Influence of low temperature annealing on structural, optoelectrical and morphological properties of In2S3 thin films grown by thermal evaporation method with Bk7 substrate
Subject Areas : journal of New Materials
1 - Department of solid state physics, Marv.C., Islamic Azad University, Marvdasht, Iran
Keywords: Thin films, Indium sulfide, Thermal annealing, Raman spectroscopy, Thin films solar cell.,
Abstract :
In thin-film solar cells based on multi-component semiconductors like CuInₓGaₓ₋₁Se₂ (CIGS), the buffer layer between the p-type absorber and low-resistance n-type layer plays a crucial role. Typically, n-conductive buffer layers employ wide-bandgap semiconductors such as cadmium sulfide (CdS) deposited from chemical solutions. Chemically vapor-deposited CdS layers (40-100 nm thick) in CIGS solar cells have achieved ~21% conversion efficiency. However, due to CdS toxicity, researchers are seeking alternative materials. Current investigations focus on B32C63 semiconductor compounds (where B32 = Al/Ga/In and C63 = S/Se/Te) for developing radiation-resistant, high-efficiency thin-film solar cells. Among these, the binary compound In2S3 has shown particular promise. This study aims to obtain new data on the microstructure and optical properties of In2S3 thin films as functions of deposition methods, with potential implications for advancing thin-film photovoltaic technology.
1. Reddy KK, Reddy PR, Reddy PS. Annealing temperature induced phase transformation in In₂S₃ thin films and its impact on
optical and electrical properties. Journal of Alloys and Compounds.* 2020;831:154788. 2. Souilah M, Lafane S, Abdelli-Messaci S, Kerdja T. Structural and optical properties of thermally evaporated In₂S₃ thin films:
Effect of annealing in sulfur atmosphere. Materials Science in Semiconductor Processing. 2019;101:32–39. 3. Ouerghi A, Ben Nasr T, Turki-Kamoun N. Effect of post-deposition annealing on the properties of In₂S₃ thin films for
photovoltaic applications. Thin Solid Films. 2021;732:138780. 4. Mariappan R, Ponnuswamy V, Ragavendar M, Chandra Bose A. Thermal annealing induced enhancement in the optical and electrical properties of In₂S₃ thin films deposited by thermal evaporation. Journal of Materials Science: Materials in
Electronics. 2018;29(12):10296–10304. 5. Gedi S, Reddy VRM, Pejjai B, Park C. Impact of annealing on the microstructural and optoelectronic properties of
thermally evaporated In₂S₃ thin films for buffer layer applications. Solar Energy Materials and Solar Cells. 2016;157:28–36. 6. Nguyen TKT, Le HT, Dao VA, Choi J, Yi J. Tuning the optical bandgap and microstructure of In₂S₃ thin films through post-
deposition annealing for solar cell applications. Applied Surface Science. 2022;571:151324. 7. Moutinho HR, Dhere RG, Jiang CS, Al-Jassim MM. Effects of annealing on the properties of In₂S₃ thin films grown by
thermal evaporation. Journal of Vacuum Science & Technology A. 2015;33(2):021502. 8. Pathan, H.M., Lokhande, C.D., Kulkarni, S.S., Amalnerkar, D.P., Seth, T. and Sung-Hwan, Han. (2005). Materials Research
Bulletin, 40(6), 1018. 9. Ranjith, R., Teny Theresa John, Sudha Kartha, C., Vijayakumar, K.P., Abe, T. and Kashiwaba, Y. (2007). “Post-deposition annealing effect on In2S3 thin films deposited using SILAR technique”, Materials Science in Semiconductor Processing, 10(1),
49. 10. Bhira, L., Essaidi, H., Belgacem, S., Couturier, G., Salardenne, J., Barreau, N. and Bernede, J. C. (2000). Phys. Status Solidi
A. 181, 427. 11. Izadneshan H, Gremenok VF. Influence of annealing on the optical parameters of In₂S₃ thin films produced by thermal
evaporation. Journal of Applied Spectroscopy. 2014;81(2):297-300.