Fabrication of Silver Oxide and Nickel Oxide Nanoparticles by Green Synthesis Method Using Malva Sylvestris Plant Extract

Subject Areas : Chemistry

Azam  Beheshtian ¹ (Department of Chemistry, Science and Research Branch, Islamic Azad University, Tehran, Iran)
Mohammad Hadi  Givianrad ² (Department of chemistry, Science and Research Branch, Islamic Azad University, Tehran Iran)
Hossain-Ali  Rafiee-Pour ³ (Department of Cell and Molecular Biology, Faculty of Chemistry, University of Kashan, Kashan, Iran)
Parviz  Aberoomand Azar ⁴ (Department of Chemistry, Science and Research Branch, Islamic Azad University, Tehran, Iran)

Received: 2023-08-22 Accepted : 2023-12-02 Published : 2023-02-01

Keywords: nanoparticles, Quercetin, green chemistry, Nickel oxide, silver oxide, malva sylvestris extract,

Abstract :

This paper reports the green preparation of silver oxide and nickel oxide nanoparticles. The malva sylvestris extract was used as the green reductant and capping agent. The prepared nanoparticles were characterized using XRD, SEM, FT-IR, and EDX analysis. The XRD analysis discloses that the prepared silver oxide nanoparticles comprise both Ag2O and Ag metal phases. In addition, it was found that the prepared nickel oxide nanoparticles have an amorphous structure. The FT-IR results show the presence of metal-oxide bonds at the wavenumber range 750-600 cm-1. Also, the green synthesis of the metal oxide nanoparticles was confirmed by the existence of the organic functional groups on the surface of the prepared samples. The SEM images show the spherical nanoparticles in the size range below 50 nm for both prepared nanoparticles. These results reveal the superior ability of the malva sylvestris extract to prepare the fine metal oxide nanoparticles. In this research, synthesized Ag2O nanoparticles (Ag2O NPs) and NiO nanoparticles (NiO NPs) were used as modifiers for carbon paste electrode (CPE) and their effect on the electrochemical determination of Quercetin (QCT) was investigated by using differential pulse voltammetry (DPV).

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