Adsorption study of Ni (II) ion and azo dye DR278 in aqueous media using MoS2/O-MWCNTs adsorbent and optimization by response surface methodology
الموضوعات : Journal of NanoanalysisElham Ahangaran 1 , Hossein Aghaie 2 , Reza Fazaeli 3
1 - Department of Chemistry, Science and Research Branch, Islamic Azad University, Tehran, Iran
2 - Department of Chemistry, Science and Research Branch, Islamic Azad University, Tehran, Iran
3 - Department of Chemistry, Faculty of Engineering, South Tehran Branch, Islamic Azad University, Tehran, Iran
الکلمات المفتاحية: MoS2, O-MWCNTs, Adsorption, DR278, Ni (II),
ملخص المقالة :
In this research, molybdenum disulfide (MoS2) particles were synthesized by hydrothermal method and loaded on oxidized multiwalled carbon nanotubes (O-MWCNTs). MoS2 and MoS2/O-MWCNTs particles were characterized by several techniques. Adsorption of Direct Red 278 (DR278), and Ni (II) ion were investigated onto MoS2 and MoS2/O-MWCNTs particles. The effect of adsorbent mass (g), contact time (min), pH was evaluated by response surface methodology (RSM). The software determined the best point to achieve the highest removal efficiency for azo dye DR278, in the optimal conditions of adsorbent mass 0.03 (g), contact time 27.54 (min) and pH 5.01, 99.99%. Also, the removal efficiency for Ni (II) ion, under optimal conditions of adsorbent mass 0.04 (g), time 26.61 (min) and pH 7.09, 97.83%. Isothermal studies showed that the Dubinin–Radushkevich model had the highest correlation coefficients of 0.98 and 0.97 for Ni (II) ion and azo dye DR278 with the respectively lowest error rate, and the highest correlation to the experimental data. The adsorption kinetic results showed ion Ni (II) ion and Azo dye DR278 adsorptions are well described by the mentioned adsorbent with pseudo-second order kinetic model.
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