Abstract :
Para-Nitrophenol (PNP) as a nitroaromatic matter is a hazardous pollutant in industrial wastewaters. In this paper degradation of the pollutant was performed by the catalysts of CuWO4/CuO, Na0.01WO3, and WO3 under visible light. The catalysts were synthesized by hydrothermal method and the process was performed in a suspension reactor equipped with a metal halid lamp (400 W). The synthesized catalysts were characterized using X-ray diffraction (XRD), Field emission scanning electron microscopy (FE-SEM), and Diffuse reflection spectroscopy (DRS). The effective parameters of pH, reaction temperature, and light intensity have been studied. The results showed that using [Catalyst] = 2000 ppm, [PNP] = 20 ppm, T = 25 °C, and pH = 12 after 240 min, the degradation efficiency for WO3, Na0.01WO3, and CuWO4/CuO obtained about 40%, 42.3%, and 30%, respectively.
References:
[1] Bastam, T.R.; Entezari, M.H.; Chem. Eng. J. 210, 510-519, 2012.
[2] Alinnor, I.-J. and Nwachukwu, M.-A.; J. Environ. Chem. Ecotoxicol. 2, 32-36, 2011.
[3] Nwokem, C.O.; Gimba, C.E.; Ndukw, G.I.; Abechi, S.E.; Adv. Appl. Sci. Res. 2, 268-278, 2014.
[4] Nayak, P.S.; Singh, B.K.; Ind. J. Chem. 46, 620-623, 2007.
[5] Saien, J.; Soleymani, A.R.; J. Hazard. Mater. 144, 506–512, 2007.
[6] Wang, N.; Zheng, T.; Jiang, J.; Lung, W.S; Miao, X.; Wang, P.; Chem. Eng. J. 239, 351-359, 2014.
[7] Herrera-Melian, J.A.; Martin-Rodriguez, A.J.; Ortega-Mendez, A.; Arana, J.; Dona-Rodriguez, J.M.; Perez-Pena, J.; J. Environ. Manag. 105, 53-60, 2012.
[8] Liou, M.J.; Lu, M.C.; Chen, J.N.; Water Res. 37, 3172–3179, 2003.
[9] Zhang, M.; Chen, X.; Zhou, H.; Murugananthan, M.; Zhang, Y.; Chem. Eng. J. 264, 39-47, 2015.
[10] Zhang, W.; Xiao, X.; An, T.; Song, Z.; Fu, J.; Sheng, G.; Cui, M.; J. Chem. Technol. Biotechnol. 78, 788–794, 2003.
[11] Kiwi, J.; Pulgarin, C.; Peringer, P.; Appl. Catal. B.: Environ. 3, 335–350, 1994.
[12] MA, O.; Peiroten, J.; Chartrain, P.; Acher, A.J.; Environ. Sci. Technol., 34, 3474–3479, 2000.
[13] حمیدرضا، پوراعتدال؛ محمدحسین، کشاورز؛ «تخریب فوتوکاتالیستی آلایندههای شیمیایی»، انتشارات دانشگاه صنعتی مالک اشتر، 1391.
[14] Tang, J.; Zou, Z.; Ye, J.; Angew. Chem. Int. Edition. 43, 4463–4466, 2004.
[15] Konstantinou, I.K.; Albanis, T.A.; A review. Appl. Catal. B. : Environ. 49, 1–14, 2004.
[16] Melghit, K.M.; Rubaei, S.A.; Al-Amri, I.; J. Photochem. Photobiol. A. 181, 137–141, 2006.
[17] Gaffour, H.; Mokhtar, M.; Res. Chem .Int. 42, 6025-6038, 2016.
[18] Basahel, S.N.; Mokhtar, M.; Alshareah, E.H.; Katabathini, N.; Nanosci. Nanotechnol. Lett. 8, 448–457, 2016.
[19] Sugiyama, M.; Salehi, Z.; Tokumura, M.; Kawase, Y.; Water Sci. Technol. 65, 1882-6, 2012.
[20] Kuzhalosai, V.; Subash, B.; Senthilraja, A.; Dhatshanamurthi, P.; Shanthi, M.; Spectrocheimi. Act. Part A 115, 876-882, 2013.
[21] Nishimoto, S.; Mano, T.; Kameshima, Y.; Miyake, M.; Chem. Phys. Lett. 500, 86–89, 2010.
[22] Lee, H.; Choi, J.; Lee, S.; Yun, S.T.; Lee, C.; J. Appl. Catal. B.: Environ. 138, 311–317, 2013.
[23] فرهادیان، موسی؛ سنگپور، پروانه؛ رئیسی، بابک؛ سومین همایش ملی مدیریت پساب و پسماند در صنایع نفت و انرژی، 1-8، 1391
[24] Kim, H.; Yoo, H.Y.; Hong, S.; Lee, S.; Lee, S.; Park, B.S.; Park, H.; Lee, C.; Lee, J.; Appl. Catal.: B. Environ. 162, 515–523, 2015.
[25] Aslama, M.; qbal, I.; Ismaila, M.I.; Chandrasekarana, S.; Hameeda, A.; J. Hazard. Mater. 276, 120–128, 2014.
[26] Nambi, A.B.; Anusha, J.V.; Subramanian, E.; J. Environ. Biotechnol. Res. 6, 157-167, 2017.
[27] Ahmadi, M.; Younesi, R.; Guinel, M.J.F.; J. Mater. Res. 29, 1424-1430, 2014.
[28] Wang, X.; Pang, L.; Hu, X.; Han, N.; J. Environ. Sci. 35, 76–82, 2015.
[29] Wang, L.; Zhan, J.; Fan, W.; Cui, G.; Sun, H.; Zhuo, L.; Zhaoc, X.; Tang, B.; J. RSC. 46, 8833-8835, 2010.
[30] Chen, H.; Leng, W.; Xu, Y.; J. Phys. Chem. 118, 9982−9989, 2014.
[31] Vamvasakis, I.; Georgaki, I.; Vernardou, D.; Kenanakis, G.; Katsarakis, N.; J. Sol-Gel Sci. Technol. 76, 120-128, 2015.
[32] Liu, B.; Phys. Chem. Chem. Phys. 18, 11520-11527, 2016.
[33] Luo, X.; Deng, F.; Min, L.; Luo, S.; Guo, B.; Zeng, G.; AU, C; Environ. Sci. Technol. 47, 7404-7412, 2013.
[34] Xin, Y.; Gao, M.; Wang, Y.; Ma, D.; J. Chemi. Engin. 242, 162–169, 2014.
[35] Yoona, M.; Ohb, Y.; Hongd, S.; Sang Leea, J.; Boppellaa, R.; Kimd, S.H.; Motaa, F.M.; Kimb, S.O.; Kim, D.H.; Appl. Catal. B.: Environ. 206, 263–270, 2017.
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