Investigation of Wear Resistance and Corrosion of Ni-P-PTFE Composite Coatings Prepared by Electrodeposition Method
Subject Areas : Composite materials
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Keywords: Electrodeposition, Composite Coatings, PTFE, Wear, Corrosion, EIS.,
Abstract :
Coating is one of the effective ways to increase the corrosion resistance and wear of metallic substrates. Additionally, the composite coatings using nanoparticles can also further protect the substrate. In this study, using electrodeposition process and polytetrafluoroethylene (PTFE) particles (with concentrations of 10, 20 or 30 g /L), Ni- PTFE coatings were prepared and their corrosion and wear properties were investigated and compared with Ni-P coating. Using scanning electron microscopy (SEM) and X-ray diffraction (EDS) method, the surface morphology and elemental composition of the coatings were analyzed and finally, by using open circuit potential (OCP) techniques, electrochemical impedance spectroscopy (EIS) and TAFEL polarization techniques, the corrosion resistance of the resulting coatings in 3/5 wt.% NaCl solution were evaluated. Microhardness and pin on disk tests were also utilized to investigate the effect of PTFE concentration on the tribological properties of the coatings. The results of SEM and EDS studies confirmed the formation of nanocomposites. Electrochemical studies also showed that Ni-PTFE coatings, at a concentration of 20 g/L PTFE, had the highest electrochemical corrosion resistance. Microhardness also decreased with increasing PTFE particles in the coating and reached its lowest value. By using the wear test, the lowest coefficient of friction obtained in composite coatings with concentration of 20 g/L, which shows the applicability of PTFE particles as a solid lubricant in Ni-P coatings.
[1] A. Lelevic. F.C. Walsh. Electrodeposition of NiP alloy coatings: a review. Surface and Coatings Technology. 369 (2019) 198-220.
[2] M. Hosseini. M. Abdolmaleki. S.S. Sadjadi. Electrodeposition and mechanical properties of NiWB composites from tartrate bath. Protection of Metals and Physical Chemistry of Surfaces. 46 (2010). 117-122.
[3] G. A. Di Bari: Electrodeposition of Ni, in Modern electroplating, 5th ed.’, (eds. M. Schlesinger and M. Paunovic) 79–114 (2010), Hoboken, John Wiley & Sons.
[4] V. Torabinejad. M. Aliofkhazraei. Electrodeposition of Ni-Fe alloys, composites, and nano coatings–A review. Journal of Alloys and Compounds. 691. (2017). 841-859.
[5] V. Hasannaeimi. S. Mukherjee. highly catalytic amorphous Ni–P synthesized via pulsed electrodeposition. Advanced Engineering Materials, 21. (2019), 1801122-1801129.
[6] M. Hosseini. M. Abdolmaleki. J. Ghahremani. Investigation of corrosion resistance of electrodeposited Ni-W/SiC composite coatings. Corrosion Engineering, Science and Technology. 49 (2014) 247-253.
[7] C.R. Raghavendra. S. Basavarajappa. I. Sogalad. Electrodeposition of Ni-nano composite coatings: a review. Inorganic and Nano-Metal Chemistry, 48(2018.) 583-598.
[8] V. Tseluikin. A. Dzhumieva.A. Yakovlev. Electrodeposition and Corrosion Properties of Nickel–Graphene Oxide Composite Coatings. Materials. 14(2021). 5624.
[9] M. Ganji. H. Yousefnia. Z.S. Seyedraoufi. The corrosion behavior of Ni–Fe and Ni–Fe–TiC nanoparticles deposited using pulse electrodeposition on low-carbon steel. Journal of the Australian Ceramic Society, 7 (2022). 1-13.
[10] J.-Y. Lee. D.-P. Lim. D.-S. Lim. Tribological behavior of PTFE nanocomposite films reinforced with carbon nanoparticles. Composites Part B: Engineering. 38 (2007) 810-816.
[11] Mirzaaghaei, Mahdi, Mohammad-Hossein Enayati, and Mahdi Ahmadi. "Fabricating the Tribological Properties and Investigating of Ni3Al-MoS2 Composite Coating." Journal of Advanced Materials and Processing 9.1 (2021): 21-30.
[12] Y. He. W.T. Sun. S.C. Wang. An electrodeposited Ni-P-WS2 coating with combined super-hydrophobicity and self-lubricating properties. Electrochimica Acta. 245 (2017). 872- 882.
[13] Y. He. S.C. Wang. F.C. Walsh. Self-lubricating Ni-P-MoS2 composite coatings. Surface and Coatings Technology. 307 (2016) 926-934.
[14] Mirzaaghaei, M., Enayati, M. H., & Ahmadi, M. (2021). Fabricating the Tribological Properties and Investigating of Ni3Al-MoS2 Composite Coating. Journal of Advanced Materials and Processing, 9(1), 21-30.
[15] I.R. Mafi. C. Dehghanian, Comparison of the coating properties and corrosion rates in electroless Ni–P/PTFE composites prepared by different types of surfactants. Applied Surface Science. 257 (2011) 8653-8658.
[16] S. Sangeetha. G.P. Kalaignan. J.T. Anthuvan. Pulse electrodeposition of self-lubricating Ni– W/PTFE nanocomposite coatings on mild steel surface. Applied Surface Science. 359 (2015). 412- 419.
[17] S. Ghanbari. F. Mahboubi. Corrosion resistance of electrodeposited Ni–Al composite coatings on the aluminum substrate. Materials & Design. 32(2011). 1859-1864.
[18] S. Li. G. Song. Y. Zhang. Graphene-Reinforced Zn–Ni Alloy Composite Coating on Iron Substrates by Pulsed Reverse Electrodeposition and Its High Corrosion Resistance, ACS omega, 6(2021). 13728- 13741.
[19] Soltani, M., Shafyei, A., Zarrin Naghsh, K., & Aliramezani, R. (2018). Effect of Ni-P electroless coating and heat treatment on tribological and corrosion properties of copper substrate. Journal of Advanced Materials and Processing, 6(4), 3-13.
[20] R. Balaji. M. Pushpavanam. K.Y. Kumar, Electrodeposition of bronze–PTFE composite coatings and study on their tribological characteristics. Surface and Coatings Technology, 201(2006). 3205-3211.