Investigation on Heavy Metals Concentrations and Determination of Their Relations with Soil Properties around Hashtrood Town, East Azerbaijan Province

Subject Areas : environmental management

Azita Behbahaninia ¹ (Assistant Professor of environmental, Islamic azad university, Roudehen branch, Iran *(Corresponding Author))
Ramin Salmasi ² (Member of the Science Board, Agricultural and Natural Resource Centre, Tabriz, East Azerbaijan)

Received: 2011-07-09 Accepted : 2011-12-10 Published : 2016-06-21

Keywords: Heavy Metals, cluster analysis, Environment, Soil Properties,

Abstract :

Background and Objective: Arsenic pollution in Hashtrood city was reported. Primary experiments of the stream water samples showed several times concentrations than standard. Total Contents of heavy metal in the soils of polluted villages of Hashtrood city and determining the relationships of these metals and soil properties are the goals of this research.  Method: After field investigations and the soil sampling and analysis of soil physic-chemical properties and heavy metals, correlation coefficients and cluster analysis of data were determined. Findings: Cu with OC and Al, Cr, and Mn with clay percentages of soil samples had positive correlation. Five main clusters were determined with cluster analysis that were in agreement with correlation coefficients. Discussion and Counclusion: Low range of the soil pHs causes low correlation between soil heavy metals and pH. Selective adsorption of Cu by soil organic component is the reason of high correlation of this metal with soil organic matter. Positive correlations between clay and OC of the soil samples with some metals, indicate that these 2 soil components with metals fixing, reduce their release into environment. Other researches are necessary to determine geology and anthropogenic sources of these metals.    

References:

1. Brooks R, 1983. Biological methods of prospecting for minerals. Wiley, New York.


2. Gil C Boluda, R., Ramos J, 2004. Determination and evaluation of Cd, Pb, and Ni in greenhouse soils of Almeria (Spain). chemosphere, 55: 1027- 1034.


3. Chen M Lena Q M  Harris W G, 1999. Baseline concentrations of 15 trace elements in Florida surface soils. J. Env. Quail., 28: 1173-1181.


4. Merian, E., Anke M., Inhat M., and Stoeppler, M., 2004. Elements and their compounds in the environment. Wiley VCH, Weinheim, Germany.


5. Smedley P, 2004. Arsenic occurrence in groundwater in South and East Asia – Scale, causes and mitigation. Technical Report, Vol. II, The World Bank, Report no. 31303.


6. حاجی زاده، هادى؛ کرمی، غلامحسین؛ سعادت، سعید؛ 1384. ارزیابى میزان آلایندگى عناصر سنگین در خاکهاى منطقه افیولیتى فیروزآباد شاهرود، سازمان زمین شناسى کشور، بیست و چهارمین گردهمایى علوم زمین شناسى، سازمان زمین‌شناسی کشور.


7. طلایی، علیرضا؛ 1386. بررسی نقش مناطق معدنی شمال مشگین‌شهر بر میزان آلودگی خاک‌ها به عنصر آرسنیک، دهمین کنگره علوم خاک ایران، دانشگاه تهران، قطب علمی و گروه مهندسی علوم خاک.


8. Lacatusu, R.,. Soil-plant-man relationship in heavy metal polluted areas in Romania.App Geochemistry, 1996; 11:105-107.


9. Chaosheng Zhang, 2006, Using multivariate analyses and GIS to identify pollutants and their spatial patterns in urban soils in Galway, Ireland, Environmental Pollution 142, 501-511.


10. Tao Chen, Xingmei Liu, Muzhi Zhu, Keli Zhao, Jianjun Wu, Jianming Xu, Panming Huang, 2008. Identification of trace element sources and associated risk assessment in vegetable soils of the urban-rural transitional area of Hangzhou, China. Environmental Pollution 151, 67-78.


11. Magalhaes, V.F. 2007. As concentration and distribution in Engenho Inlet,Sepetiba Bay,Brazil,Water,Air and Soil pollution,18:83-91.


12. Hans-Rudolf Pfeifer, Anne Häussermann Jean-Claude Lavanchy, Werner Halter, 2007, Distribution and behavior of arsenic in soils and waters in the vicinity of the former gold-arsenic mine of Salanfe, Western Switzerland, Journal of Geochemical Exploration 93, 121–134.


13. مسافری، محمد، تقی پور، حسن، 1388. بررسی میزان ارسنیک در آب آشامیدنی، یک مثال موردی. مجله سلامت و محیط. جلد 1، ص. 28-19.


14. Black C A, 1965.  Methods of soil analysis, Part 2, 2ed edition, Agronomy Mono. 9, SA., Madison WI.


15. Page A L, 1965.  Methods of soil analysis, Part 1, 2ed edition, Agronomy Mono. 9, SA., Madison WI.


16. موسسه حفاظت خاک و آب، 1379. مطالعات خاک شناسی و طبقه بندی هشترد، استان آذربایجان شرقی.


17. Mico, C., Recatala, L., Peris, M., Sanchez, J., 2006. Assessing heavy metal sources in agricultural sources of an European Mediterranean area by multivariate analysis. Chemosphere 65, 863-872.


18. Tume P, Bech J, and Logan, L. 2006. Trace elements in natural surface soils in Sant client. Ecol. Eng., 27: 145-152.


19. Manta, D. S., Angelone, M., Bellanca, A., Neri, r., sprovieri, m., 2002. Heavy metals in urban soils: a case study from a city of  Palermo (Sicily), Italy. Sci. Tot. Environ. 30, 229-243.


20. Mclaren, R. G., Williams, J. g. Swift, R. S., 1983. The adsorption of Cu by soil samples from Scotland at low equilibrium concentrations. Geoderma, 31: 97-106.


21. Lund l J, Betty E E, Page A L, Elliot R A, 1981. occurrence of high Cd levels in soil and its accumulation by vegetation. J. Environ. Qual. 10: 551-556.


22. Zayed A M, & Terry N. 2003. Chromium in the environment: factors affecting biological remediation. Plant Soil, 249: 139-156.  


23. Covelo E F Vega F A  Andrade M L, 2007. Simultaneous sorption and desorption of Cd, Cr, Cu, Ni, Pb, and Zn in acid soils. J. Hazardous mat. 147: 862-870. 24- Lindsay W L, 1979. Chemical equilibria in soils. John Wiley and sons, NewYork, United States.