای سیارهای و گلولهای"، نشریه فرایندهای نوین در مهندسی مواد، دوره 6، شماره 3، صفحه 85-95، 1391.
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