The Efficiency of UV/S2O82- and UV/ ZnO Photo-Oxidation Process for the Removal of Acetominophen from Aqueous Solution: A Comparative Study

الموضوعات :

Farham Aminsharei ¹ , Hossein Abbastabar ² , Ali Hassanzadeh-Tabrizi ³ , Sara Ataei ⁴

1 - Department of Safety, Health and Environment, Najafabad Branch, Islamic Azad University, Najafabad, Iran
2 - Human Environment and Sustainable Development Research Center, Najafabad Branch, Islamic Azad University, Najafabad, Iran.
3 - Advanced Materials Research Center, Department of Materials Engineering, Najafabad Branch, Islamic Azad University, Najafabad, Iran.
4 - Department of Safety, Health and Environment, Najafabad Branch, Islamic Azad University, Najafabad, Iran.

تاريخ الإرسال : 11 الإثنين , شوال, 1444 تاريخ التأكيد : 12 الأحد , محرم, 1445 تاريخ الإصدار : 14 الثلاثاء , محرم, 1445

الکلمات المفتاحية: Pharmaceutical, Persulfate, Photodegradation, Wastewater,

ملخص المقالة :

 

These days, water has a special importance in human life, and access to safe drinking water is essential to maintaining human health. The presence of residual pharmaceutical compounds as emerging contaminants (ECs) in wastewater deteriorates aquatic life and water quality due to the lack of effective treatment processes to remove them. This paper deals with the degradation and demineralization of acetaminophen (ACT) from its aqueous solution under UV-Vis irradiation using ZnO (UV/ZnO) and K₂S₂O₈ (UV/PS). Detailed batch tests were evaluated to investigate the effect of different variables such as pH, catalyst dose, reaction time, drug concentration and mineralization rate. The results showed the higher performance of the UV/PS process and the UV/ZnO at acidic and natural conditions, respectively. The constant reaction rate for ACT removal in the UV/PS process is almost double that of the UV/ZnO process. The results of the remaining TOC tests show that the processes can convert the ACT in the solution into harmless minerals such as carbon dioxide after degradation. Increasing the dose of catalysts to an optimum amount led to an increase in elimination efficiency. The UV/PS process is able to degrade 20 mg/L of acetaminophen in 50 minutes, while the UV/ZnO process breaks down this amount of acetaminophen in 100 minutes. This work can be developed for the removal of ECs related to the pharmaceutical group from contaminated water.

المصادر:

[1] A.M. Khalil, F.A. Memon, T.A. Tabish, D. Salmon, S. Zhang, D. Butler, Nanostructured porous graphene for efficient removal of emerging contaminants (pharmaceuticals) from water, Chemical Engineering Journal, Vol. 398, 2020, pp. 125440.
[2] H. Derikvandi, A. Nezamzadeh-Ejhieh, Increased photocatalytic activity of NiO and ZnO in photodegradation of a model drug aqueous solution: effect of coupling, supporting, particles size and calcination temperature, Journal of hazardous materials, Vol. 321, 2017, pp. 629-638.
[3] S. Sharifian, A. Nezamzadeh-Ejhieh, Modification of carbon paste electrode with Fe (III)-clinoptilolite nano-particles for simultaneous voltammetric determination of acetaminophen and ascorbic acid, Materials Science and Engineering: C, Vol. 58, 2016, pp. 510-520.
[4] S. Fekadu, E. Alemayehu, R. Dewil, B. Van der Bruggen, Pharmaceuticals in freshwater aquatic environments: A comparison of the African and European challenge, Science of the total Environment, Vol. 654, 2019, pp. 324-337.
[5] M. Jafarisani, A.H.C. Khavar, A.R. Mahjoub, R. Luque, D. Rodríguez-Padrón, M. Satari, A.M. Gharravi, H. Khastar, S.S. Kazemi, M. Masoumikarimi, Enhanced visible-light-driven photocatalytic degradation of emerging water contaminants by a modified zinc oxide-based photocatalyst; In-vivo and in-vitro toxicity evaluation of wastewater and PCO-treated water, Separation and Purification Technology, Vol. 243, 2020, pp. 116430.
[6] A. Mashayekh-Salehi, G. Moussavi, K. Yaghmaeian, Preparation, characterization and catalytic activity of a novel mesoporous nanocrystalline MgO nanoparticle for ozonation of acetaminophen as an emerging water contaminant, Chemical engineering journal, Vol. 310, 2017, pp. 157-169.
[7] J. Rivera-Utrilla, M. Sánchez-Polo, M.Á. Ferro-García, G. Prados-Joya, R. Ocampo-Pérez, Pharmaceuticals as emerging contaminants and their removal from water. A review, Chemosphere, Vol. 93, 2013, pp. 1268-1287.
[8] C.J. Lin, W.-T. Yang, C.-Y. Chou, S.Y.H. Liou, Hollow mesoporous TiO2 microspheres for enhanced photocatalytic degradation of acetaminophen in water, Chemosphere, Vol. 152, 2016, pp. 490-495.
[9] A. Saffar, H.A. Ahangar, A. Aghili, S. Hassanzadeh-Tabrizi, F. Aminsharei, H. Rahimi, J.A. Kupai, Synthesis of the novel CuAl2O4–Al2O3–SiO2 nanocomposites for the removal of pollutant dye and antibacterial applications, Research on Chemical Intermediates, Vol. 47, 2021, pp. 599-614.
[10] L. Rizzo, S. Malato, D. Antakyali, V.G. Beretsou, M.B. Đolić, W. Gernjak, E. Heath, I. Ivancev-Tumbas, P. Karaolia, A.R.L. Ribeiro, Consolidated vs new advanced treatment methods for the removal of contaminants of emerging concern from urban wastewater, Science of the Total Environment, Vol. 655, 2019, pp. 986-1008.
[11] Z. Cai, A.D. Dwivedi, W.-N. Lee, X. Zhao, W. Liu, M. Sillanpää, D. Zhao, C.-H. Huang, J. Fu, Application of nanotechnologies for removing pharmaceutically active compounds from water: development and future trends, Environmental Science: Nano, Vol. 5, 2018, pp. 27-47.
[12] L.F. Angeles, R.A. Mullen, I.J. Huang, C. Wilson, W. Khunjar, H.I. Sirotkin, A.E. McElroy, D.S. Aga, Assessing pharmaceutical removal and reduction in toxicity provided by advanced wastewater treatment systems, Environmental Science: Water Research & Technology, Vol. 6, 2020, pp. 62-77.
[13] S. Vahabirad, A. Nezamzadeh-Ejhieh, Evaluation of the photodegradation activity of bismuth oxoiodide/bismuth sub-carbonate nanocatalyst: Experimental design and the mechanism study, Ecotoxicology and Environmental Safety, Vol. 263, 2023, pp. 115254.
[14] A. Norouzi, A. Nezamzadeh-Ejhieh, R. Fazaeli, A Copper (I) oxide-zinc oxide nano-catalyst hybrid: Brief characterization and study of the kinetic of its photodegradation and photomineralization activities toward methylene blue, Materials Science in Semiconductor Processing, Vol. 122, 2021, pp. 105495.
[15] S. Nissen, B.D. Alexander, I. Dawood, M. Tillotson, R.P. Wells, D.E. Macphee, K. Killham, Remediation of a chlorinated aromatic hydrocarbon in water by photoelectrocatalysis, Environmental pollution, Vol. 157, 2009, pp. 72-76.
[16] E. Mena, A. Rey, E. Rodríguez, F. Beltrán, Nanostructured CeO2 as catalysts for different AOPs based in the application of ozone and simulated solar radiation, Catalysis Today, Vol. 280, 2017, pp. 74-79.
[17] K. Yaghmaeian, G. Moussavi, A. Mashayekh-Salehi, A. Mohseni-Bandpei, M. Satari, Oxidation of acetaminophen in the ozonation process catalyzed with modified MgO nanoparticles: effect of operational variables and cytotoxicity assessment, Process Safety and Environmental Protection, Vol. 109, 2017, pp. 520-528.
[18] Y.-C. Lee, S.-L. Lo, J. Kuo, Y.-L. Lin, Persulfate oxidation of perfluorooctanoic acid under the temperatures of 20–40 °C, Chemical engineering journal, Vol. 198, 2012, pp. 27-32.
[19] C. Tan, N. Gao, S. Zhou, Y. Xiao, Z. Zhuang, Kinetic study of acetaminophen degradation by UV-based advanced oxidation processes, Chemical Engineering Journal, Vol. 253, 2014, pp. 229-236.
[20] J. Chun-Te Lin, M.D.G. de Luna, G.L. Aranzamendez, M.-C. Lu, Degradations of acetaminophen via a K2S2O8-doped TiO2 photocatalyst under visible light irradiation, Chemosphere, Vol. 155, 2016, pp. 388-394.
[21] K. Pradeev Raj, K. Sadaiyandi, A. Kennedy, S. Sagadevan, Z.Z. Chowdhury, M.R.B. Johan, F.A. Aziz, R.F. Rafique, R. Thamiz Selvi, R. Rathina Bala, Influence of Mg doping on ZnO nanoparticles for enhanced photocatalytic evaluation and antibacterial analysis, Nanoscale research letters, Vol. 13, 2018, pp. 1-13.
[22] R. Andreozzi, V. Caprio, R. Marotta, D. Vogna, Paracetamol oxidation from aqueous solutions by means of ozonation and H2O2/UV system, Water research, Vol. 37, 2003, pp. 993-1004.
[23] L. Ahmadpour-Mobarakeh, A. Nezamzadeh-Ejhieh, A zeolite modified carbon paste electrode as useful sensor for voltammetric determination of acetaminophen, Materials Science and Engineering: C, Vol. 49, 2015, pp. 493-499.
[24] M.G. Alalm, A. Tawfik, S. Ookawara, Enhancement of photocatalytic activity of TiO2 by immobilization on activated carbon for degradation of pharmaceuticals, Journal of Environmental Chemical Engineering, Vol. 4, 2016, pp. 1929-1937.
[25] M. Pourakbar, G. Moussavi, S. Shekoohiyan, Homogenous VUV advanced oxidation process for enhanced degradation and mineralization of antibiotics in contaminated water, Ecotoxicology and Environmental Safety, Vol. 125, 2016, pp. 72-77.
[26] G. Moussavi, M. Mahmoudi, Degradation and biodegradability improvement of the reactive red 198 azo dye using catalytic ozonation with MgO nanocrystals, Chemical Engineering Journal, Vol. 152, 2009, pp. 1-7.
[27] A. Pourtaheri, A. Nezamzadeh-Ejhieh, Photocatalytic properties of incorporated NiO onto clinoptilolite nano-particles in the photodegradation process of aqueous solution of cefixime pharmaceutical capsule, Chemical Engineering Research and Design, Vol. 104, 2015, pp. 835-843.
[28] S.T. Glassmeyer, E.T. Furlong, D.W. Kolpin, A.L. Batt, R. Benson, J.S. Boone, O. Conerly, M.J. Donohue, D.N. King, M.S. Kostich, Nationwide reconnaissance of contaminants of emerging concern in source and treated drinking waters of the United States, Science of the Total Environment, Vol. 581, 2017, pp. 909-922.
[29] E.S. Elmolla, M. Chaudhuri, Comparison of different advanced oxidation processes for treatment of antibiotic aqueous solution, Desalination, Vol. 256, 2010, pp. 43-47.
[30] T.A. Bakka, M.B. Strøm, J.H. Andersen, O.R. Gautun, Synthesis and antimicrobial evaluation of cationic low molecular weight amphipathic 1, 2, 3-triazoles, Bioorganic & Medicinal Chemistry Letters, Vol. 27, 2017, pp. 1119-1123.
[31] S.M. Aydoghmish, S. Hassanzadeh-Tabrizi, A. Saffar-Teluri, Facile synthesis and investigation of NiO–ZnO–Ag nanocomposites as efficient photocatalysts for degradation of methylene blue dye, Ceramics International, Vol. 45, 2019, pp. 14934-14942.
[32] Z. Khodami, A. Nezamzadeh-Ejhieh, Investigation of photocatalytic effect of ZnO–SnO2/nano clinoptilolite system in the photodegradation of aqueous mixture of 4-methylbenzoic acid/2-chloro-5-nitrobenzoic acid, Journal of Molecular Catalysis A: Chemical, Vol. 409, 2015, pp. 59-68.
[33] R. Zamiri, H.A. Ahangar, D. Tobaldi, A. Rebelo, M. Seabra, M. Shabani, J. Ferreira, Fabricating and characterising ZnO–ZnS–Ag2S ternary nanostructures with efficient solar-light photocatalytic activity, Physical Chemistry Chemical Physics, Vol. 16, 2014, pp. 22418-22425.
[34] M. Rani, U. Shanker, V. Jassal, Recent strategies for removal and degradation of persistent & toxic organochlorine pesticides using nanoparticles: a review, Journal of environmental management, Vol. 190, 2017, pp. 208-222.
[35] S.Y. Jasim, J. Saththasivam, Advanced oxidation processes to remove cyanotoxins in water, Desalination, Vol. 406, 2017, pp. 83-87.