Green synthesis of Ag nanoparticels using salvia hydrangea extract and Peach kernel shell as a natural valuable support: Investigation of catalytic activity in reduction of methylene Blue and Rhodamine B

Subject Areas :

بهار خدادادی ¹ ( استادیار شیمی کاربردی، گروه شیمی، دانشکده علوم پایه، دانشگاه قم، قم، ایران )

Received: 2017-05-08 Accepted : 2018-10-10 Published : 2018-05-22

Keywords: Ag Nanoparticles, Organic dyes, NaBH4, Salvia hydrangea, Peach kernel shell,

Abstract :

In these research, the green synthesis of Ag nanoparticles )AgNPs( and AgNPs/Peach kernel shell )Ag/ P.K. Shell(, using peach kernel shell as an environmentally benign support and Salvia hydrangea extract as the reducing agent in the absence of any stabilizer or surfactant is reported. Samples were characterized by Fourier Transform Infrared spectroscopy )FTIR(, UV-Vis spectroscopy, Field Emission Scanning Electron Microscopy )FE-SEM( equipped with an energy dispersive spectroscopy )EDS(, Elemental mapping, X-ray Diffraction analysis )XRD(, and Transmittance Electron Microscopy )TEM(. These synthesized catalysts were used in the reduction of Methylene Blue )MB( and Rhodamine B )RhB( at room temperature. The Ag/ P.K. shell showed excellent catalytic activity in the reduction of these organic dyes. In addition, it was found that AgNPs/Apricot kernel shell can be recovered and reused several times without significant loss of catalytic activity.

References:

[1] Han, Z.; Ren, L.; Agi, Z.; Chen, C.; Pan, H.; J. Chen, Appl. Catal. B: Environ. 126, 298-305, 2012.

[2] Zhu, H.Y.; Xiao, L.; Jiang, R.; Zeng, G.M.; Liu, L.; Chem. Eng. J. 172, 746-753, 2011.

[3] Saravanan, R.; Gupta, V.K.; Prakash, T.; Narayanan, V.; Stephen, A.; J. Mol. Liq. 178, 88- 93, 2013.

[4] Reza Pouretedal, H.; Ahmadi, M.; Iranian J. Catal. 3(3), 149-155, 2013.

[5] Nadagouda, M.N.; Hoag, G.; Collins, J.; Varma, R.S.; Cryst. Growth Des. 9, 4979-4983, 2009.

[6] Mohanpuria, P.; Rana, N.K.; Yadav, S.K.; J. Nanopart. Res. 10, 507–517, 2009.

[7] Karimi Andeani, J.; Kazemi, H.; Mohsenzadeh, S.; Safavi, A.; Dig. J. Nanomater. Bios. 6(3), 1011-1016, 2011.

[8] Kim, F.; Connor, S.; Song, H.; Kuykendall, T.;Yang, P.; Angew. Chem. 116, 3759-3763, 2004.

[9] Sperling, R.A.; Zhang, F.; Zanella, M.; Parak, W.J.; Chem. Soc. Rev. 37, 1896-1908, 2008.

[10] Kelly, K.L,; Coronado, E.; Zhao, L.L.; Schatz, G.C.; J. Phys. Chem. B. 107, 668–677, 2002.

[11] Boisselier, E.; Astruc, D.; Chem. Soc. Rev. 38, 1759-1782, 2009.

[12] Khodadadi, B.; J. Sol-Gel Sci. Technol. 80, 793–801, 2016.

[13] Khodadadi, B.; Iranian J. Catal. 6, 305– 311, 2016.

[14] Khodadadi, B.; Bordbar, M.; Iranan J. Catal. 6, 37-42, 2016.

[15] Khodadadi, B.; J. Appl. Chem.8 (27), 61- 64, 2013.

[16] Bordbar, M.; Jafari, S.; Yeganeh Faal, A.; Khodadadi, B.; J. Iran Chem. Soc. 14, 897 -906, 2017.

[17] Shankar, S.S.; Rai, A.; Ahmad, A.; Sastry, M.; J. Colloid Interf. Sci. 275, 496–502, 2004.

[18] Asgary, S.; Naderi, G.H.; Sarrafzadegan, N.; Mohammadifard, N.; Mostafavi, S.; Vakili, R.; Drugs Exp. Clin. Res. 26(3), 89-93, 2000.

[19] Afsharypour, S.; Asgary, S.; Lockwood, G.B.; Planta Med. 62, 77-78, 1996.

[20] Zahed, B.; Hosseini-Monfared, H.; Appl. Surf. Sci. 328, 536- 547, 2015.

[21] Zargar, M.; Abdul Hamid, A.; Abu Bakar, F.; Nor Shamsudin, M.; Shameli, K.; Jahanshiri, F.; Farahani, F.; Molecules. 16, 6667- 6676, 2011.

[22] Atarod, M.; Nasrollahzadeh, M.; Sajadi, S.M.; J. Colloid Interf. Sci. 462, 272-279, 2016.

[23] Khodadadi, B.; Bordbar, M.; Nasrollahzadeh, M.; J. Colloid Interf. Sci. 490, 1- 10, 2017.

[24] Atarod, M.; Nasrollahzadeh, M.; Sajadi, J.S.M.; Colloid Interf. Sci. 465, 249-258, 2016.

[25] Rostami-Vartooni, A.; Nasrollahzadeh, M.; Alizadeh, M.; J. Colloid Interf. Sci. 470, 268- 275, 2016.

[26] Manonmani, V.; Juliet, V.; Int. Conf. Innov. Manag. Serv. IPEDR. 14, 307- 311, 2011.

[27] Shah, D.; Kaur, H.; J. Mol. Catal. A. Chem. 381, 70-76, 2014.

[28] Khodadadi, B.; Bordbar, M.; Nasrollahzadeh, M.; J. Colloid Interf. Sci. 493, 58-93, 2017.

[30] Demiral, I.; Kul, S.C.; J. Anal. Appl. Pyrol. 107, 17–24, 2014.

[31] Yang, H.; Yan, R.; Chen, H.; Lee, D.H.; Zheng, C.; Fuel. 86, 1781–1788, 2007.

[32] Putun, A.E.; Ozcan, A.; Putun, E.; J. Anal. Appl. Pyrol. 52, 33–49, 1999.

[33] Zhao, H.; Kwak, J.H.; Zhang, Z.C.; Brown, H.M.; Arey, B.W.; Holladay, J.E.; Carbohyd. Polym. 68, 235–241, 2007.

[34] Das, K.; Ray, D.; Bandyopadhyay, N.R.; Sengupta, S.; Polym. Environ. 18, 355–363, 2010.

[37] Khodadadi, B.; Bulg. Chem. Chemmun. 48, 238–243, 2016.

[38] Khodadadi, B.; J. Appl. Chem. Res. 9,119–129, 2015.