Studying the effect of beta-cyclodextrin natural polymer for improving dyeing condition and reduction of environmental pollution
Subject Areas : BIotecnologyakhtar mousavi 1 , ahmad akbari 2 , seyed kazem mousavi 3
1 - PH. D Student, Department of Art Research, Faculty of Research Excellence in Art and Entrepreneurship, Art University of Isfahan, Iran.*(Corresponding Author)
2 - Professor of Chemical Textile Engineering Carpet Department / Institute of Nanoscience and Nanotechnology Kashan University, Iran.
3 - PH. D, Department of Environmental Management, Department of Natural Resources and Environment, Science and Research Branch, Islamic Azad University, Tehran, Iran.
Keywords: β-Cyclodextrin, Environment, Dyeing, pollution, Wastewater,
Abstract :
Background and Objective: environmental and economic limitations that are imposed dramatically on textile and dyeing industry leads to the development of environmentally friendly processes for modifying the properties of fibers and improving the existing traditional processes. Many efforts have been done for decreasing costs and disposed contaminants which one of them is using natural polymers. The purpose of this study is applying beta-cyclodextrin natural polymer as an appropriate alternative with favorable environmental effects for other chemical additives in dyeing. Material and Methodology: In this study, wool fiber amended/treated by β-Cyclodextrin biocompatible polymer and its dyeing features such as the effect of β-Cyclodextrin composition (%20-0/5), dyeing pH (3-7) and density of the dye (%5-75) on the dyeing capabilities of wool with madder dye color was evaluated and compared. And finally, physical changes of crude fiber and amended fiber after dyeing was amended/treated using SEM analysis. Findings: According to the results, as the β-Cyclodextrin amount increased, the color strength of the samples are considerably enhanced and dye ability (K/S) is better in the case of modified wool rather than aluminium-mordanted wool and pristine wool. Besides, exhaustion of modified wool in neutral pH rather than acidic pH has been increased dramatically while no appreciable changes was observed in pristine wool dye ability with pH changes. Color strength (K/S) data were in the following order of the β-Cyclodextrin modified wool>. Discussion and Conclusions: In general, according to the conditions of modifying wool with β-Cyclodextrin biocompatible polymer and changes in dyeing conditions, not only removing chemical compounds from the wastewater of textile industrial can beapplied, but also the amount of consumed dye and unabsorbed dye remaining in wastewater can be reduced which is environmentally very important.
1. Jamil, A., Bokhari, T. H., Javed, T., Mustafa, R., Sajid, M., Noreen, S., & Jilani, M. I. 2020. Photocatalytic degradation of disperse dye Violet-26 using TiO2 and ZnO nanomaterials and process variable optimization. Journal of Materials Research and Technology, 9(1), 1119-1128.
2. Khan, S., & Malik, A. 2018. Toxicity evaluation of textile effluents and role of native soil bacterium in biodegradation of a textile dye. Environmental Science and Pollution Research, 25, 4446-4458.
3. Fu, Z., & Xi, S. 2020. The effects of heavy metals on human metabolism. Toxicology mechanisms and methods, 30(3), 167-176.
4. Ali, H., Khan, E., & Ilahi, I. 2019. Environmental chemistry and ecotoxicology of hazardous heavy metals: environmental persistence, toxicity, and bioaccumulation. Journal of chemistry, 2019.
5. Haji, A., Amiri, Z., Qavamnia, S., 2014. Natural dyeing of wool with Arnebia euchroma optimized by plasma treatment and response surface methodology. J. Biodiversity Environ. Sci. Vol. 5, pp. 493-498.
6. Haji, A. 2020. Functional Finishing of Textiles with β‐Cyclodextrin. Frontiers of Textile Materials: Polymers, Nanomaterials, Enzymes, and Advanced Modification Techniques, 87-116.
7. De Laender, E, 2010. Cyclodextrin-grafted cotton gauzes as drug delivery devices. Doctoral dissertation, Ghent University.
8. Shafei, A. El., Shaarawy, S., Hebeish, A., 2010. Application of reactive cyclodextrin poly butyl acrylate preformed polymers containing nano-ZnO to cotton fabrics and their impact on fabric performance. Carbohydr. Polym. Vol. 79, pp. 852-857.
9. Deng, J., Chen, Q. J., Li, W., Zuberi, Z., Feng, J. X., Lin, Q. L., ... & Zheng, X. M. 2021. Toward improvements for carrying capacity of the cyclodextrin-based nanosponges: recent progress from a material and drug delivery. Journal of Materials Science, 56, 5995-6015.
10. Abdel-Halim, E. S., Abdel-Mohdy, F. A., Fouda, M. M., El-Sawy, S. M., Hamdy, I. A., Al-Deyab, S. S., 2011. Antimicrobial activity of monochlorotriazinyl-β-cyclodextrin/ chlorohexidin diacetate finished cotton fabrics. Carbohydr. Polym. Vol. 86, pp. 1389-1394.
11. Suvarna, V., & Chippa, S. 2023. Current Overview of Cyclodextrin Inclusion Complexes of Volatile Oils and their Constituents. Current Drug Delivery, 20(6), 770-791.
12. Abdel-Halim, E. S., Fouda, M. M., Hamdy, I. A., Abdel-Mohdy, F. A., El-Sawy, S. M., 2010. Incorporation of chlorohexidin diacetate into cotton fabrics grafted with glycidyl methacrylate and cyclodextrin. Carbohydr Polym. Vol. 79, PP. 47-53.
13. Kadam, V., Truong, Y. B., Easton, C., Mukherjee, S., Wang, L., Padhye, R., & Kyratzis, I. L. 2018. Electrospun polyacrylonitrile/β-cyclodextrin composite membranes for simultaneous air filtration and adsorption of volatile organic compounds. ACS Applied Nano Materials, 1(8), 4268-4277.
14. Carpignano, R., Parlati, S., Piccinini, P., Savarino, P., De, M. R., Giorgi, R, Fochi, 2010. Use of β-cyclodextrin in the dyeing of polyester with low environmental impact. Color. Technol. Vol. 126, PP. 201–208.
15. El-Sayed, E., A Othman, H., & Hassabo, A. G. 2021. Cyclodextrin usage in textile Industry. Journal of Textiles, Coloration and Polymer Science, 18(2), 111-119.
16. Rehan, M., Mahmoud, S. A., Mashaly, H. M., & Youssef, B. M. 2020. β-Cyclodextrin assisted simultaneous preparation and dyeing acid dyes onto cotton fabric. Reactive and Functional Polymers, 151, 104573.
17. Dehabadi,V., Buschmann, H.-J., Gutmann, J., 2013. A novel approach for fixation of β-cyclodextrin on cotton fabrics, Journal of Inclusion Phenomena and Macrocyclic Chemistry, Vol. 79, pp 459–464.
18. Dhiman, P., & Bhatia, M. 2020. Pharmaceutical applications of cyclodextrins and their derivatives. Journal of Inclusion Phenomena and Macrocyclic Chemistry, 98, 171-186.
19. Bhaskara-Amrit, U.R., Agrawal, P.B., Warmoeskerken, M.M., 2011. Application of b –Cyclodexterins In Textiles, Autex Research Journal, Vol. 11, pp. 94-101.
20. Bezerra, F. M., Lis, M. J., Firmino, H. B., Dias da Silva, J. G., Curto Valle, R. D. C. S., Borges Valle, J. A., ... & Tessaro, A. L. 2020. The role of β-cyclodextrin in the textile industry. Molecules, 25(16), 3624.
21. Baig, N., Kammakakam, I., & Falath, W. 2021. Nanomaterials: A review of synthesis methods, properties, recent progress, and challenges. Materials Advances, 2(6), 1821-1871.
