In this paper, the effect of penicillin G drug as a green corrosion inhibitor on mild steel in 1.0 Mhydrochloric acid solution has been investigated using potentiodynamic polarization, electrochemicalimpedance spectroscopy (EIS) and electrochemical noise (EN) techniques أکثر
In this paper, the effect of penicillin G drug as a green corrosion inhibitor on mild steel in 1.0 Mhydrochloric acid solution has been investigated using potentiodynamic polarization, electrochemicalimpedance spectroscopy (EIS) and electrochemical noise (EN) techniques. The inhibition efficiencywas found to increase with increasing inhibitor concentration. Potentiodynamic polarizationmeasurements indicated that penicillin G is a mixed type inhibitor. Furthermore, it has beendemonstrated that the electrochemical noise (EN) technique under open circuit conditions as the onlytruly noninvasive electrochemical method can be employed for the quantitative evaluation ofcorrosion inhibition. This can be done using the standard deviation of partial signal (SDPS) forcalculation of the amount of noise charges at the particular interval of frequency, thereby calculatethe inhibition efficiency (IE) of an inhibitor. These IE values show a reasonable agreement with thoseobtained from potentiodynamic polarization and EIS measurements.
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Vanillin offers interesting possibilities for corrosion inhibition because of its safe use and highsolubility in water. The effect of vanillin on the corrosion inhibition of AISI 304 stainless steel in0.5M H2SO4 solution has been studied using potentiodynamic polarizati أکثر
Vanillin offers interesting possibilities for corrosion inhibition because of its safe use and highsolubility in water. The effect of vanillin on the corrosion inhibition of AISI 304 stainless steel in0.5M H2SO4 solution has been studied using potentiodynamic polarization and electrochemicalimpedance spectroscopy (EIS). Furthermore, this paper demonstrates that the electrochemical noise(EN) technique under open circuit conditions as the only truly noninvasive electrochemical methodcan be applied to investigate the corrosion inhibition. According to calculation of the total amount ofnoise charges due to all partial signals resulted from wavelet analysis of EN current data, it ispossible to obtain the inhibition efficiency (IE) of an inhibitor. These IE values show a reasonableagreement with those obtained from potentiodynamic polarization and EIS measurements.
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Vanillin is an interesting corrosion inhibitor because of its safe use and high solubility inwater. The effect of vanillin on the corrosion inhibition of carbon steel in 1.0 Mhydrochloric acid solution has been studied using potentiodynamic polarization,electrochemical أکثر
Vanillin is an interesting corrosion inhibitor because of its safe use and high solubility inwater. The effect of vanillin on the corrosion inhibition of carbon steel in 1.0 Mhydrochloric acid solution has been studied using potentiodynamic polarization,electrochemical impedance spectroscopy (EIS) and electrochemical noise (EN) techniques.The effect of temperature on the rate of corrosion in the absence and presence of vanillinwas also studied. Some thermodynamic parameters were computed from the effect oftemperature on corrosion and inhibition processes. Adsorption of vanillin was found to obeyLangmuir adsorption isotherm. Furthermore, in this paper the electrochemical noise (EN)technique under open circuit conditions was employed for the quantitative evaluation ofcorrosion inhibition. This was done by using the standard deviation of partial signal (SDPS)for calculation of the amount of noise charges at the particular timescale range, therebyobtaining the inhibition efficiency (IE) of an inhibitor. These IE values show a reasonableagreement with those obtained from potentiodynamic polarization and EIS measurements.
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The inhibiting effects of some newly synthesized Schiff bases on the corrosion of Al-Pure in 1.0 M HCl have been studied by means of the chemical and electrochemical methods. The Schiff bases m-Chloroaniline-N-benzylidene (m-CANB), p-Chloroaniline–N-benzylidene (p أکثر
The inhibiting effects of some newly synthesized Schiff bases on the corrosion of Al-Pure in 1.0 M HCl have been studied by means of the chemical and electrochemical methods. The Schiff bases m-Chloroaniline-N-benzylidene (m-CANB), p-Chloroaniline–N-benzylidene (p-CANB), Benzylamine-N-(p-methoxy benzylidene) (BANPMB) and 2-Phenylethylamine-N-(p-methoxy benzylidene) (2PANPMB) were synthesized from benzyldehyde or substituted benzyldehyde with the corresponding amines and characterized by IR studies. The corrosion inhibition properties of these compounds on Al-Pure in 1.0 M HCl were investigated by weight loss, galvanostatic polarization and electrochemical impedance techniques. The weight loss study showed that the inhibition efficiency increases with increase in the concentration of the inhibitor and was found to be inversely related to temperature. The values of activation energy (Ea ), free energy of adsorption (∆Gads) and heat of adsorption (Qads) were calculated from the temperature data. The adsorption of these compounds on aluminium surface follows the Langmuir adsorption isotherm. The galvanostatic polarization data show that these compounds studied are mixed type inhibitors with predominant effect on the cathode. The mechanism of corrosion inhibition is also proposed.
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