The study of oil-contamination groundwater due to Shazand Refinery
Subject Areas : Industrial pollutionAbdorreza Vaezi hir 1 , Sanaz Qobadiyan 2 , Alireza Golmohamadi 3
1 - Faculty member of Department of Earth Sciences, University of Tabriz, Tabriz, Iran
2 - Master of Hydrology, Department of Earth Sciences, University of Tabriz, Tabriz, Iran
3 - Head of Environment of Imam Khomeini Shazand Oil Refinery, Arak, Iran Faculty member of Earth Sciences, University of Tabriz, Tabriz
Keywords: BTEX, Groundwater contamination, Shazand Refinery, Drinking water and irrigation water standard, MTBE,
Abstract :
Background and Purpose: Shazand oil refinery, as the biggest producer of gasoline in the Middle East, is located 22 km to the Southwest of Arak and the Northeast of Shazand plain. Due to presence of various storage tanks of crude oil and oil products, processing unites and conveyance lines of oil products, it is very possible the leakage of pollution from tanks and conveyance lines into the soil and groundwater. Shazand plain aquifer is an unconfined and consists of coarse-grained alluvial deposits with a flow direction from the refinery to the agriculture wells which are located at the center of plain. Hence, groundwater contamination, which was resulted from the oil pollution of Shazand refinery was investigated. Material and Method: In this study, 16 wells were sampled in study area on Jun 2015 and they delivered to laboratory for analyzing. Compound BTEX and MTBE analyzed by gas chromatography with flame ionization detector (GC-FID[1]). To investigate contamination in study area, results of analyses of BTEX and MTBE were compared with valid standards of drinking and agriculture water. Result: The results show that 6 wells are polluted at the East and South of refinery and the east and Northeast of petrochemical complex. A part of the groundwater contamination was due to atmospheric washout and the other part relates to leak from utilities, tanks and conveyance lines. Discussion & Conclusion: Considering the already existing and the other possible forms of contamination in the area, it is proposed that before taking, the exact source of contamination be identified and proper measures to clean the area be chosen based on expert opinion.
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1. Cupers C., Pancras T., Grotenhuis T., Rulkens W., 2002. The estimation of PAH bioavailability in contaminated sediments using hydroxypropyl-b-cylodextrin and triton x-100 extraction techniques. Chemosphere, Vol. 46, pp. 1235-1245.
2. Fels, J., 1999. Source-identification investigations of petroleum contaminated groundwater in the Missouri Ozarks. Engineering Geology, Vol, 52, pp. 3–13.
3. EPA, 1998. Remediation of MTBE contaminated soil and groundwater. Environmental Protection Agency: EPA 510-F-97-015.
4. EPA, 2012. Drinking Water Standards and Health Advisories. Washington, DC: The Office of Water U.S. Environmental Protection Agency, see more information in: https://www.epa.gov/dwstandardsregulations/drinking-water-contaminant-human-health-effects-information
5. ATSDR, 2007. Toxicological profile for benzene. Agency for Toxic Substances and Disease Registry, see information in: https://www.atsdr.cdc.gov/toxprofiles/tp.asp?id=40&tid=14
6. Pakrvan, Sh., Saeb, K., Ghysari, M. M., 2014. Study of spreading oil pollutants from Isfahan oil refinery and petrochemical facilities to groundwater. The 7th Conference & Exhibition on Environmental Engineering, Tehran, Iran [In Persian].
7. Safari, F., Vaezihir, A. R., Kalejahi, A., 2015. Determination of hydrocarbon contamination and study of biodegradation in the aquifer at Tabriz oil refinery and petrochemical complex site. Advanced Applied Geology, Vol. 5., pp. 48-58.
8. Shadizadeh, R., Zavidanpur, M., 2008. The investigation and estimation of amount of oil in groundwater at Abadan oil refinery complex. Water and Wastewater, Vol. 2, pp. 27-36 [In Persian].
9. Feyzi, M., Sartaj, M., Fathiyan pur, N., 2007. The investigation of spreading oil pollutants from Shazand petrochemical and oil refinery facilities to groundwater, Arak, Iran. 1st Iranian Petrochemical Conference, Tehran, Iran [In Persian].
10. Naseri, H., Modaberi, S., Falsafi, F., 2009. Groundwater contamination due to oil pollutants at industrial area, Shar-e-Rey, South of Tehran, Tehran, Iran. 2nd Conference of Environmental Engineering, Tehran, Iran [In Persian].
11. Fraile. J., Ninerola, M. J., Olivella, L., Figueras, M., Ginebreda, A., Vilanova, M., 2002. Monitoring of the Gasoline Oxygenate MTBE and BTEX Compounds in Groundwater in Catalonia (Northeast Spain). The Scientific World, Vol. 2, pp. 1235-1242.
12. 13- Ministry of Energy of Iran, 2010. The report of prohibition renewal in Shazand area. Water resources office, groundwater group, water organization of Arak, Arak, Iran [In Persian].
13. Sokolovic, S., Pavlovic, p., Pavlovic, M., 2000. Risk Assessment of the NIS NOVISAD Oil Refinery Site After NATO Bombing. IUAPPA Praha, Sec. A, pp.72-76.
14. QPHR, 2005. Queensland Public Health Regulations. Queensland Government, Brisbane, Australia.
15. ISIRSI-1053, 1388. Drinking Water-Physical and Chemical Specification, Institute of Standard and Industrial Research Iran 1053, 5th revision.ICS:13.060.020.
16. MfE, 2011. Guideline for Assessing and Managing Petroleum Hydrocarbon Contamination Sites in New Zealand. Ministry for the Environment (New Zealand).