Spatial distribution of (Ni, Cr, Pb, Cu and Co)in the Surface (Superficial) Soil of Hamadan county with Geostatistic & GIS
Subject Areas :
Water and Environment
parisa Farzaneh
1
,
ali reza Soffianian
2
,
faramarz Moattar
3
1 - MSc Student in environmental Pollution major, Basic Sciences School , Tehran Sciences and researches azad university
2 - Assistant. Prof.s. Department of Natural Resources, Isfahan University of Technology, Iran
3 - Environment Department Professor, Basic Sciences school, Tehran Sciences and researches azad university
Received: 2011-04-16
Accepted : 2012-02-04
Published : 2011-12-22
Keywords:
spatial distribution,
geostatistics,
Heavy Metals,
geographical information syste,
Hamadan county,
Abstract :
Introduction:
Heavy metals are one of the most important soil pollutants. The increased level of them in environment in respect to their stability has led to researchers’ attraction at recent decades. the principal goal of present study is to determine the spatial distribution of heavy metals (Ni, Cr, Pb, Cu and Co) in surface soil of Hamadan county.
Material and methods:
For this Sampling was carried out based on systematic method from depth 0-20cm. heavy metals concentration and soil characteristics including PH, silt,clay and sand percentage were measured. Interpolation for heavy metals levels concentrations were done by geo-statistics methods . Different elements were interpolated through Radial basic function(RBF), Ordinary and Disjunctive Kriging and inverse distance weighting .The method accuracies were compared by using mean absolute error and mean bayas error.
Results:
for heavy metal concentration maps, Cr,Co and Pb, we used (RBF),for Cu inverse distance weighting(IDW),for Ni ordinary kriging with exponential model. Overplaying heavy metals distribution maps with geology and land use maps showed that Cr, Co and Ni have geological origin, The highest levels of Lead concentration is controlled by geological formation, agricultural activities and also urban pollution.
Cu have originated from bed rock. But, excessive consumption of chemical fertilizers according to agricultural activities can increase most of these elements in soil.
References:
Bowen, H. J. M., 1979, The environmental chemistry of elements, Academic press, London, New York.
Lame and Leenaers. 1997. International Ash working group, EEA, 1999
Lindsay, W. L. 1979. Cemical Equation in soil. John Wiley & Sons, INC. New York.
Romic, M., Hengl, T., Romic, D., Husnjak, S., 2007. “Representing soil pollution by heavy metals using continuous limitation scores”, Compution Geoscince. Vol. 33, No. 10, pp. 1316-1326.
Facchinelli, A., Sacchi, E.& Mallen, L., 2001. Multivariate statistical and GIS –based approach to identify heavy metal sources in soils, Journal of Environmental Pollution, 114: 313-324
Romic, M., Hengl, T., Romic, D., Husnjak, S., 2007. “Representing soil pollution by heavy metals using continuous limitation scores”, Compution Geoscince. Vol. 33, No. 10, pp. 1316-1326.
Krishna, A. K., Goil, P. K., 2005. Heavy metal distribution and contamination in soils of Thane-Belapur industrial development area, Mumbai, Western India, Journal of Enviromental Geology. 47 : 1054-1061
Shi, J., Wang, H., Xu, f, Wu, J., Liu, x., Zhu, H. and Yu, c., 2007, “Spatial - distribution of heavy metals in soils: a case study of Changxing, China”, Environ. Geol., Vol. 52, pp. 1-10.
بدری، ا. م.، حیدرنیا فتحآباد، ز.، و کریمینیا، ح. ر.، 1389، بررسی استانداردهای آلودگی خاک در دنیا و ایران، چهارمین همایش مهندسی محیط زیست، دانشگاه تهران.
Kabata-Pendias, A. and Mukherjee, A. B., 2007, Trace Elements from Soil to Human, Springer-Verlag Berlin Heidelberg New York.
شیرانی، م.، 1386، تغییرات مکانی سرب، کادمیوم، نیکل و روی در برخی خاکهای کشاورزی، صنعتی و شهری محدوده بزرگ مشهد- چناران، پایان نامه کارشناسی ارشد خاکشناسی، دانشکده کشاورزی، دانشگاه فردوسی مشهد، 92 صفحه.
موحدیراد، ز.، 1386، بررسی تغییرات مکانی روی، سرب، نیکل و کادمیوم در خاکهای بخشی از استان قم، پایان نامه کارشناسی ارشد خاکشناسی، دانشکده کشاورزی، دانشکده صنعتی اصفهان، 173 صفحه.
Manta, D. S., Angelone, M., Bellanca, A., Neri, R. and Sprovieri, M., 2002, “Heavy metals in urban soils: a case study from the city of Palermo (Sicily), Italy”, The Science of The Total Environment, Vol. 300, No. 1-3, pp. 229-243.
Rodriguez Martin, J. A., Arias, M. L. and Grau Corbi, J. M., 2006, “Heavy metals contents in agricultural topsoils in the Ebro basin (Spain). Application of the multivariate geoestatistical methods to study spatial variations”, Environmental Pollution, Vol. 144, No. 3, pp. 1001-1012.
34. De vos, W., Batista,. M. J., Demetriades, A., Duris, M. J., Lexa, J., Lis, J., Sina, K. O., connor, P. J., Metallogenic Mineral Provinces and World Class Ore Deposits in Europe, In: Geochemical Atlas of Europe. Part 1 Background Information, Methodology and Maps, by Salminen, R., 2005. Geological Survey of Finland.[Online] Availability
Luis, R.L., Tomislav, H., Hannes, LR., 2008, “Heavy metal; in European soils: A geostatistical analysis of the FOREGS Geochemical database”, Geoderma, Vol. 148, pp. l89-199.
محمدی، ج.، 1381، "پهنه بندی و ارزیابی آلودگی خاک با استفاده از نظریه مجموعه های فازی"، گزارش سومین همایش مجموعه های فازی و کاربردهای آن، 139-133.
Cattle, J. A, M. A., Minasny, B., 2002. “Kriging method evaluation for assessing the spatial distribution of urban soil lead contamination”. Journal of Enviromental Quality. Vol. 31, pp. 1576-1588.
Wrrick,W., Myers. D. E., Neilson. D. R., 1986. Geostatistical methods applied to soil science, Method of soil analysis, part 1, physical and mineralogical methods,Journal of Argonomy Monograph, 9 (2) : 53-81.
Koutev, V., Julien, P, 2001. Spatial variability of total and bioavailable Zn in the Canton of Fribourg Switzerland . Swiss Federal Institute of Technology, PP:189-190
Martin, J. A., Arias, M. L., Grau, C, J. M., 2006. “Heavy metals contents in agricultural topsoils in the Ebro basin (Spain). Application of the multivariate geoestatistical methods to study spatial variations”. Enviromental Pollution. Vol. 144, No. 3, pp. 1001-1012.
بینام، 1386، مطالعات مکان یابی محلهای دفن و دفن پسماندهای ویژه در استان همدان، گزارشات هواشناسی، هیدرولوژی، زمین شناسی، خاک شناسی، تکتونیک- لرزه خیزی، تلفیق و GIS، سازمان حفاظت محیط زیست، دفتر بررسی آلودگی آب و خاک، معاونت پژوهشی دانشگاه شهید بهشتی
حسنی پاک،1377، زمین آمار (ژئواستاتیستیک)، انتشارات دانشگاه تهران، 306 صفحه.
Cao, H. F., Change, A. C., A. L., 1984. “Heavy Metal Contents of Sludge-Treated Soils as Determined by Three Extraction Procedures”. Enviromental Quality. Vol. 13, No. 4, pp. 632-634
Weaver, R.W., Angle J. S., Bottomley P.S., 1994. Methods of soil analysis, microbiological and biochemical properties, part II, Soil Science of America INC, Wisconsia, USA, 1097 pp
مدنی، ح.، 1373، مبانی زمین آمار، انتشارات دانشگاه صنعتی امیر کبیر واحد تفرش، 659 صفحه
Yang, P., R. Mao, H. Shaom., Y. Gao., 2009. An investigation on the distribution of eight hazardous heavy metals in the suburban farmland of china, Journal of Hazardous Material. 167 : 1246–1251
Goovaerts, P., 1997. Geostatistics for Natural Resources Evaluation. Oxford Univ. Press, New York, 512 pp.
Kabata Pendias, A., Pendias, H, 2001. Trace Elements in Soil and Plants, 3rd Ed. Boca Raton London, New York Washington,D. C, 400pp
خسروی دهکردی، ا.، 1387، توزیع مکانی فلزات سنگین در خاکهای کشاورزی، شهری و صنعتی اصفهان، پایان نامه کارشناسی ارشد محیط زیست، دانشکده منابع طبیعی، دانشگاه صنعتی اصفهان، 89 صفحه
دیانی، م.، محمدی، ج. و نادری، م.، 1388، "تجزیه و تحلیل زمین آماری غلظت سرب، روی و کادمیوم در خاک های حومه سپاهان شهر واقع در جنوب اصفهان"، نشریه آب و خاک، جلد 23، شماره 4، صفحه 67-76.
De Temmerman, L., Vanongeval, L., Boon, W., Hoenig, M., Geypens, M., 2003. “Heavy Metal Content of Arable Soils in Northern Belgium”. Water, Air, & Soil Pollution. Vol. 148, No. 1, pp. 61-76.
Chen, M., Ma, L. Q., Harris, W. G., 1999. “Baseline concentrations of 15 trace elements in Florida surface soils”. Journal of Enviromental Quality. Vol. 28, No. 4, pp. 1173-1181.
Acosta, J., Faz, A. and Martinez-Martinez, S., 2010. “Identification of heavy metal sources by multivariable analysis in a typical Mediterranean city (SE Spain)”. Environmental Monitoring Assessment. Vol. 169, No. 1, pp. 519-530
Alloway, B. J., 1990. Heavy Metal in Soils, Blackie and Son, Ltd. Glasgow and London. 339 Pages
Mico, C., Recatala. L., Peris. M., Sanchez, J., 2006. Assessing heavy metal sources in agricultural soils of an European Mediterranean area by multivariate analysis, Journal of Chemosphere, 65 : 863–872.
Gregori, J. D., Fuentes, E., Rojas, M., Pinocheta, H. and Potin-Gautier, M. , 2003, “Monitoring of copper, arsenic and antimony levels in agricultural soils impacted and non-impacted by mining activities, from three regions in Chile”, Environ. Monit., Vol. 5, pp. 287-295