Synthesis and characterization of iron-phosphonate (Fe-DTPMP) nanoparticle and investigating their anti-bacterial activities

Subject Areas :

سیده زهرا موسوی کیش ¹ , بیژن ممبنی گوداژدر ²

1 - دانشگاه آزاد اسلامی، واحد امیدیه، دانشکده علوم، گروه شیمی، امیدیه، ایران
2 - دانشگاه آزاد اسلامی، واحد امیدیه، دانشکده علوم، گروه شیمی، امیدیه، ایران

Received: 2019-07-22 Accepted : 2020-01-13 Published : 2020-09-22

Keywords: antibacterial effect, Diethylentriamine pentamethylphosphonic acid, Iron-phosphonate,

Abstract :

In this study, Organic-inorganic iron-phosphonate nano-catalyst was prepared by using Iron (ΙΙ) chloride with a basic solution of diethylene triamine-penta (methylene phosphonate). The size of nanoparticles was controlled by cetyl tri-methyel ammonium bromide (CTAB) as a surfactant. The structure of the synthesized Fe@DTPMP nanomaterials was fully characterized by using different methods such as FTIR, scanning electron microscopy (SEM), X-ray diffraction (XRD), thermal gravimetric analysis (TGA), vibrating sample magnetometry (VSM), and Energy-dispersive X-ray spectroscopy (EDS). The SEM analyze confirmed a hollow spherical micromorphology with well-defined porosity. In the presence of surfactant, the nanoparticles have a spherical structure and particle size of about 20-30 nm. The magnetization of synthesized nanoparticles in a field with a strength of 15KOe is about 5 emu/g. The TGA analysis demonstrates significant catalyst stability against heat, so that there is no specific failure at temperatures up to 300 ° C. The antibacterial test of this nanoparticle showed that these materials prevented the growth of the gram-negative and positive bacteria (Staphylococcus aureus, colic Oshirshiyya). These nanoparticles created a halo 14-16 mm in diameter in their surroundings.

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