Evaluation of efficiency and optimization of Photo- Fenton process parameters in beet sugar wastewater treatment using response surface methodology (RSM)
Subject Areas :
Environment Pullotion (water and wastewater)
Abbas Alipour Hajiagha
1
,
Mojgan Zaeimdar
2
*
,
Seyed Ali Jozi
3
,
nooshin sajadi
4
,
Arezoo Ghadi
5
1 - PhD Student, Department of Environment, Faculty of Marine Science and Technology, North Tehran Branch Islamic Azad University, Tehran, Iran.
2 - Assistant Professor, Department of Environment, Marine Science and Technology Faculty, North Tehran Branch Islamic Azad University, Tehran, Iran. * (Corresponding author)
3 - Professor, Department of Environment, Technical and Engineering Fauclty, North Tehran Branch Islamic Azad University, Tehran, Iran.
4 - Assistant Professor, Department of Environment, Marine Science and Technology Faculty, North Tehran Branch Islamic Azad University, Tehran, Iran.
5 - Assistant Professor, Department of Chemical Engineering, Technical and Engineering Faculty, Islamic Azad University Amol Branch, Amol, Iran
Received: 2018-12-08
Accepted : 2019-03-06
Published : 2022-03-21
Keywords:
Sugar industry,
Pollution load reduction,
Photo- Fenton process,
Wastewater treatment,
Abstract :
Background & Objective: The wastewater obtained from sugar production cannot be naturally degraded due to the presence of various color precursors, colored impurities, lime carbonation sludge and other organic impurities. In this study, optimization of the effective parameters for the sugar industry wastewater treatment is investigated using photo- Fenton process and response surface methodology.Material and Methodology: This empirical research was conducted on a laboratory scale on refined wastewater obtained from sugar beet factory (Qazvin, Iran), in ternms of the intensity of contamination, considering the reduction of the three factors including COD, phenolic, and color content using the advanced oxidation process (photo- Fenton process). In order to optimize the ocndions for wastewater treatment, the results of these experiments wre ultimately optimized by response surface methodology.Findings: The results obtained that the optimal condition for color and phenolic removal were: pH of 6.1' reaction time 15 minutes' Fenton's reagent (Fe2+/H2O2) concentrations: 20/1500 of ppm. Under these conditions, the color and phenolic reduction were achieved 73.92% and 93.9%, respectively.Discussion & Conclusions: The photo- Fenton process has a good efficacy in treating the sugar industry wastewater in the removal of important pollution parameters such as color impurities, phenolic compounds, and COD.Also, the statistical results showed that the pH parameter, Fenton's reagent concentration and contact time were significant during treatment process (p<0.05).
References:
Ali Abadi, Mohammad et al.,. " The Application of Cracking Acid and Processes of Fenton in Oliver Oil Waste Treatment", Journal of Water and Sewage, Volume 17, Issue 1, Pages 36-30. (In Persian)
Gharib Beilalan, Saadi et al., "Optimization of coloring conditions of melanoidin with activated carbon powder and determination of molecular weight distribution using permeation gel chromatography", Journal of Food Industry Researchs, vol. 26, No. 3, Page 443-42. (In Persian)
Gharib-Bibalan, S., Keramat J & Hamdami, N., 2017, ²Better Lime Purification of Raw Sugar Beet Juice by Advanced Fenton Oxidation Process². Ozone Science and Engineering. Vol. 40(1), pp. 54-63.
Gharib-Bibalan, S., Keramat, J., Hamdami, N., Hojjatoleslamy, M., 2016, ²Optimization of Fenton Oxidation Process for the Degradation of Color Precursors in Raw Sugar Beet Juice². Sugar Tech. Vol. 18(3), pp. 273-284.
ICUMSA 2000 Methods Book, Supplement. Pub: International Commission for Uniform Methods of Sugar Analysis, Method GS2/3-10.
Kushwaha, J.P., 2015, ²A review on sugar industry wastewater: sources, treatment technologies, and reuse². Desalination and Water Treatment. Vol. 53(2), pp. 309-318.
Maamir,W., Ouahabi, Y., Poncin, S., Li, H.Z., Bensadok, K., 2017, ²Effect of Fenton Pretreatment on Anaerobic Digestion of Olive Mill Wastewater and Olive Mill Solid Waste in Mesophilic Conditions². International Journal of Green Energy. (In Persian)
Mohajeri, L., Aziz, H.A., Isa, M.H., Zahed, M.A., 2010, ²A statistical experiment design approach for optimizing biodegradation of weathered crude oil in coastal sediments². Bioresource Technology. Vol. 101, pp. 893-900.
Mudoga, H.L., Yucel, H., Kincal, N.S., 2008, ²Decolorization of sugar syrups using commercial and sugar beet pulp based activated carbons². Bioresource Technology. Vol. 99, pp. 3528-3533.
Nasehi, M.S., Ansari, S., Sarshar, M., 2012, ²Removal of dark colored compounds from date syrup using activated carbon: A kinetic study². Journal of Food Engineering, 111, pp. 490-495.
Oturan, M.A., Aaron, J.J., 2014, ²Advanced oxidation processes in water/wastewater treatment: principles and applications. A review². Critical Review Environmental Science and Technology. Vol. 44(23), pp. 2577-2641.
Rodrigues, C.S., Neto, A.R., Duda, R.M., de Oliveira, R.A., Boaventura, R.A., Madeira, L.M., 2017, ²Combination of chemical coagulation, photo-Fenton oxidation and biodegradation for the treatment of vinasse from sugar cane ethanol distillery². Journal of Cleaner Producttion. Vol. 142, pp. 3634-3644.
Poddar, P.K., Sahu, O., 2017, ²Quality and management of wastewater in sugar industry². Applied Water Science. Vol. 7(1), pp. 461-468.
Sahu, O., 2016, ²Degradation of colour and chemical oxygen demand of sugar industry wastewater by thermo-chemical combined processes². Environmental Nanotechnology, Monitoring & Management. Vol. 6, pp. 194-205.
Sahu, O., Rao, D.G., Gopal, R., Tiwari, A., Pal, D., 2017, ²Treatment of wastewater from sugarcane process industry by electrochemical and chemical process: Aluminum (metal and salt)². Journal of Water Process Engineering. Vol. 17, pp. 50-62.
Thanapimmetha, A., Srinophakun, P., Amat, S., Saisriyoot, M., 2017, ²Decolorization of Molasses-Based Distillery Wastewater by Means of Pulse Electro-Fenton Process². Journal of Environment Chemical Engineering.
Vaccari, G., Tamburini, E., Sgualdino, G., Urbaniec, K., Klemeš, J., 2005, ²Overview of the environmental problems in beet sugar processing: possible solutions². Journal of Cleaner Production. Vol. 13(5), pp. 499-507.
Xu, X., Cheng, Y., Zhang, T., Ji, F., Xu, X., 2016, ²Treatment of pharmaceutical wastewater using interior micro-electrolysis/Fenton oxidation-coagulation and biological degradation². Chemosphere. Vol. 152, pp. 23-30.
Gharib-Bibalan, S2018."High Value- Added Products Recovery from Sugar Processing By Products and Residuals by Green Technologies: Opportunities, Challenges, and Prospects" Food Engineering Reviews. Vol. 10 (2), pp.95-111.
Rodrlguez- Chueca, J., Amor, C. Fermandes, J.R., Tavares, P.B., Lucas, M.S. and Peres, J.A., 2016. Treatment of crystallized- fruit wastewater by UV-A LED photo- Fenton and coagulation flocculation. Chemosphere, 145, pp.351-359.
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Ali Abadi, Mohammad et al.,. " The Application of Cracking Acid and Processes of Fenton in Oliver Oil Waste Treatment", Journal of Water and Sewage, Volume 17, Issue 1, Pages 36-30. (In Persian)
Gharib Beilalan, Saadi et al., "Optimization of coloring conditions of melanoidin with activated carbon powder and determination of molecular weight distribution using permeation gel chromatography", Journal of Food Industry Researchs, vol. 26, No. 3, Page 443-42. (In Persian)
Gharib-Bibalan, S., Keramat J & Hamdami, N., 2017, ²Better Lime Purification of Raw Sugar Beet Juice by Advanced Fenton Oxidation Process². Ozone Science and Engineering. Vol. 40(1), pp. 54-63.
Gharib-Bibalan, S., Keramat, J., Hamdami, N., Hojjatoleslamy, M., 2016, ²Optimization of Fenton Oxidation Process for the Degradation of Color Precursors in Raw Sugar Beet Juice². Sugar Tech. Vol. 18(3), pp. 273-284.
ICUMSA 2000 Methods Book, Supplement. Pub: International Commission for Uniform Methods of Sugar Analysis, Method GS2/3-10.
Kushwaha, J.P., 2015, ²A review on sugar industry wastewater: sources, treatment technologies, and reuse². Desalination and Water Treatment. Vol. 53(2), pp. 309-318.
Maamir,W., Ouahabi, Y., Poncin, S., Li, H.Z., Bensadok, K., 2017, ²Effect of Fenton Pretreatment on Anaerobic Digestion of Olive Mill Wastewater and Olive Mill Solid Waste in Mesophilic Conditions². International Journal of Green Energy. (In Persian)
Mohajeri, L., Aziz, H.A., Isa, M.H., Zahed, M.A., 2010, ²A statistical experiment design approach for optimizing biodegradation of weathered crude oil in coastal sediments². Bioresource Technology. Vol. 101, pp. 893-900.
Mudoga, H.L., Yucel, H., Kincal, N.S., 2008, ²Decolorization of sugar syrups using commercial and sugar beet pulp based activated carbons². Bioresource Technology. Vol. 99, pp. 3528-3533.
Nasehi, M.S., Ansari, S., Sarshar, M., 2012, ²Removal of dark colored compounds from date syrup using activated carbon: A kinetic study². Journal of Food Engineering, 111, pp. 490-495.
Oturan, M.A., Aaron, J.J., 2014, ²Advanced oxidation processes in water/wastewater treatment: principles and applications. A review². Critical Review Environmental Science and Technology. Vol. 44(23), pp. 2577-2641.
Rodrigues, C.S., Neto, A.R., Duda, R.M., de Oliveira, R.A., Boaventura, R.A., Madeira, L.M., 2017, ²Combination of chemical coagulation, photo-Fenton oxidation and biodegradation for the treatment of vinasse from sugar cane ethanol distillery². Journal of Cleaner Producttion. Vol. 142, pp. 3634-3644.
Poddar, P.K., Sahu, O., 2017, ²Quality and management of wastewater in sugar industry². Applied Water Science. Vol. 7(1), pp. 461-468.
Sahu, O., 2016, ²Degradation of colour and chemical oxygen demand of sugar industry wastewater by thermo-chemical combined processes². Environmental Nanotechnology, Monitoring & Management. Vol. 6, pp. 194-205.
Sahu, O., Rao, D.G., Gopal, R., Tiwari, A., Pal, D., 2017, ²Treatment of wastewater from sugarcane process industry by electrochemical and chemical process: Aluminum (metal and salt)². Journal of Water Process Engineering. Vol. 17, pp. 50-62.
Thanapimmetha, A., Srinophakun, P., Amat, S., Saisriyoot, M., 2017, ²Decolorization of Molasses-Based Distillery Wastewater by Means of Pulse Electro-Fenton Process². Journal of Environment Chemical Engineering.
Vaccari, G., Tamburini, E., Sgualdino, G., Urbaniec, K., Klemeš, J., 2005, ²Overview of the environmental problems in beet sugar processing: possible solutions². Journal of Cleaner Production. Vol. 13(5), pp. 499-507.
Xu, X., Cheng, Y., Zhang, T., Ji, F., Xu, X., 2016, ²Treatment of pharmaceutical wastewater using interior micro-electrolysis/Fenton oxidation-coagulation and biological degradation². Chemosphere. Vol. 152, pp. 23-30.
Gharib-Bibalan, S2018."High Value- Added Products Recovery from Sugar Processing By Products and Residuals by Green Technologies: Opportunities, Challenges, and Prospects" Food Engineering Reviews. Vol. 10 (2), pp.95-111.
Rodrlguez- Chueca, J., Amor, C. Fermandes, J.R., Tavares, P.B., Lucas, M.S. and Peres, J.A., 2016. Treatment of crystallized- fruit wastewater by UV-A LED photo- Fenton and coagulation flocculation. Chemosphere, 145, pp.351-359.