High efficient solar light photocatalytic degradation of malachite green by solid state synthesized Bi2Sn2O7 and Bi2MxSn2O7 ﴾M = Y3+, Eu3+, Gd3+ and Yb3+) nanomaterials
Ladan Roohandeh
1
(
Department of Physics, Faculty of Science, Jundi-Shapur University of Technology, Dezful, Iran
)
Alireza Hakimyfard
2
(
1Department of Basic science, Jundi-Shapur University of technology, Dezful, Iran
)
Mohammad Samimifar
3
(
Department of Chemistry, Faculty of Science, Jundi-Shapur University of Technology, Dezful, Iran
)
Keywords:
Abstract :
High efficient solar light photocatalytic degradation of malachite green by solid state synthesized Bi2Sn2O7 and Bi2MxSn2O7 ﴾M = Y3+, Eu3+, Gd3+ and Yb3+) nanomaterials
Running Title:
MG photodegradation by Bi2Sn2O7 nanomaterials
Abstract
Nanostructured Bi2Sn2O7 and Bi2MxSn2O7 ﴾M = Y3+, Eu3+, Gd3+ and Yb3+) nanomaterials were synthesized by conventional one-step solid state crystal growth reactions among Bi(NO3)3, SnCl2 and M2O3 raw materials at 800 ̊C for 10 and 15 h. The doped nanomaterials were synthesized to study the capacity of the crystal system to locate each of the dopant ions into the crystal system cavities. The synthesized nanomaterials were characterized by powder X-ray diffraction (PXRD) technique. Rietveld analysis showed that the obtained materials were crystallized well in orthorhombic crystal structure with the space group Aba2. The PXRD data revealed that dopant ion type had a considerable influence on the crystal phase purity of the obtained targets. The morphologies of the synthesized materials were studied by field emission scanning electron microscopy (FESEM) technique. Ultraviolet-visible spectra analysis showed that the synthesized nanomaterials had strong light absorption in the ultraviolet light region. Photocatalytic performance of the synthesized nanomaterials was investigated for the degradation of pollutant Malachite Green under solar light condition. The optimum conditions were modeled and obtained by design expert software for Bi2Sn2O7 that was synthesized at 800 ̊C for 10 h which were 0.06 mL H2O2, 12 mg catalyst and 40 min for the removal of 50 mL of 40 ppm MG solution. The degradation yield in these conditions was 100 %. The photocatalytic degradation fitted to the Langmuir–Hinshelwood kinetic model. As a result of the model, the kinetic of degradation followed a pseudo-zero-order kinetic model.
Keywords: photodegradation, Solid state, Rietveld, Kinetic, pyrochlore.
1. Introduction
Mixed metal oxides with general formula A2B2O7 (A is a medium-large cation and B is an octahedrally coordinated, high charge cation) have been widely studied for their potential applications [1-3]. The Pyrochlore-type Bi2Sn2O7 was first reported by Roth [4]. The pyrochlore structure is formed when the ionic radius ratio of the two cations (A/B) lies between 1.46 and 1.78. In the case of Bi2Sn2O7, the radius ratio is 1.70 [5]. So, Bi2Sn2O7 belongs to the pyrochlore family of general formula A2B2O7 [6]. Bi2Sn2O7 shows certain photocatalytic ability in the visible light range. The direct optical band gap value of Bi2Sn2O7 is 2.3–2.8 eV [7,8]. Bi2Sn2O7 is a desirable ternary oxide showing utility in a wide array of organic transformations and acts as a selective CO-sensing device [9,10]. So, Bi2Sn2O7 has found applications in gas-sensing devices as a selective sensor for carbon monoxide in the presence of other gases [11,12]. Bi2Sn2O7 is not only a key component of multiphasic catalyst for isobutene-to-methacrolein conversion [13], but it has also been utilized as a catalyst in several reactions such as oxidative dehydrodimerization of propylene [14], oxidative dehydroaromatization of isobutene [15], and oxidative coupling of methane [16,17]. Besides, bismuth-containing oxides are of considerable importance as heterogeneous catalysts for a variety of processes and also are used as electrode materials in the reduction of oxygen [18]. The photocatalytic property of the pyrochlore compound is enhanced with doping with rare earth ions that can reduce the recombination rate of electron-hole pairs and enhance the interfacial charge transfer efficiency [19]. Previous experimental investigations have confirmed that Bi2Sn2O7 has three polymorphs. At room temperature, Bi2Sn2O7 adopts a monoclinic structure and is designated as α phase. At intermediate temperature higher than 90 ◦C, orthorhombic phase (β phase) is found. At temperature above 680 ◦C, Bi2Sn2O7 is the ideal pyrochlore structure with cubic symmetry and designated as the γ phase [20]. β-Bi2Sn2O7 has orthorhombic crystal structure with space group Aba2 and unit cell parameters a = 7.571833(8), b = 21.41262(2), and c = 15.132459(14) Å. α-Bi2Sn2O7 has monoclinic crystal structure with space group Cc and unit cell parameters a = 13.15493(6), b = 7.54118(4), and c = 15.07672(7) Å and β = 125.0120(3)° [21]. The other crystal system reported in the literature is cubic crystal system with the space group Fd-3m and the lattice parameter a = b = c = 10.7 Å [22]. In Bi2Sn2O7 crystal phases, α-Bi2Sn2O7 is mentioned as a catalyst in several partial oxidation reactions such as dehydrodimerization or aromatic dehydroaromatization of propene, selective oxidation of propene into acrolein, oxidative dehydrogenation of 1-butene into butadiene and oxidative coupling of methane [23]. However, β-phase has band gap energy of 2.3 eV, which is lower than that of the α-phase (2.85 eV). But the α phase is considered as catalyst because it has a high quantum efficiency thus offering low speed recombination of photo generated electron–hole pairs [24]. So, until now, there is no reported published work considers β-Bi2Sn2O7 as a photocatalyst. Several methods have been reported for the synthesis of Bi2Sn2O7 materials such as hydrothermal [4,25,4,7,17, 26, 27-30], thermal decomposition of complex [10], chemical co-precipitation [8], solving metal oxides in organic solvent and heating at 800 ̊C for 24 h [23], organic solution and heating at 800 ̊C for 20 h [27], solid state at 1000 ̊C for 4 days [18], solid state at 1000 ̊C for 16 h [21], solid state using Bi2O3, SnO2 at 800 – 900 ̊C for 8 h and then 1050 ̊C for 2 h. A cubic crystal system was obtained by this method [22], solid state using Bi2O3, SnO2 mixed in a liquid medium and calcined at 800 ̊C for 8 h and then at 900 ̊C for 8 h in silica crucible under air atmosphere. The obtained Bi2Sn2O7 had cubic crystal phase [31]; solid state gas phase using Sn and Bi powders raw materials at 700 – 900 ̊C. In this case, a tetragonal crystal system was obtained [32]; solid-state using Bi2O3 and SnO2 at 1100 ̊C. In the process, a cubic crystal system was achieved [33]; solid state at 800 ̊C for 24 h and then 48 h reaction using SnO2 and Bi2O3; a cubic crystal phase was obtained [34]; Solid state by heating SnO2 and Bi2O3 mixtures for 24 h at 900 to 1000°C in gold lined Al2O3 crucible. Cubic and tetragonal crystal systems were obtained [35]; solid state using Bi2O3 and SnO2 at 750 ̊C for 12-24 h. Monoclinic and cubic phase distributions at different temperatures were achieved [36]; solid state using Bi2O3 and SnO2 at 750 – 950 ̊C for 8 to 24 h. A mixture of cubic and orthorhombic crystal system was obtained [37]; solid state using Bi2O3 and SnO2 at 1100 ̊C and a tetragonal crystal system was obtained [38], etc.
A photocatalytic application for removing MG from aqueous waste water is also reported in the present work. MG is a triarylamine dye and used in pigment industry. MG is used in leather, paper, silk, cotton, and jute dyeing processes. It is also used as an antifungal and anti-protozoan agent in fisheries and aquaculture industry [39,40]. It is a non-biodegradable dye pollutant and is a highly controversial compound. Furthermore, MG and its metabolites are known to cause mutagenic, carcinogenic, and teratogenic effects to living organisms [41]. It should not be used for beverages, food, medicines. Its inhalation may cause irritation to the respiratory tract, and in large quantities causes tissue damage and inflammation of kidneys [42,43]. Recently, several metal oxides and sulfides have been used for the degradation of MG under different conditions summarized in ref. [44,45].
The present work reports a conventional one-step solid state method for the synthesis of β-Bi2Sn2O7 and Bi2MxSn2O7 (M = Y3+, Eu3+, Gd3+ and Yb3+) nanomaterials using Bi(NO3)3, SnCl2, Y2O3, Eu2O3, Gd2O3 and Yb2O3 raw materials at 800 ̊C for 10 and 15 h. Rietveld analysis data are used to calculate the variation of the crystallographic parameters of the obtained materials when the reaction time and the dopant ion are changed. Besides, the band gap energies of the as-prepared pure and doped nanomaterials are initially estimated from ultraviolet-visible spectra. FESEM images are also used to study the morphology changes of the obtained targets when the reaction time and the dopant type are changed. Besides, the photocatalytic application of the synthesized Bi2Sn2O7 nanomaterial is also investigated for the degradation of MG under solar light condition. The experimental design method is used to optimize the factors affecting the degradation process. The parameters are the amount of the nanocatalyst, H2O2 and the reaction time. The data show that the synthesized Bi2Sn2O7 nanocatalyst has very good efficiency at aqueous solution under the optimized conditions.
2. Experimental
2.1. General remarks
All chemicals were of analytical grade, obtained from commercial sources, and used without further purification. Phase identifications were performed on a powder X-ray diffractometer D5000 (Siemens AG, Munich, Germany) using CuKa radiation. The Rietveld analysis was performed by FullProf software. The morphology of the obtained materials was examined with a Philips XL30 scanning electron microscope (Philips, Amsterdam, Netherlands) equipped with energy-dispersive X-ray (EDX) spectrometer. FTIR spectra were recorded on a Tensor 27 (Bruker Corporation, Germany). Absorption spectra were recorded on an Analytik Jena Specord 40 (Analytik Jena AG Analytical Instrumentation, Jena, Germany). For the photocatalytic degradation, the test solutions were prepared daily by solving certain amount of the solid MG dye in the deionized distilled water. The MG concentration of MG was determined at 606 nm using a Shimadzu UV-visible1650 PC spectrophotometer. A BEL PHS-3BW pH-meter with a combined glass-Ag/AgCl electrode was used for adjustment of the solution pH.
2.2. Synthesis of Bi2Sn2O7 nano-photocatalyst
In a typical synthetic experiment, 0.243 g (0.5 mmol) of Bi(NO3)3 (Mw = 485.08 g mol-1 ) and 0.113 g (0.5 mmol) of SnCl2 (Mw = 225.5 g mol-1 ) were mixed in a mortar and ground until a nearly homogeneous powder was obtained. The obtained powder was added into a 25 mL crucible and treated thermally in one step in a pre-heated electrical oven at 800 ̊C for 10 (S1) or 15 h (S2). The crucible was then cooled normally in oven to the room temperature. The obtained powder was collected for further analyses. The synthesis yield for Bi2Sn2O7 (Mw = 767.4 g mol-1) was 0.34 g (89 %) and 0.35 g (91 %) for S1 and S2, respectively.
2.3. Synthesis of Bi2MxSn2O7 (M= Y3+, Eu3+, Gd3+ and Yb3+) (x=mmol of dopant ion) nanomaterials
For the synthesis of the doped materials, 0.5 mmol of Bi(NO3)3, 0.5 mmol of SnCl2 and 0.01 g of Y2O3 (S3), or Eu2O3 (S4), or Gd2O3 (S5) and/or Yb2O3 (S6) were mixed in a mortar and ground until a nearly homogeneous powder was obtained. The obtained powder was added into a 25 mL crucible and treated thermally in one step at 800 ̊C for 15. The crucible was then cooled normally in oven to the room temperature. The obtained powder was collected for further analyses. The powder weight amount for the doped Bi2Sn2O7 was 0.21 g, 0.31 g, 0.26 g and 0.29 g for S3, S4, S5 and S6, respectively.
3. Result and discussion
3.1. Characterization
The phase composition of the as-prepared Bi2Sn2O7 and Bi2MxSn2O7 (M= Y3+, Eu3+, Gd3+ and Yb3+) nanomaterials was examined by powder X-ray diffraction technique. Figs. 1 and 2 show the PXRD patterns of the obtained materials in the 2θ range 10–80̊. The results of structural analysis performed by the FullProf program employing profile matching with constant scale factors are also included in the Figs. Red lines are the observed intensities while the black ones are the calculated data. The blue line is the difference: Yobs - Ycalc. The Bragg reflection positions are indicated by blue bars for the main crystal phase (Bi2Sn2O7) and red bars to the impurity crystal phase. Figure 1 a-c shows a comparison study of the crystal system type of the obtained target. It was found that when the crystallographic parameters of cubic crystal system including Fd-3m space group with a=b=c= 10.7 Å [22] is used in the rietveld analysis, some impurity peaks marked with * are appeared. Besides, the impurity peaks are still present when the crystallographic parameters of monoclinic crystal system is included in the rietveld analysis ﴾Space group = Cc, a=13.08907 Å, b = 7.53348 Å and c = 15.02513 Å and β = 125 ̊) [21]. However, when orthorhombic crystallographic parameters are included in the rietveld analysis ﴾space group = Aba2, a = 7.54632 Å, b = 21.51632 Å and c = 15.08011 Å) [21], no impurity peak was observed. Table 1 shows the rietveld analyses data of S2. The table shows that the refinement of S2 is good when the crystallographic data of orthorhombic crystal system is used in the rietveld analysis. So the orthorhombic crystallographic parameters are selected for the rietveld analyses for all of the obtained targets. Figure 2 a-f shows the PXRD patterns of S1 – S6, respectively, based on the orthorhombic crystal system parameters. The data show that when the reaction time is increased from 10 h to 15 h, the purity of the obtained target is increased from 72 % to 100 %. The impurity phase is belonged to Bi2O3 crystal structure with space group P21/c and the lattice parameters a = 5.84993 Å, b = 8.18493 Å and c = 7.50562 Å with β = 112.86938 ̊ [46]. Because the purity of the target was increased with increasing the reaction time to 15 h, the doping process was performed according to the reaction condition for the synthesis of S2. The PXRD patterns of the doped materials are shown in figure 2 c-f. The ionic radii of Bi3+, Sn4+, Y3+, Eu3+, Gd3+ and Yb3+ are 1.17, 0.69, 1.019, 1.066, 1.053 and 0.985 Å, respectively. So, it is desirable for the crystal system to accept the dopant ions in the eight coordinated cavity. The intercalation in the A position is confirmed by calculating the unit cell volume of the doped materials. The data show that no considerable change in the unit cell volume is observed. According to the PXRD data shown in Figure 2, it is clear that there is no impurity peak related to the dopant ions. Table 2 shows the crystallographic parameters and the rietveld refinement data of the obtained materials. The data show that the doping processes proceed in a way that an impurity peak corresponded to Bi2O3 is observed. The impurity amount is varied when the dopant ion type is changed. The purity data of the obtained materials reveal that when the ionic radius of the dopant ion is close to the ionic radius of Bi3+, the purity of the doped target is increased. So, the data show that when Yb3+ with high difference is doped into the crystal system, the purity is decreased more. However, the purities of Y3+, Gd3+ and Eu3+ - doped Bi2Sn2O7 nanomaterials are high because the difference between the ionic radii of dopant ions and Bi3+ is small. Table 2 displays the rietveld analyses data of the obtained targets. The data show the goodness of the fittings. It is clear that the crystal phase growth (Counts) of the obtained targets has an important influence on the goodness of the fitting.
The crystallographic data of the obtained samples are calculated and compared to the observed data presented in table 3.
Also, Table 3 shows the crystallite size data (D) of the obtained nanomaterials calculated by Scherrer equation:
In this equation, D is the entire thickness of the crystalline sample, λ is the X-ray diffraction wavelength (0.154 nm), K is the Scherrer constant (0.9), B1/2 of FWHM is the full width at half its maximum intensity and θ is the half diffraction angle at which the peak is located. The interplanar spacing values calculated using Bragg equation was also included in Table 3. The value of the dislocation density δ [(lines/m2)1014], which is related to the number of defects in the crystal was calculated from the average values of the grain size (D) by the relationship given below:
It was found that the dislocation density was increased when the dopant ions were introduced into the crystal system. However, the data show that doping the lanthanide ions into the crystal cavity increases the dislocation density considerably due to the decreasing the crystallite sizes of the materials. The strain ε (10–3) values are also determined using the following formula:
The variation in the strain as a function of the dopant ion type is included in Table 3. The increasing in the strain value with changing the dopant ion is probably due to the retrograde in the degree of the crystallite of the obtained target. However, when Y3+ is doped into the crystal system, the strain value is small. Besides, when the lanthanide ions are doped into the crystal system, the strain value is increased. This is maybe due to the lanthanide contraction effect of 4f energy level on the crystallite size.
The X-ray density (Dx) is calculated using the following formula:
Where M is the molecular weight of Bi2Sn2O7 (MW=867.34 gmol−1), N is the Avogadro number, and a, b and c are lattice parameters (Table 2). The data show that the X-ray density value is small and is not changed considerably by changing the dopant ions. This can be due to the similar/smaller atomic weight of the dopant ions compared to Sn or Bi, respectively, and incorporation of small amount of the dopant ion into the crystal system.
Figure 1. A Comparison among the PXRD patterns refined using the Rietveld method for the possible crystal system of S2. a) Orthorhombic, b) Monoclinic and c) Cubic crystal system.
Figure 2. PXRD patterns refined with the Rietveld analysis of a) S1, b) S2, c) S3, d) S4, e) S5 and f) S6.
The unit cell volume included in table 2 can be obtained from the bellow formula:
The interplanar spacing can be calculated from the below formula:
The highest intensity peak at 2θ ≈ 28.90 ᵒ, the (h k l) value of (0 4 4) was used in the above equation.
So,
Table 1. Comparison study for crystal system conformity for S2.
Crystal system | RF | RBragg | χ2 |
Orthorhombic | 1.10 | 1.53 | 2.00 |
Monoclinic | 2.02 | 3.08 | 2.98 |
Cubic | 3.60 | 4.97 | 17.5 |
Table 2. Rietveld analysis and unit cell parameters data of the obtained nanomaterials.
Sample | RF | RBragg | χ2 | a | b | c | Volume (Å)3 | Dx | Counts | Purity(%) |
S1 | 2.23 | 3.04 | 3.26 | 7.43443 | 21.44484 | 15.21620 | 2426 | 0.48 | 1723 | 72 |
S2 | 1.10 | 1.53 | 2.00 | 7.54632 | 21.51632 | 15.08011 | 2439 | 0.47 | 1836 | 100 |
S3 | 2.11 | 4.56 | 1.91 | 7.64699 | 21.10178 | 14.89042 | 2402 | 0.48 | 377 | 92 |
S4 | 1.17 | 1.76 | 1.84 | 7.60161 | 21.33780 | 15.14071 | 2455 | 0.47 | 1204 | 95 |
S5 | 2.17 | 3.61 | 2.29 | 7.66606 | 21.17765 | 14.92759 | 2423 | 0.48 | 746 | 94 |
S6 | 1.80 | 2.60 | 2.54 | 7.67314 | 21.38833 | 14.84477 | 2436 | 0.47 | 1354 | 87 |
Table 3. Crystallite size, interplanar spacing, dislocation density and strain data of the obtained nanomaterials.
Sample | 2θ | B (̊) | B (rad) | cosθ | Sinθ | D (nm) | δ (lines/m2) | e | dBragg (Å) | dCalc (Å) |
S1 | 29.2105 | 0.25441 | 0.004438 | 0.967686 | 0.25216 | 32 | 9.76 | 1.07 | 0.31 | 3.08 |
S2 | 28.9961 | 0.25415 | 0.004434 | 0.968156 | 0.25035 | 32 | 9.76 | 1.07 | 0.30 | 3.09 |
S3 | 29.3357 | 0.27346 | 0.004770 | 0.967410 | 0.25321 | 31 | 10.41 | 1.15 | 0.30 | 3.05 |
S4 | 28.9004 | 0.29085 | 0.005074 | 0.968365 | 0.24954 | 28 | 12.76 | 1.22 | 0.31 | 3.05 |
S5 | 29.2554 | 0.29552 | 0.005155 | 0.967587 | 0.25234 | 28 | 12.76 | 1.25 | 0.31 | 3.05 |
S6 | 29.2692 | 0.29112 | 0.005078 | 0.967557 | 0.25265 | 28 | 12.76 | 1.23 | 0.30 | 3.05 |
| H2O2 (mL) | Catalyst (mg) | Time (min) | Yield (%) |
Day 1 | 30 | 0.1 | 10 | 100 |
Day 1 | 20 | 0.075 | 25 | 98 |
Day 1 | 3 | 0.075 | 25 | 96 |
Day 1 | 20 | 0.075 | 25 | 98 |
Day 1 | 20 | 0.075 | 25 | 100 |
Day 1 | 10 | 0.05 | 40 | 97 |
Day 1 | 20 | 0.075 | 25 | 98 |
Day 1 | 37 | 0.075 | 25 | 100 |
Day 1 | 30 | 0.05 | 10 | 77 |
Day 1 | 10 | 0.05 | 10 | 24 |
Day 1 | 20 | 0.075 | 50 | 100 |
Day 1 | 20 | 0.03 | 25 | 60 |
Day 2 | 20 | 0.075 | 25 | 61 |
Day 2 | 20 | 0.075 | 25 | 92 |
Day 2 | 30 | 0.1 | 40 | 100 |
Day 2 | 20 | 0.075 | 1 | 4 |
Day 2 | 10 | 0.1 | 40 | 100 |
Day 2 | 30 | 0.05 | 40 | 100 |
Day 2 | 20 | 0.12 | 25 | 98 |
Day 2 | 10 | 0.1 | 10 | 47 |
Table 5. The experimental range and levels of independent variables in CCD.
Independent variables | Ranges and levels | ||||
| Low Actual | High Actual | Low Coded | High Coded | Mean |
(A) Catalyst (mg) | 10 | 30 | -1 | 1 | 20 |
(B) H2O2 (mL) | 0.05 | 0.1 | -1 | 1 | 0.075 |
(C) Time (min) | 10 | 40 | -1 | 1 | 25 |
Table 6. Analysis of variance for suggested model.
Source | squares | df | Mean squares | F value | P value |
|
Model | 12694.2 | 5 | 2538.83 | 12.99 | < 0.0001 | significant |
A-catalyst | 980.66 | 1 | 980.66 | 5.02 | 0.0419 |
|
B-H2O2 | 933.47 | 1 | 933.47 | 4.78 | 0.0464 |
|
C-Time | 7057.3 | 1 | 7057.3 | 36.1 | < 0.0001 |
|
AC | 1326.12 | 1 | 1326.12 | 6.78 | 0.0208 |
|
C2 | 2396.61 | 1 | 2396.61 | 12.26 | 0.0035 |
|
Residual | 2736.84 | 14 | 195.49 |
|
|
|
Lack of Fit | 1608 | 9 | 178.67 | 0.79 | 0.6425 | not significant |
Pure Error | 1128.83 | 5 | 225.77 |
|
|
|
Cor Total | 15431 | 19 |
|
|
|
|
To prepare 40 ppm of MG solution, 10 mg of MG powder was dissolved in 250 mL of distilled water. The pH value of the obtained solution was 4. To increase the pH value, we used a 0.01 M NaOH solution. According to the table 4, in a typical experiment, certain amount (g) of the as-synthesized Bi2Sn2O7 (S1) photocatalyt was added into 50 mL of MG solution and sonicated for 10 min in a dark room to establish an adsorption/desorption equilibrium between MG molecules and the surface of the photocatalyst. Afterwards, certain volume (mL) of H2O2 was added into the mixture solution followed by further magnetic stirring under solar light. When the designed time (min) was elapsed, the solution was drawn out and the photocatalyst was separated by centrifugation in order to measure the absorption spectrum of MG and calculate the MG concentration using UV-Vis spectroscopy. The photodegradation (%) of MG was calculated by the following formula:
(3)
where, A0 and At represent the initial absorbance of MG at 612 nm and the absorbance at time t, respectively.
Scheme 1 presents the general procedure for the photocatalytic degradation of MG by the as-synthesized nanomaterials.
Scheme 1. The general process for the photocatalytic degradation of malachite green.
Figure 6 shows the dye degradation graphs for the obtained material at the optimum conditions. Figure 6 a shows the effect of dye concentration on the degradation yield. It is clear that when the dye concentration is increased more up to 60 ppm, the degradation is decreased. It seems that when the dye concentration is high, light wavelength can not penetrate into the dye solution and the photocatalytic activity cannot be started efficiently. Figure 6 b shows the dye volume effect on the degradation yield. It indicates that the degradation is complete when dye volume is 50 mL; when the volume the dye volume is increased up to 70 mL, the yield is decreased, considerably. It is due to the decreasing the adsorption of dye on the catalyst; so the process is continued slowly at the desired time. Figure 6 c shows the effect of pH value on the degradation yield. Figure 6 c shows that the degradation yield is small at pH values up to 3. However, when the pH is increased up to 10, the degradation yield is increased. The yield is 100% at pH=4 to 10. It is due to the increased amount of OH- ion in the solution. Figure 6 d shows the comparison among the raw materials and the as-synthesized nanomaterial for the degradation yield. It shows that Bi2Sn2O7 efficiency for removal of MG is so higher than those for raw materials.
Figure 6. MG degradation (%) at different (a) dye concentrations, (b) dye volumes, (c) dye pH values and (d) comparison tests among the raw materials and Bi2Sn2O7.
3.4. Kinetic study
Studying the reaction kinetics is important for appointing the parameters affecting the reaction rate. This study finds a suitable kinetic model for the photo-catalytic degradation reaction. For this purpose, the rate constant (k) and the correlation coefficient (R2) of dye degradation is studied by zero- (Eq. (1)), first- (Eq. (2)), and second-order (Eq. (3)) kinetics.
[C]=-k0 t+[C] 0 (1)
ln [C] 0/[C] =k1 t (2)
1/[C] -1/[C] 0 =k2 t (3)
where C is the MG concentration in an aqueous solution at time t; C0 is the initial MG concentration; and k0 (mg. L-1min-1), k1 (min-1), and k2 (L .mg-1min-1) are the zero-, first-, and second-order rate constants, respectively. The results showed that the kinetics of the degradation using Bi2Sn2O7 followed a zero-order kinetic model.
By plotting [C] - [C0] versus t, a straight line was obtained (Figure 7). The slope of this line represents the apparent rate constant (kapp). Figure 7 shows that the photo-catalytic degradation fits to the Langmuir–Hinshelwood kinetic model. As a result of the data, the kinetic of degradation followed a pseudo-zero-order kinetic model. The amount of R2 and kapp are 0.075 and 0.972 for the dye concentrations of MG, respectively.
Figure 7. Plots of a) [C] – [C0], b) ln ([C0]/[C]), c) 1/[C] – 1/[C0] versus irradiation time and d) UV-visible absorption spectra for MG degradation.
To show the merit of the present work with the other reported photocatalytic degradation researches, we present a copmarison study among the yield in the present work with the other catalysts ﴾table 7).
Table 7. Comparison study for the degradation efficiency [44].
Catalyst | Condition | Yield (%) |
Bi2Sn2O7(Present work) | H2O2, 12 mg catalyst, 40 min, Natural ligth, 50 mL and 40 ppm MG | 100 |
Carbon/TiO2 | 25 ppm MG, 30 min, pH=8 | 82-100 |
MoS2/TiO2 | 40 min, sunlight irradiation, 0.1 g catalyst, 10 ppm MG | 97 |
PbCrO4 | 365 ppm MG, 0.1 g catalyst, 4 h, pH=7.5, visible light, 60 min | 90 |
Ni1-xCoxFe2O4 | Sunlight, 50 mL solution, 25 ppm catalyst, 1 µM MG, H2O2, 15 h | 100 |
Mg-doped TiO2 | Visible light, pH=9, 100 ppm MG | 89 |
ZnO | 4h time, 60 ppm MG, pH=7.5, solar radiation | 98 |
FeSO4 -7H2O | 10 mM Fe2+, 40 °C, 25.5mM H2O2, 10 ppm MG | 94 |
Sr2As2O7 | H2O2, 20 mg catalyst, 33 min, 70 mL of 100 ppm MG, solar light | 97 |
4. Conclusion
The present work reported the synthesis of Bi2Sn2O7 and Bi2MxSn2O7 (M= Y3+, Eu3+, Gd3+ and Yb3+) nanomaterials via a one-step solid state method at 800 ºC for 10 and 15 h. PXRD data showed that Bi2Sn2O7 was crystallized well in orthorhombic crystal system. Rietveld analysis data showed that when the reaction time was 15 h, the purity of the obtained target reached to 100 %. The doping process was performed according the reaction condition and the influence of the dopant ions on the particle size and optical band gap energy was studied. EDX analysis data revealed that dopant ion type had an important influence on the crystal system capacity to site the ions in the A or B position. The data showed that the obtained Bi2Sn2O7 nanomaterial had excellent efficiency for the removal of MG from aqueous solution. It was found that the optimum condition was 0.06 mL H2O2, 12 mg catalyst and 40 min. The degradation yield at the optimum condition was 100 % for S1. Several tests were performed for investigating the effect of different parameters on the degradation yield. It was found that the catalytic performance was excellent when the pH value was in the range of 4 to 10, the dye concentration was up to 60 ppm and the dye volume was up to 60 mL. The photo-catalytic degradation data showed that the kinetic of degradation followed a pseudo-zero-order kinetic model. The amount of R2 and kapp are 0.075 and 0.972 for the dye concentrations of MG, respectively.
Conflict of interest
The authors declare that they have no conflict of interest.
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