Manganese polymeric sensor based on scanometry

Subject Areas :

فائزه کائدی ¹ , شیدا اسمعیل‌زاده ² , عبدالرضا خواجه‌زاده ³

1 - دانشجوی کارشناس ارشد تکنولوژی و علوم پلیمر، گروه شیمی، دانشگاه آزاد اسلامی واحد داراب، داراب، فارس، ایران
2 - استادیار شیمی معدنی، گروه شیمی، دانشگاه آزاد اسلامی واحد داراب، داراب، فارس، ایران
3 - استادیار شیمی تجزیه، گروه شیمی، دانشگاه آزاد اسلامی واحد داراب، داراب، فارس، ایران

Received: 2018-05-24 Accepted : 2018-09-25 Published : 2018-11-22

Keywords: Manganese, Brilliant Cresyl Blue, Scanometry, Polymeric Sensor Film, Triacetylcellulose,

Abstract :

In this study, a new and inexpensive polymeric sensor was developed for determination of Manganese in the aqueous media. The scanometric method was used to measure the color intensities of each polymeric film. In the scanometry, the image of films were transferred into image analyzing software. In the software any spots of the film were analyzed to red, green, and blue color parameters. For the preparation of polymeric manganese sensor film, triacetylcellulose was chosen as substrate and by using the activation process, Brilliant Cresyl Blue stabilized on inexpensive polymer substrate. After the polymer film made quite active, the experimental parameters including film response time, range of pH, concentration of brilliant cresyl blue was optimized. In this study, linear range and sensitivity of polymeric sensor film for all color parameters were obtained. Maximum linear range was obtained for red and blue (equal) and minimum linear range was obtained for green paremeter. Also, the green parameter had maximum sensitivity in the films.

References:

[1]. Oga, S.; "Fundamentos de Toxicologia", Atheneu Press, São Paulo, 2008.

[2]. Amais, R.S.; Donati, G.L.; Nebrega, J.A.; Analytica Chimica Acta 706, 223- 228, 2011. 

[3]. Yukawa, M.; Suzuki-Yasumoto, M.; Amano, K.; Terai, M.; Archives of Environmental Health An International Journal 35, 36-44, 1980.

[4]. Garcia, S.J.; Gellein, K.; Syversen, T.; Aschner, M.; Toxicological Sciences 95, 205-214, 2007.

[5]. Hepp, N.M.; Journal of AOAC International 98, 160-164, 2015. 

[6]. Basargin, N.N.; Oskotskaya, E.R.; Gribanov, E.N; Kuznetsov, E.V.; Analytical Chemistry 67, 35-40, 2012.

[7]. Ohura, H.; Ishibashi, Y.; Imato, T.; Yamasaki, S.; Talanta 60, 177-184, 2003.

[8]. Marbaniang, D.G.; International Journal of Environmental Protection 2, 22-26, 2012. 

[9]. Nakano, Sh.; Matumoyo, Y.; Yoshii, M.; Talanta 68, 312-317, 2005.

[10]. Ji, H.; Sha, Y.; Xin, H.; Qi, Y.; Journal of Ocean University of China 8, 127-132, 2009.

[11]. Rustamov, N.Kh.; Abbasova, G.G.; Ame. Analytical Chemistry 5, 275-280, 2014. 

[12]. Filipe, M.S.; Christopher, M.A.; Talanta 61, 643-650, 2003.

[13]. Liu, L.; Li, T.; Wu, M.; Yu, H.; Analytical Letters 50, 135-147, 2017.

[14]. Lima, F.F.; Tormin, T.F.; Richter, E.M.; Munzo, R.A.A.; Microchemistry Journal 116, 178-182, 2014. 

[15]. Bilo, F.; Borgese, L.; Zacco, A.; Lazo. P.; Zoani, C.; Zappa, G.; Bontempi, E.; Depero, L.E.;  

Journal of Analytical and Bioanalytical Techniques 7, 1-7, 2015.

[16]. Manzoori, J.L.; Amjadi, M.; Abulhassani, J.; Talanta 77, 1539-1544, 2009.

[17]. Payehghadr, M.; Tagdiri, M.; Zamani, A.; Hesaraki, N.; Iranian Journal of Chemistry and Chemical Engineering 31, 1-7, 2012.

[18]. Rakow, N.A.; Suslick, K.S.; Nature 406, 710-713, 2000. 

[19] Janzen, M.C.; Ponder, J.B.; Bailey, D.P.; Ingison, C.K.; Suslick, K.S.;  Analytical Chemistry 78, 3591-3600, 2006.

[20]. Abbaspour, A.; Khajehzadeh, A.; Ghaffarinejad, A.A; Analyst 134, 1692-1698, 2009. 

[21]. Abbaspour, A.; Mirahmadi, E.; Khajehzadeh, A.;  Analytical Methods, 2, 349-353, 2010.

[22]. Abbaspour, A.; Khajehzadeh, A.;  Analytical Methods 4, 923-932, 2012. 

[23]. Kazemzadeh, A.; Moztarzadeh, F.; Sensors & Actuators B 106, 832–836, 2005.