Preconcentration and determination of Pb(II) using magnetic nanoparticles coated with DABCO-PDO ionic liquid with FAAS in aqueous samples
Subject Areas :
sara
khodadadi
1
(دانشجوی دکترای شیمی تجزیه، گروه شیمی، ، دانشگاه آزاد اسلامی واحد تهران مرکز، تهران، ایران)
elahe
konoz
2
(دانشیار شیمی تجزیه، گروه شیمی، دانشگاه آزاد اسلامی واحد تهران مرکز، تهران، ایران)
ali
niazi
3
(استاد شیمی تجزیه، گروه شیمی، دانشگاه آزاد اسلامی واحد تهران مرکز، تهران، ایران)
ali
ezabadi
4
(استادیار شیمی آلی، گروه شیمی، دانشگاه آزاد اسلامی واحد تهران مرکز، تهران، ایران)
Keywords: Lead, FAAS, Magnetic nanoparticles coated with DABCO-PDO, Aqueous samples,
Abstract :
In this study, magnetic nanoparticles modified with DABCO-PDO ionic liquid were used to preconcentration and determination of trace amount of Pb(II) in aqueous samples using a flame atomic absorption instrument. Experimental factors affecting Pb(II) extraction and preconcentration were investigated and optimized. The calibration curve for Pb(II) was linear under the optimum condition in the concentration range of 0.8-1.6 µg l-1 with the determination coefficient of 0.9986. The concentration factor of Pb(II) was 100 with the detection limit of 0.25 µg l-1. The relative standard deviations (RSD %) for the concentration of the method were 1.8 and 2.5, respectively, with 4 successive replications in one day and between days. Lead determination was successfully applied for aqueous samples (rainwater in Tehran, tap water in Shahrak Gharb, Tehran, and mineral water). Recoveries in the ranges 90.6-97.8 was reported. Structure and morphology of the synthesized nanosorbent were investigated by using Fourier transform infrared spectroscopy (FTIR) analysis, scanning electron microscopy (SEM), and X-ray powder diffraction (XRD).
[1] Samadi, S.; Kharkhaneh, A.; Moghadam, M.; Zakaria, A.; Journal of Applied Researches in Chemistry (JARC) 2, 61-73, 1398.
[2] Lin, H.T.; Wong, S.S.; Li, G.Ch.; Journal of Food and Drug Analysis 12, 74-167, 2004.
[3] Mehrabad, T.; Sheikhlouie, H.; Arjmandi Rad, F.; Nashrieh Shimi va Mohandesi Shimi Iran (NSMSI) 4, 61-68, 1393.
[4] Muhammad, S.; Shah, M.T.; Khan, S.; Microchemical Journal 98, 334-341, 2011.
[5] Bakirdere, S.; Yaroǧlu, T.; Tirik, N.; Demiröz, M.; Fidan, A.K.; Maruldali, O.; Karaca, A.; Journal of Spectroscopy 1, 1–7, 2013.
[6] AL- Rajhi, M.A.; American Journal of Environmental Sciences 10, 283-288, 2014.
[7] Feist, B.; Mikula, B.; Pytlakowska, K.; Puzio, B.; Buhl, F.; Journal of Hazardous Materials 152, 1122–1129, 2008.
[8] Trzcinka-Ochocka, M.; Brodzka, R.; Janasik, B.; Journal of Clinical Laboratory Ananlysis 30, 130–139, 2016.
[9] Arpa, Ç.; Aridaşir, I.; Journal of Analytical Mrthods in Chemistry 1, 1-7, 2018.
[10] Iwasaki, T.; Morikane, R.; Edura, T.; Tokuda, M.; Tsutsui, K.; Wada, Y.; Kawarada, H.; Carbon 45, 2351-2355, 2007.
[11] Ayata, S.;, Bozkurt,S.; Ocakoglu, K.; Talanta 84, 212-215, 2011.
[12] Hong-Yan Lü, A.; Shu-Hong Yang, A.; Jia Deng, A.; and Zhan-Hui Zhang,A.; Australian Journal of Chemistry 63, 1290–1296, 2010.
[13] Wang, S.; Zhang, Z.; Liu, B.; Li, J.; Catalysis Science & Technology 3, 2104, 2013.
[14] Ying, A.;Ni, Y.; Xu, S.; Liu, S.; Yang, J.; Li, R.; Industrial & Engineering Chemistry Research 53, 5678−5682, 2014.
[15] Sahebi, H.; Konoz, E.; Ezabadi, A.; New Journal of Chemistry 43, 13554-13570, 2019.
[16] Abdolmohammad-Zadeh,H.; Hassanlouei,S.; Zamani, M.; RSC Adv. 7, 23293–23300, 2017.
[17] Rezaee, M.; Yamini, Y.; Khanchi, A.; Faraji, M.; Saleh, A.; Journal of Hazardous Materials 178, 766–770, 2010.
[18] Durukan, I.; Arpa Şahin, C.; Bektaş, S.; Microchemical Journal 98, 215–219, 2011.
[19] Zhou, Q.; Ding, Y.; Xiao, J.; Analytical and Bioanalytical Chemistry 385, 1520-1525, 2006.
[20] Mahmoud, M.; Talanta 45, 309-315, 1997.
[21] khourasani, R.; Dindarloo, K.; Rahmanian, O.; Goudarzi, B.; Journal of Applied Researches in Chemistry (JARC) 44, 171-185, 1396.
[22] Gouda, A.A.; Zordok, W.A.; Turkish Journal of Chemistry 42, 1018 – 1031, 2018.
[23] Fasih Ramandi, N.; Shemirani, F.; Talanta 131, 404-411, 2015.
[24] Şahin, U.; Tokalioglu, S.; Kartal, S.; Ulgen, A.; Chemia Analityczna 50, 529-237, 2005.
_||_[1] Samadi, S.; Kharkhaneh, A.; Moghadam, M.; Zakaria, A.; Journal of Applied Researches in Chemistry (JARC) 2, 61-73, 1398.
[2] Lin, H.T.; Wong, S.S.; Li, G.Ch.; Journal of Food and Drug Analysis 12, 74-167, 2004.
[3] Mehrabad, T.; Sheikhlouie, H.; Arjmandi Rad, F.; Nashrieh Shimi va Mohandesi Shimi Iran (NSMSI) 4, 61-68, 1393.
[4] Muhammad, S.; Shah, M.T.; Khan, S.; Microchemical Journal 98, 334-341, 2011.
[5] Bakirdere, S.; Yaroǧlu, T.; Tirik, N.; Demiröz, M.; Fidan, A.K.; Maruldali, O.; Karaca, A.; Journal of Spectroscopy 1, 1–7, 2013.
[6] AL- Rajhi, M.A.; American Journal of Environmental Sciences 10, 283-288, 2014.
[7] Feist, B.; Mikula, B.; Pytlakowska, K.; Puzio, B.; Buhl, F.; Journal of Hazardous Materials 152, 1122–1129, 2008.
[8] Trzcinka-Ochocka, M.; Brodzka, R.; Janasik, B.; Journal of Clinical Laboratory Ananlysis 30, 130–139, 2016.
[9] Arpa, Ç.; Aridaşir, I.; Journal of Analytical Mrthods in Chemistry 1, 1-7, 2018.
[10] Iwasaki, T.; Morikane, R.; Edura, T.; Tokuda, M.; Tsutsui, K.; Wada, Y.; Kawarada, H.; Carbon 45, 2351-2355, 2007.
[11] Ayata, S.;, Bozkurt,S.; Ocakoglu, K.; Talanta 84, 212-215, 2011.
[12] Hong-Yan Lü, A.; Shu-Hong Yang, A.; Jia Deng, A.; and Zhan-Hui Zhang,A.; Australian Journal of Chemistry 63, 1290–1296, 2010.
[13] Wang, S.; Zhang, Z.; Liu, B.; Li, J.; Catalysis Science & Technology 3, 2104, 2013.
[14] Ying, A.;Ni, Y.; Xu, S.; Liu, S.; Yang, J.; Li, R.; Industrial & Engineering Chemistry Research 53, 5678−5682, 2014.
[15] Sahebi, H.; Konoz, E.; Ezabadi, A.; New Journal of Chemistry 43, 13554-13570, 2019.
[16] Abdolmohammad-Zadeh,H.; Hassanlouei,S.; Zamani, M.; RSC Adv. 7, 23293–23300, 2017.
[17] Rezaee, M.; Yamini, Y.; Khanchi, A.; Faraji, M.; Saleh, A.; Journal of Hazardous Materials 178, 766–770, 2010.
[18] Durukan, I.; Arpa Şahin, C.; Bektaş, S.; Microchemical Journal 98, 215–219, 2011.
[19] Zhou, Q.; Ding, Y.; Xiao, J.; Analytical and Bioanalytical Chemistry 385, 1520-1525, 2006.
[20] Mahmoud, M.; Talanta 45, 309-315, 1997.
[21] khourasani, R.; Dindarloo, K.; Rahmanian, O.; Goudarzi, B.; Journal of Applied Researches in Chemistry (JARC) 44, 171-185, 1396.
[22] Gouda, A.A.; Zordok, W.A.; Turkish Journal of Chemistry 42, 1018 – 1031, 2018.
[23] Fasih Ramandi, N.; Shemirani, F.; Talanta 131, 404-411, 2015.
[24] Şahin, U.; Tokalioglu, S.; Kartal, S.; Ulgen, A.; Chemia Analityczna 50, 529-237, 2005.
