Free Chemicals - Sonoelectrochemical Treatment as a Biocompatible Procedure for Decolourization of Anthraquinone Dyes
Subject Areas : Dyes and Their IntermediatesMohammad Hassan Ehrampoosh 1 , Atefeh Rezaee 2 , M.A Ahmadabadi 3
1 - Department of Environmental Health Engineering, Shahid Sadoughi University of Medical Sciences, Yazd, Iran.
2 - Department of Environmental Health Engineering, Shahid Sadoughi University of Medical Sciences, Yazd, Iran.
3 - Research and Development Center, Nano Kimia Kavir Yazd Company, Yazd, Iran.
Keywords: Degradation, Sonoelectrochemical, Basic Blue 47, Free Chemicals,
Abstract :
Dye compounds are known as one of the most important environmental pollutants. Up to now, several methods have been offered to eliminate these pollutants from industrial wastes, especially in the textile industry. A method that has received a great deal of attention in recent years is the sonoelectrochemical method. In this study, using the Central Composite Design, the interactive effects of four essential variables such as pH, initial dye concentration, time, and applied potential on sonoelectrochemical decolorization of Basic Blue 47 were optimized and investigated.Based on the obtained results in the absence of oxidant agents, the best index for decolorization in optimal conditions includes pH of 9.0, initial dye concentration of 303.3 μM, time of 93 min, and potential of 0.81 V corresponding to the design by the CCD was 98%. It was experimentally found to be 96.0 %, and the Chemical Oxygen Demand (COD) was 97 %.
Eslami, A., Moradi, M., Ghanbari, F., Mehdipour, F., Decolorization and COD removal from real textile wastewater by chemical and electrochemical Fenton processes: a comparative study, J. Environ. Health. Sci. Eng., 2013, vol, 11, p. 1-8.
Saggioro, E., Oliveira, A., Buss, D., Magalhaes, D., Pavesi, T., Jimenez, M., Maldonado, M., Ferreira, L., Moreira, J., Photo-decolorization and ecotoxicological effects of solar compound parabolic collector pilot plant and artificial light photocatalysis of indigo carmine dye, Dyes. Pigments., 2015, vol. 113, p. 571-80.
Demir, N., Gunduz, G., Dukkancı, M., Degradation of a textile dye, Rhodamine 6G (Rh6G), by heterogeneous sonophotoFenton process in the presence of Fe-containing TiO2 catalysts Environ. Sci. Pollut. R. 2015, vol. 22, p. 3193-3201.
Yang, B., Zuo, J., Tang, X., Liu, F., Yu, X., Tang, X., Effective ultrasound electrochemical degradation of methylene blue wastewater using a nanocoated electrode, Ultrason. Sonochem., 2014, vol. 21, p. 1310-1317.
Haque, M., Smith, W. T., Wong, D.K.Y., Conducting polypyrrole films as a potential tool for electrochemical treatment of azo dyes in textile wastewaters, J. Hazard. Mater., 2015, vol. 283, p. 164-170.
Nava, L. J., Sires, I., Brillas, E., Electrochemical incineration of indigo. A comparative study between 2D (plate) and 3D (mesh) BDD anodes fitted into a filter-press reactor, Environ. Sci. Pollut. R., 2014, vol. 21, p. 8485-8492.
Tzikalos, N., Belessi, V., Lambropoulou, D., Photocatalytic degradation of Reactive Red 195 using anatase/brookite TiO2 mesoporous nanoparticles: Optimization using response surface methodology (RSM) and kinetics studies, Environ. Sci. Pollut. R., 2013, vol. 20, p. 2305-2320.
Thiam, A., Sires, I., Garrido, J. A., Rodriguez, R. M., Brillas, E., Decolorization and mineralization of Allura Red AC aqueous solutions by electrochemical advanced oxidation processes, J. Hazard. Mater., 2015, vol. 290, p. 34-42.
Saez, V., Esclapez, M. D., Tudela, I., Bonete, P., Louisnard, O., Gonzalez-Garcia, J., 20 kHz sonoelectrochemical degradation of perchloroethylene in sodium sulfate aqueous media: Influence of the operational variables in batch mode, J. Hazard. Mater., 2010, vol. 183, p. 648-654.
Araujo, C.K., Oliveira, G.R., Fernandes, N., Zanta, C.L.P.S., Castro, S., da Silva, D., Martinez-Huitle, C., Electrochemical removal of synthetic textile dyes from aqueous solutions using Ti/Pt anode: role of dye structure, Environ. Sci. Pollut. R., 2014, vol. 21, p. 9777-9784.
Gu, L., Zhu, N., Guo, H., Huang, S., Lou, Z., Yuan, H., Adsorption and Fenton-like degradation of naphthalene dye intermediate on sewage sludge derived porous carbon, J. Hazard. Mater., 2013, vol. 247, p. 145-153.
Diriba, D., Hussen, A., Rao, V.M., Removal of Nitrite from Aqueous Solution Using Sugarcane Bagasse and Wheat Straw, B. Environ. Contam. Tox., 2014, vol. 93, p. 126-131.
Chen, T.S., Huang, K.L., Chen, J.L., Electrochemical Approach to Simultaneous Determination of Acetaminophen and Ofloxacin, B. Environ. Contam. Tox., 2012, vol. 89, p. 1284-1288.
Bagastyo, A.Y., Batstone, D.J., Kristiana, I., Escher, B.I., Joll, C., Radjenovic, J., Electrochemical treatment of reverse osmosis concentrate on boron-doped electrodes in undivided and divided cell configurations, J. Hazard. Mater., 2014, vol. 279, p. 111-116.
Kiran, S., Ali, S., Asgher, M., Degradation and Mineralization of Azo Dye Reactive Blue 222 by Sequential Photo-Fenton’s Oxidation Followed by Aerobic Biological Treatment Using White Rot Fungi, B. Environ. Contam. Tox., 2013, vol. 90, p. 208-215.
Stadler, L.B., Su, L., Moline, C.J., Ernstoff, A.S., Aga, D.S., Love, N.G., Effect of redox conditions on pharmaceutical loss during biological wastewater treatment using sequencing batch reactors, J. Hazard. Mater., 2015, vol. 282, p. 106-115.
Wei, S., Hu, X., Liu, H., Wang, Q., He, C., Rapid degradation of Congo red by molecularly imprinted polypyrrole-coated magnetic TiO2 nanoparticles in dark at ambient conditions, J. Hazard. Mater. 2015, vol. 294, p. 168-176.
Iglesias, O., de Dios, M. A. F., Rosales, E., Pazos, M., Sanroman, M. A., Optimisation of decolourisation and degradation of Reactive Black 5 dye under electro-Fenton process using Fe alginate gel beads, Environ. Sci. Pollut. R., 2013, vol. 20, p. 2172-2183.
Rivera, M., Pazos, M., Sanroman, M., Improvement of dye electrochemical treatment by combination with ultrasound technique, J. Chem. Technol. Biot. 2009, vol. 84, p. 1118-1124.
Arat, C., Biçer, E., Electrochemical monitoring of decolorization of diazo dye Evans blue by Fenton process under anaerobic conditions: Kinetics and optimization, Russ. J. Electrochem., 2015, vol. 51, p. 730.
Mao, X., Tian, F., Gan, F., Lin, A., Zhang, X., Comparison of the performances of Ti/SnO2-Sb, Ti/SnO2-Sb/PbO2, and Nb/BDD anodes on electrochemical degradation of azo dye, Russ. J. Electrochem., 2008, vol. 44, p. 802.
Radi, M.A., Nasirizadeh, N., Rohani-Moghadam, M., Dehghani, M., The comparison of sonochemistry, electrochemistry and sonoelectrochemistry techniques on decolorization of C.I Reactive Blue 49, Ultrason. Sonochem. 2015, vol. 27, p. 609-615.
Weng, M., Zhou, Z., Zhang, Q., Electrochemical degradation of typical dyeing wastewater in aqueous solution: performance and mechanism, Int. J. Electrochem. Sci., 2013, vol. 8, p. 290-296.
Labiadh, L., Oturan, M.A., Panizza, M., Hamadi, N.B., Ammar, S., Complete removal of AHPS synthetic dye from water using new electro-fenton oxidation catalyzed by natural pyrite as heterogeneous catalyst, J. Hazard. Mater. 2015, vol. 297, p. 34-41.
Siddique, M., Farooq, R., Khan, Z.M., Khan, Z., Shaukat, S., Enhanced decomposition of reactive blue 19 dye in ultrasound assisted electrochemical reactor, Ultrason. Sonochem. 2011, vol. 18, p. 190-196.
Yaqub, A., Ajab, H., Applications of sonoelectrochemistry in wastewater treatment system, Rev. Chem. Eng., 2013, vol. 19, p. 123-130.
Thokchom, B., Kim, K., Park, J., Khim, Ultrasonically enhanced electrochemical oxidation of ibuprofen, J., Ultrason. Sonochem., 2015, vol. 22, p. 429-436.
Nasirizadeh, N., Dehghanizadeh, H., Yazdanshenas, M.E., Moghadam, M.R., Karimi, A., Optimization of wool dyeing with rutin as natural dye by central composite design method, Ind. Crop. Prod., 2012, vol. 40, p. 361-366.
Guimaraes, J.R., Maniero, M.G., de Araujo, R.N., A comparative study on the degradation of RB-19 dye in an aqueous medium by advanced oxidation processes, J. Environ. Manage., 2012, vol. 110, p. 33-39.
30. He, Z., Song, S., Zhou, H., Ying, H., Chen, J., CI Reactive Black 5 decolorization by combined sonolysis and ozonation, Ultrason. Sonochem., 2007, vol. 14, p. 298-304.
