Efficiency of Combination Powder Activated Carbon Magnetized by Fe3O4 Nanoparticles for Removal of Cadmium from Aqueous Solutions with the Response Surface Methodology (RSM) Box – Behnken design (BBD)
Subject Areas : Environment Pullotion (water and wastewater)Khoshnaz Pyandeh 1 , Sadegh Ghasemi 2
1 - Assistant Professor, Department of Soil Science, Ahvaz Branch, Islamic Azad University, Ahvaz, Iran
2 - Young Researchers and Elite Club, Ahvaz Branch, Islamic Azad University, Ahvaz, Iran
Keywords: Heavy metal, Removal of pollutant, magnetic activated carbon,
Abstract :
Background and Objective: Due to its low cost, simplicity and speed of separation and high efficiency, the magnetic separation method widely used to remove contaminants and to solve the problems of the environment. The aim of this study was synthesis of magnetic activated carbon by Fe3O4 and investigating its efficiency in adsorption of Cadmium from aqueous solutions. Method: Magnetic adsorbent prepared by the method of sequestration and physical characteristics and structure of synthesized absorbent were determined by XRD, SEM and TEM. To remove the Cadmium from aqueous solutions, the Box-behnken design (BBD) of response surface methodology (RSM) was employed for optimizing all parameters affecting the adsorption process. The studied parameters were pH (5-9), temperature (25-45 0C) and the amount of adsorbent (0.5-2 g). 15 experimental runs were calculated by using BBD. Findings: The optimal condition for removal Cadmium by synthesis of magnetic activated carbon by Fe3O4 nanoparticles were pH=7, 450C temperature and the 2 g of adsorbent. Discussion and conclusion: The study showed that magnetic activated carbon has a high potential for removing cadmium. Therefore, it is believed that magnetized active carbon by keeping its physical and surface properties could be a suitable method to solve some related problems including separation and filtration.
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- Jafari, N., Ahmadi asbchin, S., 2014. Adsorption of cadmium and lead ions from aqueous solution by brown algae Cystoseira indica. Journal Plant Researches, Vol. 27(1), pp. 23-31.
- Ghasemi, S., MafiGholami, R., 2014. Cadmium removal by Ziziphus sawdust and determination of isotherms and kinetic of adsorption process. Journal of Wetland Ecobiology, Vol. 7(3), pp. 67-80.
- Shakibayi, MR., Khosravan, A., Farahmand, A., Zare, S., 2009. Remove the heavy metals copper and zinc from industrial waste from factories of Kerman by bacteria resistant mutant absorbing metal. Journal of Kerman University of Medical Sciences, Vol. 16(1), pp. 13-34.
- Mohammadi, M., Fotovat, A., Haghniya, G., 2009. Efficiency of sand - soil - organic matter filter, the removal of heavy metals copper, nickel, zinc and chromium from industrial wastewater. Journal of Soil and Water (Agricultural Science and Technology), Vol. 262, pp. 23-51.
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- Shokohi, R., Ehsani, H., Tarlani azar, M., 2014. Removal of Lead and Cadmium by Coral Limestone Granules of Aquatic Solutions. Journal of Environmental Science and Technology. Vol. 16(1), pp. 109-121.
- Ghasemi, S., MafiGholami, R., 2015. Lead Adsorption from Synthetic Wastewater by Prosopis Mimosaceae Sawdust. Jundishapur J Health Sci, Vol. 7(1), pp. 1-7.
- Prasad, M., Saxena, S., 2004. Sorption mechanism of some divalent metal ions onto low-cost mineral adsorbent. Industrial & Engineering Chemistry Research, Vol. 43(6), pp. 1512-1522.
- Chang, Y.-C., Chen, D.-H., 2005. Preparation and adsorption properties of monodisperse chitosan-bound Fe 3 O 4 magnetic nanoparticles for removal of Cu (II) ions. Journal of Colloid and Interface Science, Vol. 283(2), pp. 446-451.
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- Ge, F., Li, M., Ye, H., Zhao, B.,2012. Effective removal of heavy metal ions Cd2+, Zn2+, Pb2+, Cu2+. J. Hazardous Materials, Vol. 211, pp. 366-372.