Removal of azo dye (Direct Yellow 86) from the wastewater of linen fabric dyeing units using 4-sulfocalixarene
Mojtaba Ghorbani
1
(
Chemistry Department
)
سعید تقوایی گنجعلی
2
(
استاد شیمی آلی دانشگاه آزاد اسلامی واحد تهران شمال
)
ali akbar tarlani
3
(
عضو هیئت علمی
)
مرسده ملک زاده
4
(
)
Keywords: Direct yellow 86, Benesi Hildebrand diagram, 4-sulfocalix[4]arene, Absorption.,
Abstract :
This article presents the synthesis method of 5,11,17,23-para-tert-butyl calix[4]arene and 5,11,17,23- tetrasulfonic acid calix[4]arene (4-S-calix[4]) and the use of 4-S-calix[4], the sulfonated derivative of 5,11,17,23- para tert-butyl calix[4]arenea, as a very efficient molecular host for the adsorption of Direct Yellow 86, an azo dye, in an aqueous environment. Para-tert-butyl calix[4]arene and sulfonated derivative of para-tert-butyl calix[4]arene were identified using Fourier transform infrared spectroscopy (FTIR). Due to its stability and rigid conical form, this chemical displays potency potential in host-guest interactions. Hence, the compound 4-S-calix[4] was used as a guest molecule in order to examine the characteristics of the complex and the absorption intensity of Direct Yellow 86 dye. The estimation of the formation constant (Kf) for the complex between 4-S-calix[4] and DY86 was conducted by comparing the absorption intensity. The formation constant was predicted to be 4.6×104 M-1. The stoichiometric ratio of the compound was discovered to be 1:1 by the use of the Benesi-Hildebrand diagram.
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