Synthesis and study of corrosion inhibition Poly (epichlorohydrin) containing NTO and P(OH)2 (PECH / NTO / P (OH)2 on the mild steel in hydrochloric acid medium
Subject Areas :
fariborz aabaki
1
(دانشیار شیمی آلی، دانشکده شیمی، دانشگاه صنعتی مالک اشتر، تهران، ایران)
shahrzad jahangiri
2
(دانشجوی دکترا دانشکده شیمی، دانشگاه صنعتی مالک اشتر، تهران، ایران)
Keywords: 2, 3-nitro-1, 4-triazol-5-one(NTO)/ Poly(epichlorohydrin)(PECH) / Electrochemical impedance spectroscopy/ Polarization,
Abstract :
In this way, the chlorine branches of poly (epichlorohydrin) (PECH) were substituted with 3-nitro-1,2,4-triazol-5-one(NTO) and P(OH)2 were replaced and The inhibitory efficiency of these compounds for immersed steel in hydrochloric acid medium has been investigated. Fourier transform infrared spectroscopy (FT-IR) and nuclear magnetic resonance (NMR) and Elemental analyzer (CHN) and thermogravimetric analysis (TGA) and UV-visible were used to characterize the chemical composition of the synthesized organic compounds. Electrochemical impedance spectroscopy (EIS) and electrochemical polarization techniques were used to evaluate the corrosion inhibition performance of the organic inhibitors. The results of these studies showed that the sample containing NTO and P (OH)2 had the highest amount of corrosion inhibition.. Polarization results revealed that the corrosion inhibition efficiency in the inhibitor-containing samples was increased by increasing the concentration of the inhibitors in the corrosive electrolyte. Also, the results of the polarization test proved that these inhibitors acted as a mixed inhibitor in the acidic environment and by absorbing the steel surface in the corrosive environment, both the anode and cathode corrosion reactions were affected
[1] Mousavi, M.; Mohammadalizadeh, M.; Khosravan, A.; Corros. Sci. 53, 3086-3091, 2011.
[2] Jokar, M.; Farahani, T.S.; Ramezanzadeh, B.; J. Taiwan Inst. Chem. E. 63, 436-452, 2016.
[3] Hamadi, L.; Mansouri, S.; Oulmi, K.; Kareche, A.; Egypt. J. Pet. 27, 1157-1165, 2018.
[4] Chugh, B.; Singh, A.K.; Thakur, S.; Pani, B.; Pandey, A.K.; Lgaz, H.; Chung, I.M.; Ebenso, E.E.; J. Phys. Chem. C. 123, 22897-22917, 2019.
[5] Mazhar, A.A.; Arab, S.T.; Noor, E.A.; J. Appl. Electrochem. 31, 1131-1140, 2001.
[6] Saji, V.S.; Recent Patents on Corrosion Science. 2, 6-12, 2010.
[7] Umoren, S.A.; Solomon, M.M.; Obot, I.B.; Suleiman, R.K.; J. Ind. and Eng.Chem. 76, 91-115, 2019.
[8] Atabaki, F.; Jahangiri, Sh.; Sadati, Z.; Advanced Materials and Novel Coatings 6, 1669-1679, 2018.
[9] Atabaki, F.; Jahangiri, Sh.; Pahnavar, Z.; Prot. Met. Phys. Chem. Surf. 55, 1161-1172, 2019.
[10] Shahmoradi, A.R.; Talebibahmanbigloo, N.; Javidparvar, A.A.; Bahlakeh, G.; Ramezanzadeh, B.; J. Mol. Liq. 304, 112751, 2020.
[11] Verma, C.; Ebenso, E.E.; Bahadur, I.; Quraishi, M.A.; J. Mol. Liq. 266, 577-590, 2018.
[12] Rani, B.E.A.; Basu, B.B.J.; Int. J. Corros. 2012, 1-15, 2012.
[13] Atabaki, F.; Noorollahy Bastam, N.; Hafizi- Atabak, H.M.R.; Radvar, M.; Jahangiri, Sh.; IJCCE. 1, 2020.
[14] Atabaki, F.; Jahangiri, Sh.; J. Appl. Chem. 11, 67-74, 2017.
[15] Krim, O.; Messali, M.; Hammouti, B.; Elidrissi, A.; Khaled, K.; Salghie, R.; Lgaze, H.; Portug. Electrochim. Acta. 34, 213-229, 2016.
[16] Javidparvar, A.A.; Naderi, R.; Ramezanzadeh, B.; J. Hazard. Mater. 389, 122135, 2020.
[17] Loto, R.T.; Loto, C.A.; Fedotova, T.; Int. J. Electrochem. Sci. 7, 10763–10778, 2012.
[18] Obot, I.B.; Obi-Egbedi, N.O.; Umoren, S.A.; Int. J. Electrochem. Sci. 4, 863–877, 2009.
[19] Ahmed, S.K.; Ali, W.B.; Khadom, A.A.; Int. J. Ind. Chem. 10, 159–173, 2019.
[20] Salman, M.; Ansari, K.R.; Haque, J.; Srivastava, V.; Quraishi, M.A.; Mazumder, M.A.J.; J. Heterocycl. Chem. 57, 2157–2172, 2020.
[21] Al-Baghdadi, S.B.; Hashim, F.G.; Salam, A.Q.; Abed, T.K.; Gaaz, T.S.; Al-Amiery, A.A.; Kadhum, A.A.H.; Reda, K.S.; Ahmeda, W.K.; Results. Phys. 8, 1178–1184, 2018.
[22] Ahmed, M.H.O.; Al-Amiery, A.A.; Al-Majedy, Y.K.; Kadhum, A.A.H.; Mohamad, A.B.; Gaaz, T.S.; Results. Phys. 8, 728–733, 2018.
[23] Zhang, T.; Jiang, W.; Wang, H.; Zhang, S.; Mater. Chem. Phys. 237, 121866, 2019.
[24] About, H.; El Faydy, M.; Benhiba, F.; Rouifi, Z.; Boudalia, M.; Guenbour, A.; Zarrok, H.; Lakhrissi, B.; Oudda, H.; Warad, I.; Zarrouk, A.; J. Bio. Tribo.Corros. 5 , 1-15, 2019.
[25] Benali, Y.H.O.; Larabi, L.; M.s Mekelleche, S.; J. Mater. Sci. 41, 7064–7073, 2006.
[26] Ammal, P.R.; Prajila, M.; Joseph, A.; J. Environ. Chem. Eng. 6, 1072–1085, 2018.
[27] Dutta, A.; Saha, S.K.; Adhikari, U.; Banerjee, P.; Sukul, D.; Eval. Prog. Plann. 2017.
[28] Javidparvar, A.A.; Ramezanzadeh, B.; Ghasemi, E.; J. Taiwan Inst. Chem. Eng. 61, 356–366, 2015.
[29] Dong, Q.; Kumada, N.; Yonesaki, Y.; Takei, T.; Kinomura, N.; J. Ceram. Soc. Jap. 117, 881–886, 2009.
[30] Javidparvar, A.A.; Ramezanzadeh, B.; Ghasemi, E.; Corros. 72, 761–774, 2016.
[31] Javidparvar, A.A.; Naderi, R.; Ramezanzadeh, B.; Bahlakeh, G.; J. Ind. Eng. Chem. 72, 196-213, 2018.
[32] Kumar Trivedi, M.; Pharm. Anal. Acta. 06 , 1-5, 2015.
[33] Javidparvar, A.A.; Naderi, R.; Ramezanzadeh, B.; J. Mol. Liq. 284, 415-430, 2019.
[34] Yu, Y.H.; Lin, Y.Y.; Lin, C.H.; Chan, C.C.; Huang, Y.C.; Polym. Chem. 5, 1-49 , 2014.
[35] Parhizkar, N.; Ramezanzadeh, B.; Shahrabi, T.; J. Ind. Eng. Chem. 64, 1-49, 2018.
[36] Bharanidharan, S.; Saleem, H.; Subashchandrabose, S.; Suresh, M.; Ramesh Babu, N.; Arch. Chem. Res. 01, 1-14, 2017.
[37] Yang, Y.; Wang, J.; Zhang, J.; Liu, J.; Yang, X.; Zhao, H.; Langmuir. 25, 11808-11814, 2009.
[38] Wang, H.; Xiao, Z.; Yang, J.; Lu, D.; Kishen, A.; Li, Y.; Chen, Z.; Que, K.; Zhang, Q.; Deng, X., Yang, X.; Cai, Q.; Chen, N.; Cong, Ch.; Guan, B.; Li, T.; Zhang, X.; Sci. Rep. 7, 1-13, 2017.
[39] Khoshtinat, K.; Barzegar, M.; Sahari, M.A.; Hamidi, Z.; J. Agr. Sci. Tech. 19, 97–111, 2017.
[40] Kakiuti, Y.; Kida, S.; Quagliano, J.V.; Spectrochim. Acta. 19, 201–211, 1963.
[41] Kunkely, H.; Vogler, A.; Inorg. Chem. Commun. 4, 692–694, 2001.
[42] Zou, S.; Li, R.; Kobayashi, Liu, H. J.; Fan, J.; Chem. Comm. 49, 1906-1908, 2013.
[43] Sheshmani, S.; Akhundi Nematzadeh, M.; Shokrollahzadeh, S.; Ashori, A.; Int. J. Biol. Macromol. 80, 475–480, 2015.
[44] Khaled, K.F.; Amin, M.A.; J. Appl. Electrochem. 39, 2553–2568, 2009.
[45] Mahdavian, M.; Ashhari, S.; Electrochim. Acta. 55, 1720–1724, 2010.
[46] Touir, R.; Belakhmima, R.A.; Touhami, M.; Lakhrissi, L.; El Fayed, M.; Lakhrissi, B.; Essassi, El M.; J. Mater. Environ. Sci. 4(6), 921–930, 2013.
[47] Ramezanzadeh, M.; Bahlakeh,G.; Sanaei, Z.; Ramezanzadeh, B.; Appl. Surf. Sci. 463, 1058–1077, 2019.
_||_
[1] Mousavi, M.; Mohammadalizadeh, M.; Khosravan, A.; Corros. Sci. 53, 3086-3091, 2011.
[2] Jokar, M.; Farahani, T.S.; Ramezanzadeh, B.; J. Taiwan Inst. Chem. E. 63, 436-452, 2016.
[3] Hamadi, L.; Mansouri, S.; Oulmi, K.; Kareche, A.; Egypt. J. Pet. 27, 1157-1165, 2018.
[4] Chugh, B.; Singh, A.K.; Thakur, S.; Pani, B.; Pandey, A.K.; Lgaz, H.; Chung, I.M.; Ebenso, E.E.; J. Phys. Chem. C. 123, 22897-22917, 2019.
[5] Mazhar, A.A.; Arab, S.T.; Noor, E.A.; J. Appl. Electrochem. 31, 1131-1140, 2001.
[6] Saji, V.S.; Recent Patents on Corrosion Science. 2, 6-12, 2010.
[7] Umoren, S.A.; Solomon, M.M.; Obot, I.B.; Suleiman, R.K.; J. Ind. and Eng.Chem. 76, 91-115, 2019.
[8] Atabaki, F.; Jahangiri, Sh.; Sadati, Z.; Advanced Materials and Novel Coatings 6, 1669-1679, 2018.
[9] Atabaki, F.; Jahangiri, Sh.; Pahnavar, Z.; Prot. Met. Phys. Chem. Surf. 55, 1161-1172, 2019.
[10] Shahmoradi, A.R.; Talebibahmanbigloo, N.; Javidparvar, A.A.; Bahlakeh, G.; Ramezanzadeh, B.; J. Mol. Liq. 304, 112751, 2020.
[11] Verma, C.; Ebenso, E.E.; Bahadur, I.; Quraishi, M.A.; J. Mol. Liq. 266, 577-590, 2018.
[12] Rani, B.E.A.; Basu, B.B.J.; Int. J. Corros. 2012, 1-15, 2012.
[13] Atabaki, F.; Noorollahy Bastam, N.; Hafizi- Atabak, H.M.R.; Radvar, M.; Jahangiri, Sh.; IJCCE. 1, 2020.
[14] Atabaki, F.; Jahangiri, Sh.; J. Appl. Chem. 11, 67-74, 2017.
[15] Krim, O.; Messali, M.; Hammouti, B.; Elidrissi, A.; Khaled, K.; Salghie, R.; Lgaze, H.; Portug. Electrochim. Acta. 34, 213-229, 2016.
[16] Javidparvar, A.A.; Naderi, R.; Ramezanzadeh, B.; J. Hazard. Mater. 389, 122135, 2020.
[17] Loto, R.T.; Loto, C.A.; Fedotova, T.; Int. J. Electrochem. Sci. 7, 10763–10778, 2012.
[18] Obot, I.B.; Obi-Egbedi, N.O.; Umoren, S.A.; Int. J. Electrochem. Sci. 4, 863–877, 2009.
[19] Ahmed, S.K.; Ali, W.B.; Khadom, A.A.; Int. J. Ind. Chem. 10, 159–173, 2019.
[20] Salman, M.; Ansari, K.R.; Haque, J.; Srivastava, V.; Quraishi, M.A.; Mazumder, M.A.J.; J. Heterocycl. Chem. 57, 2157–2172, 2020.
[21] Al-Baghdadi, S.B.; Hashim, F.G.; Salam, A.Q.; Abed, T.K.; Gaaz, T.S.; Al-Amiery, A.A.; Kadhum, A.A.H.; Reda, K.S.; Ahmeda, W.K.; Results. Phys. 8, 1178–1184, 2018.
[22] Ahmed, M.H.O.; Al-Amiery, A.A.; Al-Majedy, Y.K.; Kadhum, A.A.H.; Mohamad, A.B.; Gaaz, T.S.; Results. Phys. 8, 728–733, 2018.
[23] Zhang, T.; Jiang, W.; Wang, H.; Zhang, S.; Mater. Chem. Phys. 237, 121866, 2019.
[24] About, H.; El Faydy, M.; Benhiba, F.; Rouifi, Z.; Boudalia, M.; Guenbour, A.; Zarrok, H.; Lakhrissi, B.; Oudda, H.; Warad, I.; Zarrouk, A.; J. Bio. Tribo.Corros. 5 , 1-15, 2019.
[25] Benali, Y.H.O.; Larabi, L.; M.s Mekelleche, S.; J. Mater. Sci. 41, 7064–7073, 2006.
[26] Ammal, P.R.; Prajila, M.; Joseph, A.; J. Environ. Chem. Eng. 6, 1072–1085, 2018.
[27] Dutta, A.; Saha, S.K.; Adhikari, U.; Banerjee, P.; Sukul, D.; Eval. Prog. Plann. 2017.
[28] Javidparvar, A.A.; Ramezanzadeh, B.; Ghasemi, E.; J. Taiwan Inst. Chem. Eng. 61, 356–366, 2015.
[29] Dong, Q.; Kumada, N.; Yonesaki, Y.; Takei, T.; Kinomura, N.; J. Ceram. Soc. Jap. 117, 881–886, 2009.
[30] Javidparvar, A.A.; Ramezanzadeh, B.; Ghasemi, E.; Corros. 72, 761–774, 2016.
[31] Javidparvar, A.A.; Naderi, R.; Ramezanzadeh, B.; Bahlakeh, G.; J. Ind. Eng. Chem. 72, 196-213, 2018.
[32] Kumar Trivedi, M.; Pharm. Anal. Acta. 06 , 1-5, 2015.
[33] Javidparvar, A.A.; Naderi, R.; Ramezanzadeh, B.; J. Mol. Liq. 284, 415-430, 2019.
[34] Yu, Y.H.; Lin, Y.Y.; Lin, C.H.; Chan, C.C.; Huang, Y.C.; Polym. Chem. 5, 1-49 , 2014.
[35] Parhizkar, N.; Ramezanzadeh, B.; Shahrabi, T.; J. Ind. Eng. Chem. 64, 1-49, 2018.
[36] Bharanidharan, S.; Saleem, H.; Subashchandrabose, S.; Suresh, M.; Ramesh Babu, N.; Arch. Chem. Res. 01, 1-14, 2017.
[37] Yang, Y.; Wang, J.; Zhang, J.; Liu, J.; Yang, X.; Zhao, H.; Langmuir. 25, 11808-11814, 2009.
[38] Wang, H.; Xiao, Z.; Yang, J.; Lu, D.; Kishen, A.; Li, Y.; Chen, Z.; Que, K.; Zhang, Q.; Deng, X., Yang, X.; Cai, Q.; Chen, N.; Cong, Ch.; Guan, B.; Li, T.; Zhang, X.; Sci. Rep. 7, 1-13, 2017.
[39] Khoshtinat, K.; Barzegar, M.; Sahari, M.A.; Hamidi, Z.; J. Agr. Sci. Tech. 19, 97–111, 2017.
[40] Kakiuti, Y.; Kida, S.; Quagliano, J.V.; Spectrochim. Acta. 19, 201–211, 1963.
[41] Kunkely, H.; Vogler, A.; Inorg. Chem. Commun. 4, 692–694, 2001.
[42] Zou, S.; Li, R.; Kobayashi, Liu, H. J.; Fan, J.; Chem. Comm. 49, 1906-1908, 2013.
[43] Sheshmani, S.; Akhundi Nematzadeh, M.; Shokrollahzadeh, S.; Ashori, A.; Int. J. Biol. Macromol. 80, 475–480, 2015.
[44] Khaled, K.F.; Amin, M.A.; J. Appl. Electrochem. 39, 2553–2568, 2009.
[45] Mahdavian, M.; Ashhari, S.; Electrochim. Acta. 55, 1720–1724, 2010.
[46] Touir, R.; Belakhmima, R.A.; Touhami, M.; Lakhrissi, L.; El Fayed, M.; Lakhrissi, B.; Essassi, El M.; J. Mater. Environ. Sci. 4(6), 921–930, 2013.
[47] Ramezanzadeh, M.; Bahlakeh,G.; Sanaei, Z.; Ramezanzadeh, B.; Appl. Surf. Sci. 463, 1058–1077, 2019.
