Evaluation of physical and chemical properties of imidazolium based ionic liquid:1-butyl 3-methylimidazoium methyl sulfate.

Subject Areas :

seyed mohammadreza shoja ¹ , majid abdouss ² , ali akbar miran beigi ³

1 - PhD student in Applied Chemistry, Department of Chemistry, Amirkabir University of Technology, Tehran, Iran
2 - Prof. of Organic Chemistry, Department of Chemistry, Amirkabir University Of Technology, Tehran, Iran
3 - Associate Prof. of Analytical Chemistry, Oil Refining Department, Research Institute of Petroleum Industry, Tehran, Iran

Received: 2019-12-22 Accepted : 2020-01-21 Published : 2020-08-22

Keywords: Ionic liquid, Physical and Chemical Properties, Synthesis and identification, Electrochemical window,

Abstract :

In this work, the imidazolium based ionic liquid, i.e. 1-butyl 3-methylimidazolium methyl sulfate [BMIM][MeSO4], was synthesized and identified using NMR, FT-IR, and elemental analysis (CHNOS). Physical and chemical properties of this ionic liquid including density, viscosity, surface tension, refractive index, pH, and speed of sound were initially investigated in the temperature range of 10°C-90°C as well as its electrochemical window at ambient temperature. The results showed that, this ionic liquid had a wide electrochemical window (6V) and all the mentioned physical and chemical parameters except pH were completely temperature-dependent and decreased by increasing temperature. The pH of the ionic liquid was almost constant in the desired temperature range. The results of this research can be utilized as a database on the mentioned temperature range for this ionic liquid.

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