Studying the Effect of the Presence of Different Amounts of Bioactive Glass on the Physical and Mechanical Properties of the Nanocomposite Coating Based on Polycaprolactone-Chitosan-58S Bioactive Glass

Subject Areas :

Mohammad Hosein Haddadi ¹ , Ebrahim Karamian ² , Hamid Reza Bakhsheshi Rad ³ , Masoud KasiriAsgarani ⁴

1 - Advanced Materials Research Center, Department of Materials Engineering, Najafabad Branch, Islamic Azad University, Najafabad, Iran
2 - Advanced Materials Research Center, Department of Materials Engineering, Najafabad Branch, Islamic Azad University, Najafabad, Iran
3 - Advanced Materials Research Center, Department of Materials Engineering, Najafabad Branch, Islamic Azad University, Najafabad, Iran
4 - Advanced Materials Research Center, Department of Materials Engineering, Najafabad Branch, Islamic Azad University, Najafabad, Iran.

Received: 2024-10-31 Accepted : 2025-01-08 Published : 2025-09-15

Keywords: Polycaprolactone Chitosan Physical and Mechanical Properties 58S Bioactive Glass,

Abstract :

In this research, nanocomposite coating based on polycaprolactone-chitosan was prepared in the presence of zero, one, three and five weight percent of 58S bioactive glass synthesized by sol-gel method, and the effect of the presence different amounts of bioactive glass were evaluated on contact angle, water absorption, surface roughness, tensile strength and corrosion behavior by metallurgical characterization. According to the results of the contact angle tests, the percentage of water absorption, surface roughness and tensile strength in the synthesized samples, the increase in hydrophilicity due to the decrease in the contact angle (3.2 and 5.6 percent), the increase in water absorption (13.14 and 23.21 percent), an increase in surface roughness (70.16 and 148.44 percent) and an increase in tensile strength (45.26 and 48.70 percent) were reported in PCB3 and PCB5 samples, respectively, compared to PCB0. According to the results of electrochemical impedance spectroscopy and linear polarization test of the PCB3 sample, an increase in the corrosion potential of the coating up to -0.29 V and a decrease in the corrosion current density up to 2.05 microamps per cubic centimeter was reported compared to other samples. Therefore, according to the results of the research, the presence of the optimal amount of 3% by weight of bioactive glass leads to the improvement of the physical and mechanical properties of the investigated coating by increasing the corrosion resistance of the coating, reduction of the contact angle, increasing the percentage of water absorption, hydrophilicity, and surface roughness in The sample was PCB3.

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