Adsorption of Nickel Ions from Aqueous Solutions using Immobilized Silica Nanoparticles onto Zeolite 13x

Subject Areas : Water and Environment

Tahere Mardani ¹ ( Department of Chemical Engineering, Shahreza Branch, Islamic Azad University, P.O. Box 311-86145, Shahreza, Iran. )
Elham Ameri ² ( Department of Chemical Engineering, Najafabad Branch, Islamic Azad University, Najafabad, Iran. *(Corresponding Author) )

Received: 2023-12-11 Accepted : 2024-01-17 Published : 2024-02-17

Keywords: Zeolite, Silica nano particles, Nickel, Isotherm, Kinetics.,

Abstract :

Background and Objective: Nano material has attracted much attention due to its functional groups and special properties. In this study, silica nanoparticles immobilized on zeolite 13X granules (SZX13), by sol gel method was synthesized. The aim of this study was determination of the performance of prepared nano sorbent in nickel ions removal from aqueous solution. Material and Methodology:The present historical research, with an analytical-comparative approach, has used inferential and deductive reasoning. First, the principles of organic style architecture, derived from a comparative study of written evidence and existing documents, were explained as a criterion of measurement. Then, a list of works of organic architecture in Iran was prepared to select samples for analysis by purposive sampling. Finally, the analyzed samples were compared with the principles of organic architecture. Findings: Scanning Electron Microscope analysis showed that the immobilization process was successfully carried out and the immobilized particles has a nano size distribution. Optimized values for each factor to achieve the highest uptake were found to be as follows: The Ni initial concentration of 60 mg/L, the pH 6, the adsorbent (SZX13) dose of 1 g, at 40 ° C. Discussion and Conclusion: Results showed that the immobilization of nano particles on the zeolite not only led to that the particles were distributed in an expanded volume, but also prepare the accessible usage of that in an industrial scale. In addition, with immobilization of silica nanoparticles onto zeolite granules, the sorption of nickel ions were increased in comparison to that by using zeolite 13X, and the removal percentage was increased from %26 to %43.98.

References:

1. Vijayaraghavan, K., Yun Y. S., 2008. Bacterial biosorbents and biosorption. Biotechnology Advances, Vol.26, pp. 266-291.
2. Ozer, A., 2007. Removal of Pb(II) of ions from aqueous solutions by sulphuric acid-treaed wheat bran, Journal of Hazardous Materials, Vol. 141, pp. 753-761.
3. Srivastava, N. K., Majumder, C. B., 2008. Novel biofiltration methods for the treatment of heavy metals from industrial wastewater. Journal of Hazardous Materials, Vol. 151, pp. 1-8.
4. Ranjbaran, H., Ameri, E., Dehghani, B., 2023. Preparation of dendrimer/TiO2 polysulfone nanofiltration membrane to improve antibacterial, antifouling and separation performance of contaminants (heavy metals, salts, dyes), Polymer Bulletin, Article in press.
5. Hashemibeni, M., Ameri, E., Hashemibeni, J., Seifi, H., 2022, Synthesis of nanocomposite membranes embedded with cellulose nanocrystals and their application to filtrate of arsenic aqueous solutions, Desalination and Water Treatment, Vol. 247, pp. 17-27.
6. Asaad Abdollahi, S., Mokhtariyan, N., Ameri, E., 2022, Design of a solar reactor based on porous nanocomposite ceramics for removal of heavy metal ions from wastewater, Solar Energy, Vol. 233, pp. 61-70.
7. Asaad Abdollahi, S., Mokhtariyan, N., Ameri, E., 2022, Design, synthesis and application of a sponge-like nanocomposite ceramic for the treatment of Ni(II) and Co(II) wastewater in the zinc ingot industry, Arabian Journal of Chemistry, Vol. 15(1),103477.
8. Amini, M., Unesi, H., Ziyai, M.A., 2012. Investigation of nickel and lead metallic ions removal from industrial wastewater using biological adsorption with Aspergillusniger. The 1st national conference on solutions to access sustainable development, Tehran, Iran. (In Persian)
9. Hu, J., Chen, G.H., Lo-Irene, M.C, 2006. Removal and recovery of Pb(II) from wastewater by maghemite nanoparticles, Water Research, Vol. 39, pp. 4528–4536.
10. kiani, R., Nikbakht fard, F., Rahbar, A., 2013, Lead ion adsorption isotherms study on different adsorbents and evaluation of thermodynamic parameters, The fourth national conference on wastewater and solid waste management in oil and energy, Tehran, Iran. (In Persian)
11. Saidi, M., Ayati nia, M., Ghorbanian, T., 2014, The effect of organic materials on lead, zinc and nickel competitive adsorption to clay: caolen, montmorilonite and sand mixture, The first national conference of environmental health, health and sustainable environment, Hamedan, Iran. (In Persian)
12. Srivastava, V., Weng, C.H., Singh, V.K., Sharma Y.C., 2011. Adsorption of Nickel Ions from Aqueous Solutions by Nano Alumina: Kinetic, Mass Transfer, and Equilibrium Studies. Journal of Chemical and Engineering Data, Vol. 56, pp. 1414–1422.
13. Rahmani, H. M., Zavvar, Mousavi, H., Fazli, M., 2010. Effect of nanostructure alumina on adsorption of heavy metals. Desalination, Vol. 253, pp. 94-100.
14. Karami, H., 2013, Heavy metal removal from water by magnetite nanorods. Chemical Engineering Journal, Vol. 219, pp. 209–216.
15. Low, K. S., Lee, C. K., Leo, A. C., 2016. Removal of metal from electroplating wastes using mana pith, Bioresource Technology, Vol. 51, pp. 227-231.
16. Cheraghi, E., Ameri, E., Moheb, A., 2015. Adsorption of cadmium ions from aqueous solutions using sesame as a low-cost biosorbent: kinetics and equilibrium studies, International Journal of Environmental Science and Technology, Vol. 12, pp. 2579-2592.
17. Azizi, Z., Ameri, E., 2016. Synthesis and characterization of nano magnetic wheat straw for lead adsorption, Vol. 57, pp. 9813-9823.